Abstract: Compositions, structures and methods are described that improve fire retardant characteristics of various material, and which can be used for protecting structures, devices, or components therein. In one example, a mixture suitable for imparting heat or cold blocking properties to an object is produced. The mixture includes a catalyst comprising particles that are 8 microns or less in diameter, a charring agent comprising particles that are 8 microns or less in diameter, and a blowing agent comprising particles that are 8 microns or less in diameter. The catalyst, the charring agent and the blowing agent are mixed together in equal portions by weight to produce the mixture suitable for imparting heat or cold blocking properties to an object.