Abstract: Submerged combustion glass manufacturing systems include a melter having a floor, a roof, a wall structure connecting the floor and roof, and an exhaust passage through the roof. One or more submerged combustion burners are mounted in the floor and/or wall structure discharging combustion products under a level of material being melted in the melter and create turbulent conditions in the material. The melter exhausts through an exhaust structure connecting the exhaust passage with an exhaust stack. The exhaust structure includes a barrier defining an exhaust chamber having an interior surface, the exhaust chamber having a cross-sectional area greater than that of the exhaust stack but less than the melter. The barrier maintains temperature and pressure in the exhaust structure at values sufficient to substantially prevent condensation of exhaust material on the interior surface.

Abstract: Methods of melting particulate feedstocks in a submerged combustion melter employing an arrangement of one or more submerged combustion burners emitting combustion products into turbulent molten material. Operating the burners such that there is established a turbulent melting region extending vertically from the floor to a splash region, the splash region extending vertically between the turbulent melting region and a head space region, the head space region extending vertically between the splash region and the melter ceiling, the ceiling positioned above the floor a height H2. Feeding the particulate feedstock into the splash region through one or more inlet ports, the inlet ports positioned at a height H1 measured from the floor, where H1/H2 ranges from about 0.33 to about 0.67. The SCM may have a baffle extending from the ceiling into the splash region. A particulate feedstock conduit may be employed, having an exit port in the splash region.

Abstract: A melter apparatus includes a floor, a ceiling, and a wall connecting the floor and ceiling at a perimeter of the floor and ceiling, a melting zone being defined by the floor, ceiling and wall, the melting zone having a feed inlet and a molten glass outlet positioned at opposing ends of the melting zone. Melter apparatus include an exit end having a melter exit structure for discharging turbulent molten glass formed by one or more submerged combustion burners, the melter exit structure fluidly and mechanically connecting the melter vessel to a molten glass conditioning channel. The melter exit structure includes a fluid-cooled transition channel configured to form a frozen glass layer or highly viscous glass layer, or combination thereof, on inner surfaces of the fluid-cooled transition channel and thus protect the melter exit structure from mechanical energy imparted from the melter vessel to the melter exit structure.

Abstract: Fluid-cooled impingement burners have an external conduit and a first internal conduit substantially concentric therewith forming a first annulus for passing a cooling fluid. A second internal conduit forms a second annulus between the first and second internal conduits. A burner tip body defined by an inner wall, an outer wall, and a half-toroid crown, the inner wall connected to the first internal conduit, the outer wall connected to the external conduit, the inner wall defining a central flow passage for a combustible mixture. A third internal conduit generally concentric with the external conduit and positioned between the external and the first internal conduits, a first end of the third internal conduit extending into but not connecting with the half-toroid crown. A first end of the second internal conduit recessed is below the half-toroid crown, and the position of the first ends of the second and third internal conduits delay combustion of fuel with the oxidant.

Abstract: Feedstock supply structure apparatus, including an exhaust conduit fluidly and mechanically connectable to a structure defining a melting chamber, the exhaust conduit positioned at an angle to vertical ranging from 0 to about 90 degrees. The exhaust conduit may include a heat exchange substructure, or the conduit itself may serve as a heat exchanger. A feedstock supply structure fluidly connected to the exhaust conduit. Systems include a structure defining a melting chamber and an exhaust conduit fluidly connected to the structure. The exhaust conduit includes a heat exchange substructure for preheating the feedstock. Methods include supplying a granular or pellet-sized feedstock to the melter exhaust conduit, the exhaust conduit including the heat exchange substructure, and preheating the feedstock by indirect or direct contact with melter exhaust in the heat exchange substructure.

Abstract: Submerged combustion methods and systems including a melter equipped with an exhaust passage through the ceiling or the sidewall having an aggregate hydraulic diameter. Submerged combustion burners configured to create turbulent conditions in substantially all of the material being melted, and produce ejected portions of melted material. An exhaust structure including a liquid-cooled exhaust structure defining a liquid-cooled exhaust chamber having a cross-sectional area greater than that of the exhaust stack but less than the melter.

