Patents Examined by William Diemler
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Patent number: 5059306Abstract: In the removal of pure aromatics from aromatic-containing hydrocarbon mixtures by liquid-phase extraction or extractive distillation using a selective solvent, the specific cost of separation can be reduced at the same yield of aromatics or the yield of aromatics can be increased at the same specific cost of separation if the liquid-phase extraction or the extractive distillation is carried out in the presence of a reactive solid. At the same time, substantially aromatic-free raffinates are obtained.Type: GrantFiled: June 21, 1990Date of Patent: October 22, 1991Assignee: Bayer AktiengesellschaftInventors: Hans-Joachim Kramer, Bruno Schulwitz, Werner Horlitz, Peter M. Lange, Alfred Mitschker
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Patent number: 5043058Abstract: Effective quenching is provided in a catalytic cracking process to increase product yield and decrease thermal cracking. To this end, the quench is injected at special locations and a special quench is used. In the illustrated embodiment, the quench is injected into the oil product immediately downstream of an external gross cut separator before the product enters a disengaging vessel and the quench comprises cycle oil.Type: GrantFiled: March 26, 1990Date of Patent: August 27, 1991Assignee: Amoco CorporationInventors: John M. Forgac, F. William Hauschildt, George P. Quinn, Douglas N. Rundell, John G. Schwartz, Mark S. Camp
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Patent number: 5028313Abstract: A process for treating a hydrocarbonaceous feed stream containing a non-distillable component to produce a distillable hydrocarbonaceous product and a heavy product comprising the non-distillable component while minimizing thermal degradation of the hydrocarbonaceous feed stream which process comprises the steps of: (a) contacting the hydrocarbonaceous feed stream with a hot first hydrogen-rich gaseous stream having a temperature greater than the hydrocarbonaceous feed stream in a flash zone at flash conditions without indirect heat exchange thereby increasing the temperature of the hydrocarbonaceous feed stream and vaporizing at least a portion thereof to provide a hydrocarbonaceous vapor stream comprising hydrogen and a heavy product comprising the non-distillable component; (b) removing the hydrocarbonaceous vapor stream comprising hydrogen from the flash zone without contacting the vapor stream with hydrocarbonaceous liquid; (c) condensing at least a portion of the hydrocarbonaceous vapor stream comprisinType: GrantFiled: May 19, 1989Date of Patent: July 2, 1991Assignee: UOPInventors: Tom N. Kalnes, Robert B. James, Jr.
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Patent number: 5017735Abstract: A process for enriching the fraction of 2,6-diisopropylnaphthalene contained in a quantity of mixed dialkylated naphthalenes. The mixed dialkylated naphthalenes are contacted with an adsorbant bed containing one or more molecular sieves which demonstrate shape selective preference for the 2,6-diisopropylnaphthalene isomer over other dialkylated naphthalenes. The adsorbant bed is then contacted with a desorbant capable of desorbing the 2,6-diisopropylnaphthalene from the pores of the adsorbant.Type: GrantFiled: July 24, 1989Date of Patent: May 21, 1991Assignee: Catalytica, Inc.Inventors: Jere Fellmann, Paul R. Wentrcek, Peter Kilner
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Patent number: 5015364Abstract: A process is disclosed for operating a refinery gas plant such as the unsaturated gas plant of a catalytic hydrocarbon conversion process that results in a reduction of the corrosive effect of acid gases on the gas plant vessels and equipment. The process comprises contacting acidic hydrocarbon feedstreams to an unsaturated gas plant separator zone with lean acid gas absorbing absorbent in an absorbtion zone comprising at least one liquid absorber bed and one vapor absorber bed. The liquid and vapor absorber beds are located upstream of the separator zone. The feedstreams to the gas plant comprise unstabilized, or wild, liquid gasoline and liquid and vapor output streams from the liquid-vapor separator for inter-stage wet gas compressor of the conversion process main fractionator. Accordingly, these feedstreams are deacidified before separation in the USGP deethanizer-absorber, sponge absorber, and debutanizer. This also eliminates the need for deacidification of the gas plant product stream.Type: GrantFiled: June 21, 1989Date of Patent: May 14, 1991Assignee: Mobil Oil CorporationInventor: Mohsen N. Harandi
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Patent number: 5011592Abstract: A process for controlled, multi-stage regeneration of FCC catalyst is disclosed. A modified high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed regenerates the catalyst in at least two stages. The primary stage of regeneration is in the coke combustor, at full CO oxidation conditions. The second stage of catalyst regeneration occurs in the second fluidized bed, at partial CO combustion conditions. The process permits regeneration of spent FCC catalyst while minimizing NOx exmissions and achieving significant reduction of SOx.Type: GrantFiled: July 17, 1990Date of Patent: April 30, 1991Assignee: Mobil Oil CorporationInventors: Hartley Owen, Paul H. Schipper
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Patent number: 5012039Abstract: A process for the separation of 2,7 DIPN from a hydrocarbon feed mixture comprising 2,7 DIPN and one or more other DIPN isomers, which process employs an adsorbent, comprising a type Y zeolite, dried to an LOI less than 10% which has been at least partially cation exchanged, at exchangeable sites, with potassium. The 2,7 DIPN thereafter is removed from the adsorbent by contacting it with an aromatic hydrocarbon desorbent material, comprising a xylene, e.g., para-xylene, benzene or toluene at desorbent conditions, and is recovered as an extract product stream. In a preferred embodiment, the process uses a simulated moving-bed countercurrent flow system.Type: GrantFiled: April 16, 1990Date of Patent: April 30, 1991Assignee: UOPInventor: Timothy J. Barder
