Abstract: According to a novel process, the triazolinethione derivative of the formula can be prepared by a) reacting the oxirane of the formula  with hydrazine hydrate in the presence of specific diluents, followed by introduction of hydrogen chloride or extraction with aqueous hydrochloric acid, b) treating the resulting hydrazine hydrochloride derivative of the formula  with alkali metal hydroxide in the presence of water and further specific diluents, followed by successive reaction with formaldehyde and thiocyanate of the formula X—SCN  (IV)  in the presence of certain solvents and finally c) reacting the triazolidine derivative of the formula  with iron(III) chloride in the presence of aqueous hydrochloric acid.

Abstract: The invention relates to a process for preparing N-(5-amino-2-cyano-4-fluoro-phenyl)-sulphonamides in which, in a first step, 2-amino-4,5-difluoro-benzonitrile is reacted with sulphonyl halides in the presence of an acid acceptor and in the presence of a diluent at temperatures between 0° C. and 150° C. and, in a second step, the N-(2-cyano-4,5-difluoro-phenyl)-sulphonamides and/or N-(2-cyano-4,5-difluoro-phenyl)-sulphonimides obtained in the first step are as pure substances or as mixtures with ammonia in the presence of a diluent reacted at a temperature between 100° C. and 200° C. The invention furthermore relates to novel intermediates of the process.

Abstract: The invention relates to a process for preparing N-(5-amino-2-cyano-4-fluoro-phenyl)-sulphonamides in which, in a first step, 2-amino-4,5-difluoro-benzonitrile is reacted with sulphonyl halides in the presence of an acid acceptor and in the presence of a diluent at temperatures between 0° C. and 150° C. and, in a second step, the N-(2-cyano-4,5-difluoro-phenyl)-sulphonamides and/or N-(2-cyano-4,5-difluoro-phenyl)-sulphonimides obtained in the first step are as pure substances or as mixtures with ammonia in the presence of a diluent reacted at a temperature between 100° C. and 200° C. The invention furthermore relates to novel intermediates of the process.

Abstract: The invention relates to a novel process for preparing 1-amino-3-aryluracils of the formula (I) 1

Abstract: The invention relates to a novel process for preparing N-substituted 2,4-diamino-5-fluoro-benzonitriles which are known as intermediates in the preparation of herbicides, to novel N-substituted 4-bromo-6-fluoro-1,3-phenylenediamines, to novel N-substituted 2-bromo-4-fluoro-5-nitro-anilines and to novel N-substituted 2-bromo-4-fluoro-anilines as intermediates for this process, and to processes for their preparation.

Abstract: According to a novel process, the triazolinethione derivative of the formula 1

Abstract: The invention relates to a process for preparing 2,4,5-trifluoro-benzonitrile of the formula (I) in which 2,4,5-trifluoro-aniline of the formula (II) is, in a first step A), reacted with a nitrosating agent in the presence of a diluent and in which, in a second step B), the reaction product obtained in step A) is reacted with an alkali metal cyanide in the presence of a transition metal compound, an acid acceptor and a diluent.

Abstract: According to a novel process, it is possible to prepare triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description by a) reacting hydrazine derivatives of the formula  with carbonyl compounds of the formula in which R3 and R4 are each as defined in the description with potassium thiocyanate, sodium thiocyanate or ammonium thiocyanate, if appropriate in the presence of a diluent and if appropriate in the presence of an acid, and b) reacting the resulting triazolidinethione derivatives of the formula  with formic acid, if appropriate in the presence of a catalyst and if appropriate in the presence of a diluent. The triazolidinethione derivatives of the formula (V) are novel.

Abstract: According to a novel process, it is possible to prepare triazolinethione derivatives of the formula 1

Abstract: According to a novel process, it is possible to prepare triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description by a) reacting hydrazine derivatives of the formula  or their acid addition salts with an inorganic or organic acid with thiocyanate of the formula Y-SCN  (III)  in which Y represents sodium, potassium or ammonium in the presence of a diluent and, if appropriate, in the presence of a catalyst and b) reacting the resulting thiosemicarbazide derivatives of the formula  with formic acid, if appropriate in the presence of a catalyst and if appropriate in the presence of a diluent. The thiosemicarbazide derivatives of the formula (IV) are novel.

Abstract: According to a novel process, it is possible to prepare triazolinethione derivatives of the formula 1

Abstract: The invention relates to a process for preparing N-(5-amino-2-cyano-4-fluoro-phenyl)-sulphonamides in which, in a first step, 2-amino-4,5-difluoro-benzonitrile is reacted with sulphonyl halides in the presence of an acid acceptor and in the presence of a diluent at temperatures between 0° C. and 150° C. and, in a second step, the N-(2-cyano-4,5-difluoro-phenyl)-sulphon-amides and/or N-(2-cyano-4,5-difluoro-phenyl)-sulphonamides obtained in the first step are as pure substances or as mixtures with ammonia in the presence of a diluent reacted at a temperature between 100° C. and 200° C. The invention furthermore relates to novel intermediates of the process.

Abstract: According to a novel process, it is possible to prepare triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description by a) reacting hydrazine derivatives of the formula  with carbonyl compounds of the formula  in which R3 and R4 are each as defined in the description  with potassium thiocyanate, sodium thiocyanate or ammonium thiocyanate,  if appropriate in the presence of a diluent and if appropriate in the presence of an acid, and b) reacting the resulting triazolidinethione derivatives of the formula  with formic acid, if appropriate in the presence of a catalyst and if appropriate in the presence of a diluent. The triazolidinethione derivatives of the formula (V) are novel.

Abstract: According to a novel process, it is possible to prepare triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description by a) reacting hydrazine derivatives of the formula or their acid addition salts with an inorganic or organic acid with thiocyanate of the formula Y—SCN  (III) in which Y represents sodium, potassium or ammonium in the presence of a diluent and, if appropriate, in the presence of a catalyst and b) reacting the resulting thiosemicarbazide derivatives of the formula with formic acid, if appropriate in the presence of a catalyst and if appropriate in the presence of a diluent. The thiosemicarbazide derivatives of the formula (IV) are novel.

Abstract: The invention relates to a process for preparing N-(3-amino-4-fluoro-phenyl)-sulphonamides, N-(3-amino-4-fluoro-phenyl)-carboxamides or N-(3-amino-4-fluoro-phenyl)-carbamates of the general formula (I) in which A represents SO2, CO or CO2 and R represents in each case optionally substituted alkyl or aryl, wherein 1-fluoro-2,4-diamino-benzene of the formula (II) is reacted with sulphonyl chlorides, carbonyl chlorides or chlororformic esters of the general formula (III)  in which A and R are as defined above in the presence of an acid acceptor and in the presence of a diluent at temperatures between −20° C. and +100° C.

Abstract: The application describes a process for preparing 4-hydroxyanilines by the reaction of phenols with diazonium salts and subsequent reduction.