Abstract: Feedstock supply structure apparatus, including an exhaust conduit fluidly and mechanically connectable to a structure defining a melting chamber, the exhaust conduit positioned at an angle to vertical ranging from 0 to about 90 degrees. The exhaust conduit may include a heat exchange substructure, or the conduit itself may serve as a heat exchanger. A feedstock supply structure fluidly connected to the exhaust conduit. Systems include a structure defining a melting chamber and an exhaust conduit fluidly connected to the structure. The exhaust conduit includes a heat exchange substructure for preheating the feedstock. Methods include supplying a granular or pellet-sized feedstock to the melter exhaust conduit, the exhaust conduit including the heat exchange substructure, and preheating the feedstock by indirect or direct contact with melter exhaust in the heat exchange substructure.

Abstract: A melter apparatus includes a floor, a ceiling, and a wall connecting the floor and ceiling at a perimeter of the floor and ceiling, a melting zone being defined by the floor, ceiling and wall, the melting zone having a feed inlet and a molten glass outlet positioned at opposing ends of the melting zone. Melter apparatus include an exit end having a melter exit structure for discharging turbulent molten glass formed by one or more submerged combustion burners, the melter exit structure fluidly and mechanically connecting the melter vessel to a molten glass conditioning channel. The melter exit structure includes a fluid-cooled transition channel configured to form a frozen glass layer or highly viscous glass layer, or combination thereof, on inner surfaces of the fluid-cooled transition channel and thus protect the melter exit structure from mechanical energy imparted from the melter vessel to the melter exit structure.

Abstract: Submerged combustion glass manufacturing systems include a melter having a floor, a roof, a wall structure connecting the floor and roof, and an exhaust passage through the roof. One or more submerged combustion burners are mounted in the floor and/or wall structure discharging combustion products under a level of material being melted in the melter and create turbulent conditions in the material. The melter exhausts through an exhaust structure connecting the exhaust passage with an exhaust stack. The exhaust structure includes a barrier defining an exhaust chamber having an interior surface, the exhaust chamber having a cross-sectional area greater than that of the exhaust stack but less than the melter. The barrier maintains temperature and pressure in the exhaust structure at values sufficient to substantially prevent condensation of exhaust material on the interior surface.

Abstract: Apparatus, systems and methods for refining molten glass include a fining chamber having a refractory floor and a sidewall structure that may include a refractory liner, and includes an inlet transition region having increasing width from initial to a final width, and depth decreasing from an initial to final depth. The floor includes a raised curb having width equal to final width of the inlet transition region, curb length less than the length of the inlet transition region, and curb height forming a shallowest depth portion of the fining chamber. The raised curb separates the fining chamber into the inlet transition region and a primary fining region, the primary fining region defined by the refractory floor and sidewall structure. The primary fining region has a constant depth greater than the shallowest depth but less than the depth of the inlet transition region.

Abstract: Methods and systems produce a molten mass of foamed glass in a submerged combustion melter (SCM). Routing foamed glass to a fining chamber defined by a flow channel fluidly connected to and downstream of the SCM. The flow channel floor and sidewalls have sufficient glass-contact refractory to accommodate expansion of the foamed glass as fining occurs during transit through the fining chamber. The foamed glass is separated into an upper glass foam phase and a lower molten glass phase as the foamed glass flows toward an end of the flow channel distal from the SCM. The molten glass is then routed through a transition section fluidly connected to the distal end of the flow channel. The transition section inlet end construction has at least one molten glass inlet aperture, such that the inlet aperture(s) are positioned lower than the phase boundary between the upper and lower phases.

Abstract: Submerged combustion systems and methods of use to produce foamed glass. One system includes a submerged combustion melter having an outlet, the melter configured to produce an initial foamy molten glass having a density and comprising bubbles filled primarily with combustion product gases. The initial foamy molten glass is deposited directly onto or into a transport apparatus that transports the initial foamy molten glass to a downstream processing apparatus. An intermediate stage may be included between the melter and the transport apparatus. One intermediate stage is a channel that includes gas injectors. Another intermediate stage is a channel that produces an upper flow of a less dense glass and a relatively more dense glass lower flow. The upper flow may be processed into foamed glass products, while the more dense flow may be processed into dense glass products.

Abstract: Methods and systems for de-stabilizing foam produced in submerged combustion melters. A molten mass of glass and bubbles is flowed into an apparatus downstream of a submerged combustion melter. The downstream apparatus includes a floor, a roof and a wall connecting the floor and roof, but is devoid of submerged combustion burners and other components that would increase turbulence of the molten mass. The molten mass has foam on at least a portion of a top surface of the molten mass. Certain methods include imposing a de-stabilizing force directly to the foam or to the molten mass and foam, where the de-stabilizing force may be a vibratory force, an acoustic wave force, a particulate-based force, or a non-particulate-based mechanical force. Systems for carrying out the methods are described.