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Patent number: 5008001Abstract: The present invention relates to a process for hydrogenating a heavy oil in a hydrogenation reactor of the suspension bed type by the use of catalyst particles and subjecting a catalyst slurry consisting of the used catalyst and the product oil withdrawn from the hydrogenation reactor to solid/liquid separation to recover the product oil and then regenerating by oxidation the used catalyst, the improvement being that the solid/liquid separation step includes at least a step of heat drying oil-containing catalyst particles.In accordance with the process of the present invention, the rate of recovery of oil in the catalyst slurry is high and the yield of product oil can be increased.Type: GrantFiled: July 25, 1988Date of Patent: April 16, 1991Assignee: Research Association for Petroleum Alternatives DevelopmentInventors: Toru Kitamura, Yoshio Ohashi, Masami Sekino, Kenichi Murakawa
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Patent number: 5004533Abstract: A process for treating an organic stream containing a non-distillable component to produce an organic vapor stream and a solid which process comprises the steps of: (a) contacting the organic stream containing a non-distillable component with a hydrogen-rich gaseous steam having a temperature greater than the organic stream in a flash zone at flash conditions thereby increasing the temperature of the organic stream and vaporizing at least a portion thereof to produce an organic vapor stream comprising hydrogen and a heavy stream comprising the non-distillable component; and (b) reacting at least a portion of the heavy stream comprising the non-distillable component in the presence of hydrogen in a pyrolysis zone to produce a thermally stabilized volatile organic stream comprising hydrogen and a solid.Type: GrantFiled: March 12, 1990Date of Patent: April 2, 1991Assignee: UOPInventors: Tom N. Kalnes, Robert B. James, Jr.
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Patent number: 4996388Abstract: A process of separating the ortho, meta and para isomers of ethyltoluene. One aspect employs a ferrierite absorbent which separates the para isomer from a mixture of the same and at least one of the meta and ortho isomers. A second aspect employs a silicalite absorbent which separates the ortho isomer from a mixture of the same and the meta isomer. A third aspect combines the ferrierite and silicalite absorbents in sequence to separate a mixture of the ortho, meta and para isomers into the essentially pure compounds.Type: GrantFiled: July 26, 1990Date of Patent: February 26, 1991Assignee: The Dow Chemical CompanyInventors: Michael M. Olken, Guo-shuh J. Lee, Juan M. Garces
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Patent number: 4995962Abstract: There is provided a process for hydroisomerizing petroleum or synthetic paraffin wax with a particular catalyst. The catalyst comprises a hydrogenating component and a layered titanate containing an interspathic polymeric oxide such as silica. The hydrogenating component may be a Group VIII metal such as Pt.Type: GrantFiled: December 29, 1989Date of Patent: February 26, 1991Assignee: Mobil Oil CorporationInventors: Thomas F. Degnan, Jr., Michael E. Landis
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Patent number: 4992621Abstract: The chromatographic adsorption separation of coumarone from indene-containing coal tar distillate feed mixtures with an alkali metal (Group IA) exchanged X-zeolite and polar materials, e.g., ketones, alcohols or esters as desorbents. Also disclosed is a process for separating a coumarone-indene coextract with sodium-exchanged Y zeolite and toluene as desorbent.Type: GrantFiled: September 26, 1989Date of Patent: February 12, 1991Assignee: UOPInventor: Hermann A. Zinnen
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Patent number: 4983783Abstract: Reduction of carbon oxides products in oxidative pyrolysis of halogenated methanes in gas phase halogen-catalyzed oxidative-pyrolytic, non-flame, conversion of methane to higher molecular weight hydrocarbons is carried out in the presence of oxygen-containing gas which is primarily introduced in a latter portion of the process sequence reducing the oxygen requirement for effective suppression of formation of carbonaceous deposits thereby reducing carbon oxides product. Conversion of halogenated methanes to high yields of ethylene by conduct of the reaction in the presence of methane further reduces oxygen requirements and results in insignificant solid carbonaceous deposit formation.Type: GrantFiled: July 25, 1989Date of Patent: January 8, 1991Assignee: Illinois Institute of TechnologyInventor: Selim M. Senkan
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Patent number: 4981578Abstract: BF.sub.3 is removed from a promoted BF.sub.3 catalyzed olefin oligomer reaction product by contacting the reaction product with either solid or aqueous KF to form a solid KBF.sub.4 precipitate. Solid NaF or NH.sub.4 F can also be used.Type: GrantFiled: December 7, 1989Date of Patent: January 1, 1991Assignee: Ethyl CorporationInventors: Lindsay T. Tycer, Everett M. Marlett
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Patent number: 4961838Abstract: A two step process for the obtainment of white oils, using hydrocarbons which are heavy alkylates obtained as a by product in the manufacture of detergent range linear alkylbenzene (9-15 carbon atom paraffin chains) as the raw material is described.The first step consists of pretreatment (of an absorbent nature) of the feed, with an activated magnesium silicate in order to eliminate the heaviest components. In a second stage, the resulting treated product acts as a feed in a hydrogenation process to produce white oils, in a presence of a hydrogenation catalyst formed by a metallic component of the group of iron and/or nickel upon a refractory inorganic oxide support.The catalytic hydrogenation process is carried out in a fix bed reactor with down flow.It is useful in the pharmaceutical and food industries.Type: GrantFiled: July 10, 1989Date of Patent: October 9, 1990Assignee: Salvador A. LloveraInventor: Salvador A. Llovera