Abstract: A printable molecular ink that is can be treated (e.g. dried or curable) and sintered using broad spectrum ultraviolet light is provided to produce electrically conductive traces on a low temperature substrate, for example PET. The ink includes a silver or copper carboxylate, an organic amine compound, and may include a thermal protecting agent.
Type:
Grant
Filed:
August 2, 2019
Date of Patent:
January 16, 2024
Inventors:
Xiangyang Liu, Jianfu Ding, Patrick Roland Lucien Malenfant, Chantal Paquet, Bhavana Deore, Arnold J. Kell
Abstract: An exemplary printable composition comprises a liquid or gel suspension of a plurality of metallic nanofibers or nanowires; a first solvent; and a viscosity modifier, resin, or binder. In various embodiments, the metallic nanofibers are between about 10 microns to about 100 microns in length, are between about 10 nm to about 120 nm in diameter, and are typically functionalized with a coating or partial coating of polyvinyl pyrrolidone or a similar compound. An exemplary metallic nanofiber ink which can be printed to produce a substantially transparent conductor comprises a plurality of metallic nanofibers; one or more solvents such as 1-butanol, ethanol, 1-pentanol, n-methylpyrrolidone, cyclohexanone, cyclopentanone, 1-hexanol, acetic acid, cyclohexanol, or mixtures thereof; and a viscosity modifier, resin, or binder such as polyvinyl pyrrolidone or a polyimide, for example.
Type:
Grant
Filed:
November 10, 2021
Date of Patent:
January 9, 2024
Assignee:
NthDegree Technologies Worldwide Inc
Inventors:
Mark David Lowenthal, Mark Lewandowski, Jeffrey Baldridge, Lixin Zheng, David Michael Chesler
Abstract: A conductive polymer composite for adhesion to a flexible substrate contains a polymer adhesive containing a curable polymer and a curing agent; and a conductive filler containing a metal and a carbonaceous material dispersed in the polymer adhesive. The conductive polymer composite is suitable for application to not only the human body but also other objects having irregular surface. In addition, due to enhanced adhesive strength of the conductive polymer composite to the flexible substrate, the reduction in conductivity or conductivity breakdown caused by external stress can be prevented and flexibility and stretchability can be improved.
Type:
Grant
Filed:
July 2, 2019
Date of Patent:
January 9, 2024
Assignee:
Korea Institute of Science and Technology
Inventors:
Heesuk Kim, Youngpyo Ko, Min Park, Sang-Soo Lee, Jeong Gon Son, Jong Hyuk Park, Seungjun Chung, Tae Ann Kim
Abstract: The present disclosure provides a method for facet-selective passivation on each crystal facet of colloidal nanocrystals via solution-phase ligand exchange process, thereby providing highly-passivated and colloidally-stable nanocrystal inks. This ligand exchange strategy separately addresses polar and non-polar facets precluding from deleterious nanocrystal aggregation in the colloid. The method involves the introduction of alkali metal organic complexes during metal halide conventional solution exchanges, and one specific example is Na+·Ac?. Alkali metal ions stabilize and passivate non polar facets whereas polar facets are passivated through metal halides. This strategy leads to a significant decrease in nanocrystal aggregation during and after ligand exchange, and to improved photophysical properties stemming from this. The resulting nanocrystal solid films exhibit improved stability, retain their absorption features, and have a minimized Stokes shift.
Type:
Grant
Filed:
May 14, 2019
Date of Patent:
December 19, 2023
Assignee:
QD SOLAR INC.
Inventors:
Younghoon Kim, Fanglin Che, Jea Woong Jo, Jongmin Choi, Francisco Pelayo Garcia De Arquer, Sjoerd Hoogland, Edward H. Sargent
Abstract: The invention relates to novel organic semiconducting compounds containing a polycyclic unit, to methods for their preparation and educts or intermediates used therein, to compositions, polymer blends and formulations containing them, to the use of the compounds, compositions and polymer blends as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photodetectors (OPD), organic field effect transistors (OFET) and organic light emitting diodes (OLED), and to OE, OPV, PSC, OPD, OFET and OLED devices comprising these compounds, compositions or polymer blends.
Type:
Grant
Filed:
March 26, 2019
Date of Patent:
December 5, 2023
Assignee:
RAYNERGY TEK INC.
