Abstract: Methods and systems for the valorization of carbon monoxide emissions from metallurgical furnaces into highly valuable low-carbon footprint chemicals using carbon monoxide electrolysis are disclosed herein are disclosed. A disclosed method includes operating a metallurgical furnace; obtaining, in connection with the operation of the metallurgical furnace, a volume of carbon monoxide; supplying the volume of carbon monoxide to a cathode area of a carbon monoxide electrolyzer to be used as a reduction substrate; and generating, using the carbon monoxide electrolyzer, the reduction substrate, and an oxidation substrate, a volume of generated chemicals. The volume of generated chemicals is at least one of: a volume of hydrocarbons, a volume of organic acids, a volume of alcohol, a volume of olefins and a volume of N-rich organic compounds.

Abstract: A method for fabricating a chemical composition containing an aromatic polymer, including the steps of: providing an anodic region and a cathodic region; providing an arene precursor; providing an electrochemical potential between the anodic region and the cathodic region; reacting the arene precursor via the electrochemical potential to form the composition, which further includes the step of conducting a cathodic reaction. A chemical composition containing an aromatic polymer prepared according to the method.

Abstract: A method for coating a substrate with a Co-Pi modified BiVO4/WO3 heterostructure film includes direct current reactive sputtering tungsten (W) onto a substrate in a gaseous mixture containing oxygen to form a tungsten trioxide (WO3) film, direct current reactive sputtering bismuth (Bi) onto the tungsten trioxide (WO3) film in a gaseous mixture containing oxygen to form a dibismuth trioxide (Bi2O3) film, drop-casting a vanadyl acetylacetonate solution onto the Bi2O3 film and heating at a temperature of at least 450° C. in ambient air to convert the Bi2O3 film to a BiVO4 film, and photoelectrochemically coating the BiVO4 film with a cobalt-phosphate (Co-Pi) to form a modified film on the surface of the substrate. A photoanode containing the Co-Pi modified BiVO4/WO3 heterostructure film prepared by the method, and its application in water splitting.

Abstract: A wet etch apparatus includes a wafer chuck, a dispensing nozzle, a liquid etchant container, and an electric field generator. The dispensing nozzle is above the wafer chuck. The liquid etchant container is in fluid communication with the dispensing nozzle. The electric field generator is operative to generate an electric field across the wafer chuck. The electric field generator includes a first electrode and a second electrode spaced apart from the first electrode in a direction substantially perpendicular to a top surface of the wafer chuck, and the second electrode is an electrode plate above the wafer chuck.

Abstract: A deionization battery cell including a first electrode compartment containing a first intercalation host electrode and includes a first water stream compartment in fluid communication with the first electrode compartment. The deionization battery cell further includes a second electrode compartment containing a second intercalation host electrode and a second water stream compartment in fluid communication with the second electrode compartment. The deionization battery cell also includes an ion exchange membrane assembly including a plurality of anion exchange membranes separated from each other, and from one or more cation exchange membranes positioned between the anion exchange membranes, by a plurality of intervening water stream compartments. The first and second water stream compartments are separated from one another by the ion exchange membrane assembly.

Abstract: Discussed is a deposition mask including a metal plate. The metal plate includes an alloy of nickel (Ni) and iron (Fe) having a plurality of through-holes. Each of the through-holes includes a first surface hole, a second surface hole opposite to the first surface hole, and a connecting part through which the first surface hole and the second surface hole communicate with each other. The metal plate includes a first outer portion, a second outer portion opposite to the first outer portion and a central portion between the first outer portion and the second outer portion. Nickel contents of the first outer portion and the second outer portion are greater than that of the central portion.

Abstract: The present disclosure is related to systems and methods for electrochemical process. The system may include a first electrode, a second electrode, an electric field distribution simulation optimizer, an electric field distribution controller, and a signal controller. The first electrode and the second electrode may form an electric field to change a substance on the second electrode. A morphology of the second electrode may be uneven. The first electrode may include an electrically conducting plate. A morphology of the electrically conducting plate may be in conformity with the morphology of the second electrode. A protruding portion of the electrically conducting plate may correspond to a recessing portion of the second electrode. A recessing portion of the electrically conducting plate may correspond to a protruding portion of the second electrode.

Abstract: Provided is a technique that allows suppressing a film thickness on an outer peripheral edge of a substrate becoming non-uniform. A plating apparatus 1 includes a plating tank, an anode, a substrate holder, at least one auxiliary anode 60a to 60d, a busbar 61 having a power feeding part 62, to which electricity is supplied, and a plurality of connecting parts 63 connected to the at least one auxiliary anode and arrayed in an extending direction of the auxiliary anode, and at least one ionically resistive element 80a to 80d. The ionically resistive element is configured to increase in resistivity of the ionically resistive element as approaching the power feeding part in an extending direction of the ionically resistive element.

