Patents Examined by William E. Parker
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Patent number: 3996174Abstract: The subject of the invention is a process for the manufacture of heat-curable synthetic resins, based on reaction products of maleic anhydride with mixtures of polybutadiene, unsaturated hydrocarbon resins and unsaturated fatty acid glyceride esters, which can be diluted with water and are suitable for the electrophoretic coating process.Type: GrantFiled: May 15, 1974Date of Patent: December 7, 1976Assignee: Hoechst AktiengesellschaftInventors: Bernhard Broecker, Richard Schardt
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Patent number: 3993612Abstract: In an aqueous coating composition comprising a vinyl polymer emulsion prepared by subjecting a vinyl monomer to emulsion polymerization in an aqueous medium in the presence of maleinized polybutadiene used as a dispersion stabilizer, an improvement which is characterized in that at least one copolymer is further incorporated, said copolymer being composed of (A) at least one monomer prepared by reacting one glycidyl ester of acrylic acid and methacrylic acid with at least one fatty acid of drying oil fatty acid and semi-drying oil fatty acid, (B) at least one .alpha.,.beta.-ethylenically unsaturated acid and (C) at least one unsaturated monomer containing substantially no carboxyl group and having a Q value of at least 0.1 as determined by Q-e theory.Type: GrantFiled: March 19, 1975Date of Patent: November 23, 1976Assignee: Kansai Paint Company, Ltd.Inventors: Tetsuo Aihara, Tadashi Watanabe, Yasuharu Nakayama, Yoshio Yamashita, Isao Toyomoto
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Patent number: 3993613Abstract: An adhesive composition is disclosed consisting essentially of a rubbery radial teleblock copolymer of a conjugated diene monomer and a vinyl-substituted aromatic monomer, a tackifier and a tackifier modifier, the latter being a polyalkene having a weight average molecular weight of about 200 to about 3000, said alkene having 2 to about 8 carbon atoms.Type: GrantFiled: February 24, 1975Date of Patent: November 23, 1976Assignee: Phillips Petroleum CompanyInventors: Richard C. Doss, Lawrence D. Jurrens
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Patent number: 3988275Abstract: This invention provides a concentrated latex of synthetic rubbers almost without causing precipitation or coagulation of the latex components.Type: GrantFiled: September 5, 1974Date of Patent: October 26, 1976Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kunio Satake, Takeshi Wada, Kuniaki Sakamoto, Hiroshi Harada, Yasushi Sato
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Patent number: 3988296Abstract: Chlorinated olefin polymer compositions having unexpectedly high tensile impact strength values and resistance to ignition and burning are composed essentially of an admixture of (1) a normally solid, linear olefin polymer having a bulk density of from about 22 to about 36 pounds/cubic foot with the individual particles thereof being predominantly in the range of at least 300 to about 800 microns in size, the olefin polymer having from about 1 to about 20 percent by weight of chemically combined chlorine substantially heterogeneously distributed along the outer surfaces of the polymer particles; such chlorine being introduced in the substantial absence of oxygen and at temperatures not substantially exceeding about 90.degree. C. while the olefin polymer particles are maintained in a fluidized bed state; and (2) from about 0.1 to about 10 percent based on polymer weight of antimony trioxide, and, optionally, up to about 5 percent based on polymer weight of certain bromine containing compounds.Type: GrantFiled: January 9, 1975Date of Patent: October 26, 1976Assignee: The Dow Chemical CompanyInventors: James R. Bethea, Robert G. Bryan, Jr., S. Douglas Stain, Jr.
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Patent number: 3988295Abstract: Benzoxazole or oxadiazole type compounds chemically combined with certain hydroxyaryl type compounds give greatly and unexpectedly improved ultraviolet stabilization to polymeric materials at concentrations ranging from about 0.05 to about 5.0 percent by weight, preferably from about 0.1 to about 2.0 percent by weight of the polymer being stabilized. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including pigments, colorants, fillers, reinforcing agents and the like. These stabilizers may be incorporated into the polymer melt, dissolved in the polymer dope, or coated on the exterior of the molded article, film or extruded fiber.Type: GrantFiled: July 1, 1974Date of Patent: October 26, 1976Assignee: Eastman Kodak CompanyInventors: Gether Irick, Jr., Charles A. Kelly, James C. Martin