Inventors:
William Mitchell, Agnieszka Pron, Mansoor D'Lavari, Kane Heard, Jonathan Snow, Ignasi Burgues, Quentin Huaulme
Abstract: A carbon fiber composite material comprising: (i) a carbon fiber having an outer surface, a thickness of at least 1 micron, and an aspect ratio of at least 1000; (ii) a sizing agent coated on the outer surface of the carbon fiber, wherein the sizing agent has a thickness of up to 200 nm; and (iii) nanoparticles having a size in at least one dimension of up to 100 nm embedded within the sizing agent, wherein the nanoparticles have a metal carbide, metal oxide, metal nitride, and/or metal boride composition. A method for producing the fiber composite material comprises: (a) continuously feeding and coating a continuous carbon fiber with a liquid containing a solvent, sizing agent, and nanoparticles in a continuous feed-through process to result in said sizing agent and nanoparticles coating the surface of the continuous carbon fiber; and (b) removing the solvent from the coated fiber.
Abstract: The invention relates to a solid body of a compound of formula Zn1-t-eTtEeO1-yYy, wherein the compound has a wurtzite structure and wherein T represents one or more transition metals, selected from one or more of Mn, Cd, Cr, Fe, Co and Ni; E represents one or more alkaline earth metals, selected from one or more of Be, Mg, Ca, Sr and Ba; Y represents one or more chalcogens, selected from S, Se, Te; tis a value in the region of 0 to <1; e is a value from 0 to <1, and y is a value from 0 to <1.
Type:
Grant
Filed:
August 9, 2018
Date of Patent:
November 21, 2023
Assignee:
Heubach GmbH
Inventors:
Dieter Lieske, Maria Kubica, Stephan Blöss
Abstract: The present invention relates to an ink composition for an organic light emitting device that can be applied to an inkjet process. The ink composition comprises a compound represented by the following Chemical Formula 1, a first solvent of aromatic esters having a boiling point of 260 to 400° C., and a second solvent of aliphatic ethers or aliphatic esters having a boiling point of 200 to 400° C., wherein the boiling point of the first solvent is higher than that of the second solvent. When this is applied to an inkjet process, it can form a flat film with a smooth surface when dried after forming the ink film. wherein L, L1 to L4, Ar1, Ar2, R1 to R4, Y1 to Y4, and n1 to n4 are described herein.
Abstract: Thermoset bulk molding compounds (BMC) useful for making electrically conductive components such as bipolar plates for fuel cells are described. The thermoset bulk molding compounds incorporate graphene nanoplatelets to increase the through-plane electrical conductivity by at least 20% compared to BMCs without the graphene nanoplatelets. Additionally, these compositions have low shrinkage, low density for lightweight parts, and are easily processed. The compositions can be used to prepare a variety of electrically conductive components, including bipolar plates for fuel cells and chemical storage batteries that operate at temperatures of less than 100° C.
Abstract: The present disclosure relates to a bridging asymmetric haloalkynyl dicobalt hexacarbonyl precursors, and ultra high purity versions thereof, methods of making, and methods of using these bridging asymmetric haloalkynyl dicobalt hexacarbonyl precursors in a vapor deposition process. One aspect of the disclosure relates to an ultrahigh purity bridging asymmetric haloalkynyl dicobalt hexacarbonyl precursor of the formula Co2(CO)6(R3C?CR4), where R3 and R4 are different organic moieties and R4 is more electronegative or more electron withdrawing compared to R3.
Type:
Grant
Filed:
November 19, 2020
Date of Patent:
October 31, 2023
Assignee:
ENTEGRIS, INC.
Inventors:
Sangbum Han, Seobong Chang, Bryan C. Hendrix, Jaeeon Park, Thomas H. Baum
Abstract: Provided is an organic metal complex having a structure represented by the following general formula (1): MLmL?n??(1) where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L?, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure MLm represents a structure represented by the following general formula (2): and a partial structure ML?n represents a structure including a monovalent bidentate ligand.
Type:
Grant
Filed:
April 27, 2020
Date of Patent:
October 17, 2023
Assignee:
SAMSUNG ELECTRONICS CO., LTD.
Inventors:
Jun Kamatani, Masashi Hashimoto, Satoshi Igawa, Shinjiro Okada
Abstract: An organic light emitting device of an embodiment of the present disclosure includes a first electrode, a hole transport region, an emission layer, an electron transport region, and a second electrode, stacked one by one, wherein the hole transport region includes a hole transport material derived from a crosslinking agent compound represented by Formula 1. The organic light emitting device may be manufactured through a wet process, and the emission efficiency and driving voltage properties of the organic light emitting device may be improved.