Abstract: A melter apparatus includes a floor, a ceiling, and a substantially vertical wall connecting the floor and ceiling at a perimeter of the floor and ceiling, a melting zone being defined by the floor, ceiling and wall, the melting zone having a feed inlet and a molten glass outlet positioned at opposing ends of the melting zone. The melting zone includes an expanding zone beginning at the inlet and extending to an intermediate location relative to the opposing ends, and a narrowing zone extending from the intermediate location to the outlet. One or more burners, at least some of which are positioned to direct combustion products into the melting zone under a level of molten glass in the zone, are also provided.

Abstract: Submerged combustion systems and methods of use to produce glass. One system includes a submerged combustion melter having a roof, a floor, a wall structure connecting the roof and floor, and an outlet, the melter producing an initial foamy molten glass. One or more non-submerged auxiliary burners are positioned in the roof and/or wall structure and configured to deliver combustion products to impact at least a portion of the bubbles with sufficient force and/or heat to burst at least some of the bubbles and form a reduced foam molten glass.

Abstract: Liquid is delivered into a void between a burner and a melt vessel, which causes a skull of a material to form within an interior of the melt vessel. The void is in fluidic communication with the interior of the melt vessel. The burner is moved from a first position internal to the void to a second position external from the void. Thereafter, the burner is isolated from the void.

Abstract: Methods of maximizing mixing and melting in a submerged combustion melter (SCM) are described. One method includes melting an inorganic feedstock in an SCM using an arrangement of two or more submerged combustion (SC) burners, the SCM having a length (L) and a width (W), a centerline (C), a north side (N) and a south side (S), and operating the arrangement of SC burners such that a progressively higher percentage of a total combustion flow from the SC burners occurs from SC burners at progressively downstream positions in the SCM. Other methods include operating the N and S SC burners with more combustion flow than the central burners. Other methods include strategic placement of fuel lean SC burners and fuel rich SC burners.

Abstract: A submerged combustion melter includes a floor, a roof, and a sidewall structure connecting the floor and roof defining an internal space. A first portion of the internal space defines a melting zone, and a second portion defines a fining zone immediately downstream of the melting zone. One or more combustion burners in either the floor, roof, the sidewall structure, or any combination of these, are configured to emit the combustion gases from a position under a level of, and positioned to transfer heat to and produce, a turbulent molten mass of glass containing bubbles in the melting zone. The fining zone is devoid of combustion burners or other apparatus or components that would increase turbulence above that in the melting zone. The melter may include a treating zone that stabilizes or destabilizes bubbles and/or foam. Processes of using the melters are a feature of the disclosure.

Abstract: Feedstock supply structure apparatus, including an exhaust conduit fluidly and mechanically connectable to a structure defining a melting chamber, the exhaust conduit positioned at an angle to vertical ranging from 0 to about 90 degrees. The exhaust conduit may include a heat exchange substructure, or the conduit itself may serve as a heat exchanger. A feedstock supply structure fluidly connected to the exhaust conduit. Systems include a structure defining a melting chamber and an exhaust conduit fluidly connected to the structure. The exhaust conduit includes a heat exchange substructure for preheating the feedstock. Methods include supplying a granular or pellet-sized feedstock to the melter exhaust conduit, the exhaust conduit including the heat exchange substructure, and preheating the feedstock by indirect or direct contact with melter exhaust in the heat exchange substructure.

Abstract: Channel apparatus for use with submerged combustion systems and methods of use to produce glass. One channel apparatus includes a flow channel defined by a floor, a roof, and a wall structure connecting the floor and roof, the flow channel divided into sections by a series of skimmers. Channel apparatus include both high and low momentum combustion burners, with one or more high momentum combustion burners positioned immediately upstream of each skimmer in either the roof or sidewall structure, or both, and one or more low momentum combustion burners positioned immediately downstream of each skimmer in either the roof, the sidewall structure, or both, and positioned to transfer heat to the molten mass of glass without substantial interference from foamed material. Certain embodiments include increased height of glass-contact refractory, in particular immediately upstream of the skimmers.