Abstract: Transition metal MXene catalysts and methods for using with electrochemical cells for reduction of carbon dioxide and production of hydrocarbons. The transition metal catalysts include nanostructured transition metal carbides, nitrides, or carbonitrides. The method includes electrochemically reducing carbon dioxide in an electrochemical cell, by contacting the carbon dioxide with at least one transition metal carbide, nitride, or carbonitride catalyst in the electrochemical cell and applying a potential to the electrochemical cell. Also an apparatus and method for energy production and carbon sequestration. A photovoltaic cell is paired with an electrochemical cell, wherein a cathode side of the electrochemical cell reduces carbon dioxide to hydrocarbon, and an anode side of the electrochemical cell oxidizes water to oxygen. The hydrocarbon outlet can be connected to a heating element of an air handling unit, and the oxygen can likewise be introduced to the unit for air improvement.

Abstract: The electrochemical cell is an electrochemical cell which electrochemically synthesizes at least one carbonyl compound selected from the group consisting of organic carbonates and organic oxalates from carbon monoxide, and has an electrolyte solution containing a redox species and a catalyst, and an electrode.

Abstract: Methods and systems related to oxocarbon electrolyzers are disclosed herein. A disclosed system includes an oxocarbon electrolysis reactor. The rector includes an aqueous anode area with an oxidation substrate, a gaseous cathode area with an oxocarbon species as a reduction substrate, and an electroneutral separator separating the anode area and the cathode area while allowing ionic migration between the anode area and cathode area. In specific approaches disclosed herein the electroneutral separator is a polymer having a coating, the coating is formed of an aliphatic molecule, and the coating increases a hydrophilicity of the electroneutral separator. In specific approaches disclosed herein, the electroneutral separator is a polymer having a coating, the polymer comprises aliphatic carbon chains, and the coating is an aliphatic carbon chain with one or more hydrophilic functional groups.

Abstract: A preparation method, a product and an application of a composite membrane with a self-repairing function are provided by the present application, relating to the technical field of surface treatment of metallic materials. The preparation method includes the following steps: adding cobalt salt, tungsten salt, complexing agent and buffering agent into water to obtain a mixed solution, and adjusting a pH value to acidity to obtain an acidic solution; adding cerium oxide and surfactant into the acidic solution to obtain an electrolyte system; and placing a metal substrate in the electrolyte system for electrodeposition to obtain the composite membrane with self-repairing function. By means of constant potential composite electrodeposition on a metallic material substrate, the invention eventually forms a micron-scale composite membrane with a self-healing function and a thickness of 6-8 micrometers on the surfaces of the metallic materials.

Abstract: There are provided a silver-plated product having a more excellent wear resistance than that of conventional silver-plated products, and a method for producing the same. The method comprises the steps of: preparing a silver-plating solution which is an aqueous solution containing silver potassium cyanide or silver cyanide, potassium cyanide or sodium cyanide, and a benzothiazole or a derivative thereof; and forming a surface layer of silver on a base material by electroplating at a liquid temperature and at a current density in the silver-plating solution so as to satisfy (BC/A)2/D?10 (° C.2·dm2/A) assuming that a concentration of free cyanide in the silver-plating solution is A (g/L), that a concentration of a benzothiazole content of the benzothiazole or derivative thereof in the silver-plating solution is B (g/L), that the liquid temperature of the silver-plating solution is C (° C.) and that the current density during the electroplating is D (A/dm2).

Abstract: Disclosed are surface modified electrodes, their process of preparation and their use in the electrolytic reduction of carbon dioxide and/or carbon monoxide, as well as an electrochemical cell including the electrode.

Abstract: The invention relates to a method for electrochemical production of a product in an electrochemical cell comprising an extraction compartment. The extraction compartment comprises a liquid comprising a dissolved polyelectrolyte. The method comprises producing cations at an anode, producing anions at a cathode and transporting the ions through ion-selective membranes into the extraction compartment where the product is formed. The invention further relates to an electrochemical cell for use in the method.

Abstract: A neutralizing composition comprising ascorbic acid as a reducing agent, citric acid as a chelator and a pH adjusting agent applied to microetched copper substrates bussed to stainless steel, which have been cleaned with an agent comprising permanganate ions. Unlike the prior art neutralizing agents comprising oxalic acid, which leave insoluble residue on the surface of the copper substrate, the present neutralizing composition leaves no residue and acts quickly. A surprising reduction in defects of Ni—Au plated copper substrates is achieved by utilization of the neutralization composition in a manufacturing process.

Abstract: The invention relates to a process for electrolysing carbon oxides selected from carbon monoxide and/or carbon dioxide into ethylene by means of an electrolyser comprising a cathode catalyst being a dendritic copper oxide catalyst or a dendritic copper catalyst.

Abstract: The current disclosure provides alternating current based systems and methods to develop chemical compounds, such as drug molecules using electrochemistry in organic synthesis.

Abstract: An electrochemical reaction device of an embodiment includes: an electrochemical reaction cell 1 that includes: a first electrode having a first flow path, a second electrode having a second flow path, and a separating membrane sandwiched between the first electrode and the second electrode; a liquid tank that contains a liquid to be treated supplied to the second flow path of the second electrode; a first pipe that connects an inlet of the second flow path and the liquid tank; a second pipe that connects an outlet of the second flow path and the liquid tank; and a backflow suppression mechanism that is provided in the second pipe to prevent backflow of the liquid to be treated flowing in the second pipe or reduce a backflow speed.

Abstract: A system and method for oxidizing organic molecules as an oxygen-atom source using an electrochemical process is described.