Abstract: The invention discloses a method of fabricating a copper-cobalt (Cu—Co) oxysulfide nanoarchitecture, the method comprising dissolving cobalt nitrate hexahydrate and copper nitrate in de-ionized (DI) water forming a growth solution, mixing disodium thiosulfate and urea to the formed growth solution, immersing a pre-cleaned Ni-foam substrate in the growth solution forming a total solution and transferring the total solution to a sealed glass bottle. The method further comprises heating the sealed glass bottle in an oil bath, thereby forming a flower-like morphology sample of copper-cobalt oxysulfide and cleaning and drying the formed sample of copper-cobalt oxysulfide. Also disclosed is a hybrid supercapacitor (HSC) comprising copper-cobalt (Cu—Co) oxysulfide nanosheets (NFs) on Ni foam as positive electrode; and copper-cobalt (Cu—Co) oxysulfide nanosheets (NFs) on porous carbon as negative electrode.
Abstract: Making a positive electrode active material for lithium ion secondary batteries includes: weighting and mixing lithium carbonate and a compound containing respective metallic elements other than Li in a composition formula Li?NixCoyM21-x-y-zM2zO2+? so as to have a metallic constituent ratio of the formula to obtain a mixture, and firing the mixture to obtain a lithium composite compound. Performing, on the mixture, a first heat treatment at 200° C. to 400° C. for 0.5 to 5 hours to obtain a first precursor. A step of performing a heat treatment on the first precursor under an oxidizing atmosphere at 450° C. to 800° C. for 0.5 to 50 hours, and reacting 92 mass % or more of the lithium carbonate to obtain a second precursor, and a finishing step of performing a heat treatment on the second precursor under an oxidizing atmosphere at 755° C. to 900° C. for 0.5 to 50 hours to obtain the lithium composite compound.
Abstract: In a method for manufacturing core-shell particles including core particles and a shell, the constituent metal elements of the core particles and the shell are different from each other. A quinone-containing core particle dispersion containing at least core particles consisting of a first metal, hydroquinone (HQ), benzoquinone (BQ), and a second metal compound including a second metal element for making up the shell is prepared, and a reduction treatment is performed on the quinone-containing core particle dispersion, through addition of a reducing agent, to form a shell including the second metal element as a main constituent element, on the surface of the core particles. A mass ratio: HQ/BQ ratio of added hydroquinone (HQ) and benzoquinone (BQ) is 0.1 to 120.
Abstract: A resin composition includes a core-shell rubber, a vinyl-containing benzoxazine resin and a maleimide resin, wherein the core-shell rubber has a core-shell ratio of 6.0:4.0 to 9.5:0.5. The resin composition may be used to make various articles, such as a prepreg, a resin film, a laminate or a printed circuit board, and achieves improvements in at least one, more or all of the properties including dissipation factor, copper foil peeling strength (3 ?m copper foil), ten-layer board T300 thermal resistance, ten-layer board glass transition temperature, ten-layer board delamination temperature, inner resin flow, and resin filling property of open area.
Type:
Grant
Filed:
April 30, 2020
Date of Patent:
September 12, 2023
Assignee:
ELITE ELECTRONIC MATERIAL (KUNSHAN) CO., LTD.
Abstract: The present application relates to polymer microparticle-metal nanoparticle composites, to methods of preparing polymer microparticle-metal nanoparticle composites and to uses of such composites. The methods comprise introducing into a microfluidic device, a composition comprising: a cationic metal nanoparticle precursor; a polymer microparticle precursor that comprises a plurality of photopolymerizable groups; and a photoreducer-photoinitiator; then irradiating the composition under conditions to simultaneously reduce the cationic metal and polymerize the photopolymerizable groups to obtain the composite.
Type:
Grant
Filed:
September 25, 2018
Date of Patent:
September 12, 2023
Assignee:
National Research Council of Canada
Inventors:
Lidija Malic, Xuefeng Zhang, Keith Morton, Teodor Veres
Abstract: A molecular ink contains: a silver carboxylate; and a polymeric binder comprising a polyester, polyimide, polyether imide or any mixture thereof having functional groups that render the polymeric binder compatible with the organic amine. Such an ink may have higher silver loading, lower viscosity and lower processing temperatures than existing silver inks.
Type:
Grant
Filed:
February 8, 2018
Date of Patent:
September 5, 2023
Inventors:
Chantal Paquet, Xiangyang Liu, Arnold J. Kell, Patrick Roland Lucien Malenfant, Bhavana Deore
Abstract: A nanocrystal including a core including a Group III element and a Group V element, and a monolayer shell on the surface of the core, the shell including a compound of the formula ZnSexS(1-x), wherein 0?x?1, and wherein an average mole ratio of Se:S in the monolayer shell ranges from about 2:1 to about 20:1.
Type:
Grant
Filed:
February 9, 2021
Date of Patent:
August 29, 2023
Assignee:
SAMSUNG ELECTRONICS CO., LTD.
Inventors:
Shin Ae Jun, Eun Joo Jang, Soo Kyung Kwon, Taek Hoon Kim, Won Joo Lee