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Patent number: 3988273Abstract: An aqueous coating composition comprising an aqueous medium and a binder resin dispersed therein as neutralized with a base, the binder resin being a copolymer of (A) a monomer prepared by reacting at least one glycidyl ester of acrylic acid and methacrylic acid with at least one fatty acid of drying oil fatty acid and semi-drying oil fatty acid, (B) and .alpha.,.beta.-ethylenically unsaturated acid and (C) an unsaturated monomer containing substantially no carboxyl group and having a Q value of at least 0.1 as determined by Q-e theory.Type: GrantFiled: March 19, 1975Date of Patent: October 26, 1976Assignee: Kansai Paint Company, Ltd.Inventors: Aihara Tetsuo, Watanabe Tadashi, Nakayama Yasuharau, Yamashita Yoshio, Toyomoto Isao
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Patent number: 3986993Abstract: A composition containing fluorocarbon polymer, colloidal silica, alkyl benzene, water-miscible alcohol containing 4 or more carbon atoms, amine, fatty acid containing 8 or more carbon atoms, and liquid carrier is provided. This composition is useful for coating metal, especially cookware, to give a non-stick finish and also to provide an excellent primer coat.Type: GrantFiled: April 1, 1975Date of Patent: October 19, 1976Assignee: E. I. Du Pont de Nemours and CompanyInventor: Eustathios Vassiliou
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Patent number: 3986995Abstract: Friable compositions suitable for use as extrusion aids in polymeric extrusion formulations are prepared by a process which comprises mixing a paraffinic hydrocarbon wax, calcium hydroxide and a fatty acid while heating to a temperature of at least 150.degree. C and thereafter cooling to recover a solid, glass-like, friable composition, said paraffinic hydrocarbon wax having a drop melting point of at least 110.degree. F, an oil content of not greater than 50 percent by weight and a needle penetration value (77.degree. F) in the range of 1 mm to 20 mm, and said fatty acid being a C.sub.16 -C.sub.24 aliphatic hydrocarbon monocarboxylic acid or mixtures thereof.Type: GrantFiled: February 10, 1975Date of Patent: October 19, 1976Assignee: Continental Oil CompanyInventors: James E. Yates, Paul H. Washecheck
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Patent number: 3983088Abstract: The proposed coating contains (in weight per cent);______________________________________ boric anhydride 15-30, silicon carbide 15-35, epoxy resin 1-10, rosin 25-50, benzene the rest.Type: GrantFiled: June 22, 1972Date of Patent: September 28, 1976Inventors: Viktor Timofeevich Pozdneev, Mikhail Lvovich Khina, Dmitry Vasilievich Bashkirov, Nikolai Fedorovich Judin, Nikolai Sergeevich Kobzev
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Patent number: 3983263Abstract: Certain glycerides are effective flow-promoting agents in powdered acrylic coating formulations. As a powdered acrylic resin coating material is applied by electrostatic sprayer means to a substrate, a rough layer of discrete particles is formed. To produce a commercially acceptable coating, this layer must be fused into a continuous film and induced to flow into a smooth, glossy finish. The subject glycerides, which may be acetylated, promote such flow and produce a surface finish equivalent to that of the conventional acrylic paints which employ an organic solvent vehicle.Type: GrantFiled: June 27, 1974Date of Patent: September 28, 1976Assignee: General Motors CorporationInventors: Philip Weiss, Gordon D. Cheever
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Patent number: 3983086Abstract: Smoke retardant vinyl chloride and vinylidene chloride polymer compositions are obtained by including therein a synergistic mixture of (A) at least one nickel compound selected from the group consisting of NiCO.sub.3, NiCrO.sub.4, NiI.sub.2, NiO, NiS, NiSO.sub.4, nickel acetylacetonate, nickel citrate and nickel formate and (B) at least one iron compound selected from the group consisting of Fe.sub.3 C, Fe.sub.2 (MoO.sub.4).sub.3, Fe.sub.2 O.sub.3, Fe.sub.3 O.sub.4, FeS, cyclopentadienyl iron dicarbonyl, ferric acetylacetonate, ferric hydroxy distearate, and ferrocene. Substantial smoke retardation is also obtained by including the above nickel compounds or iron compounds individually in the vinyl chloride or vinylidene chloride polymer compositions.Type: GrantFiled: December 30, 1974Date of Patent: September 28, 1976Assignee: The B. F. Goodrich CompanyInventor: Elmer D. Dickens, Jr.
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Patent number: 3980630Abstract: Method of preparing an emulsifier useable in emulsion polymerization processes, comprising the steps of subjecting rosin, polyunsaturated fatty acid or mixture thereof to disproportionation reaction, in the presence of a catalyst of iron iodide, and then neutralizing with alkali, and use of such emulsifier in emulsion polymerization processes.Type: GrantFiled: April 30, 1975Date of Patent: September 14, 1976Assignee: Harima Chemicals Inc.Inventors: Masahisa Ishigami, Yoshikazu Inoue
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Patent number: 3979345Abstract: Friable compositions suitable for use as extrusion aids in polymeric extrusion formulations are prepared by a process which comprises mixing a paraffinic hydrocarbon wax and calcium salt of a fatty acid while heating to a temperature of at least 160.degree.C and thereafter cooling to recover a solid, glass-like, friable composition, said paraffinic hydrocarbon wax having a drop melting point of at least 110.degree.F, an oil content of not greater than 50 percent by weight and a needle penetration value at 77.degree.F in the range of 1 mm to 20 mm, and said fatty acid being a C.sub.16 -C.sub.24 aliphatic hydrocarbon monocarboxylic acid or mixtures thereof.Type: GrantFiled: February 10, 1975Date of Patent: September 7, 1976Assignee: Continental Oil CompanyInventors: James E. Yates, Wilfred M. Pinto
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Patent number: 3979346Abstract: Emulsion systems for preparing aqueous dispersions of alkyd resins; aqueous dispersions of alkyd resins, and a process of making the dispersions are described. The emulsion system comprises an aqueous medium containing 0.5 to 3 percent by weight ammonia and (A) at least one non-ionic emulsifier, the hydrophobic part containing two or more radicals of unsaturated fatty acid and/or fatty alcohol with an iodine number of between 130 and 200, and the hydrophilic part containing polyethylene glycol chains and/or monomethoxypolyethylene glycol chains with from 6 to 100 ethylene oxide units; and (B) at least one anionic emulsifier, the hydrophobic part containing two or more radicals of unsaturated fatty acid and/or fatty alcohol with an iodine number of between 130 and 200, and the hydrophilic part including carboxylic groups. In accordance with the process for dispersing alkyd resins, the alkyd resin is dispersed in water containing 0.Type: GrantFiled: October 31, 1974Date of Patent: September 7, 1976Assignee: Vianova-Kunstharz A.G.Inventors: Bertram Zuckert, Wolfgang Schmut
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Patent number: 3978013Abstract: An adhesive composition consisting essentially of a styrene-butadiene block copolymer, a tackifier, a hydrocarbon solvent and a small amount of water.Type: GrantFiled: December 26, 1974Date of Patent: August 31, 1976Assignee: Gulf Research & Development CompanyInventor: Pallavoor R. Lakshmanan
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Patent number: 3976612Abstract: A polyethylene composition consisting of: (A) a high density polyethylene with a viscosity-average molecular weight of 10 .times. 10.sup.4 to 20 .times. 10.sup.4, a number average molecular weight of 1 .times. 10.sup.4 or greater and a ratio between weight average molecular weight and number average molecular weight of 20 or less; (B) at least one inorganic calcium compound selected from a group consisting of calcium sulfite, calcium sulfate and calcium carbonate; and (C) a solid lubricant, if desired, the composition produces a film or sheet whose internal tearing resistance is high and equal in both longitudinal and lateral directions and the processibility of the resin composition may be extremely improved by incorporating as a fourth component, within a range of 1:5 to 5:1 in weight ratio with respect to the aforementioned high density polyethylene, a different high density polyethylene with a melt index of 0.1 to 1.0.Type: GrantFiled: February 24, 1975Date of Patent: August 24, 1976Assignee: Idemitsu, Kosan Kabushiki-Kaisha (Idemitsu Kosan Co., Ltd.)Inventors: Hidehiko Kaji, Takeshi Matsumoto, Norio Sugi, Atsuo Ikenaga, Shoichi Iwata, Masami Tomikawa
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Patent number: 3976625Abstract: Compositions containing diene/nitrile polymers having active halogen sites are cured using zinc oxide and a thiourea compound to yield vulcanizates having excellent heat resistance.Type: GrantFiled: December 26, 1974Date of Patent: August 24, 1976Assignee: The B.F. Goodrich CompanyInventor: Philip H. Starmer
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Patent number: 3975323Abstract: A copolyester is formed of at least one symmetrical aromatic dicarboxylic acid member, at least one dimer acid, and at least one C.sub.2 --C.sub.10 glycol, and at least one polyester polyol member. The polyester polyol member is either a polycaprolactone polyol having a molecular weight of 500-5,000, or a mixture of a polycaprolactone diol having a molecular weight of 300-5,000 and a nonpolymeric polyol. The resultant thermoplastic copolyester has a glass transition temperature of less than 25.degree.C and a polymer melting temperature greater than 70.degree.C, and is useful both as a hot melt adhesive by itself and as an ingredient of both pressure sensitive and non-pressure sensitive hot melt adhesive formulations. In producing the copolyester, an intermediate copolyester of the symmetrical aromatic dicarboxylic acid member, the dimer acid, and the glycol is chain extended by reaction with the polyester polyol member in a 2-6 hour reaction at about 225.degree.-270.degree.C under a vacuum of about 1-30 mm.Type: GrantFiled: January 21, 1975Date of Patent: August 17, 1976Assignee: National Starch and Chemical CorporationInventors: Paul C. Georgoudis, Jules E. Schoenberg, Dilip K. Ray-Chaudhuri, Paul P. Puletti
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Patent number: 3971744Abstract: A method for producing emulsions, concentrated dispersions and pastes based on plasticizers and hydrophilic fillers consists in polymerization of a mixture of monomers, at least one of which contains one or two carboxylic groups, alternatively in a form of anhydride, and the other contains more than one vinyl group in its molecule, by common free-radical initiators in a medium of a plasticizers or a mixture of plasticizers with an admixture of saturated or unsaturated higher fatty acids, either substituted by halogen or unsubstituted, and/or higher alcohols. The resulting polymer of the maximum particle size 100 .mu.m is transformed into the Na, K, or NH.sub.4 form. The emulsion, concentrated dispersion or paste is applied without further operations in processing of plastics, especially in production of plastic and synthetic leathers.Type: GrantFiled: July 11, 1974Date of Patent: July 27, 1976Assignee: Ceskoslovenska akademie vedInventors: Slavko Hudecek, Ivana Gavrilova