Patents by Inventor Adolf Asbeck

Adolf Asbeck has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5306442
    Abstract: A mixture of C.sub.16 -C.sub.28 alkyl glucosides (A) and C.sub.16 -C.sub.28 fatty alcohols (B) in a weight ratio (A):(B) of between 20:1 and 1:9 possesses foam inhibiting properties even when highly diluted. The mixture is suitable for use in the food industry, and is preferably employed in a chemically inert liquid carrier oil that is immiscible with water.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: April 26, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karlheinz Hill, Adolf Asbeck, Karl Heinz Schmid
  • Patent number: 4981893
    Abstract: Compounds corresponding to the following formulaR.sub.1 --(CH.sub.2).sub.m --O--(CH.sub.2 CH.sub.2).sub.n --R.sub.2in which R.sub.1 is the phenyl radical or a phenyl radical which is substituted by linear or branched alkyl radicals containing a total of from 1 to 18 carbon atoms, R.sub.2 is a C.sub.4 -C.sub.8 alkyl radical, m=0 or 1 and n=3 to 30, are used as dispersants with foam-inhibiting properties in aqueous polymer dispersions and latices.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: January 1, 1991
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Hoefer, Karl-Heinz Schmid, Adolf Asbeck, Uwe Held
  • Patent number: 4965019
    Abstract: Foam-depressing additives comprising polyethyleneglycol ethers of formula IR.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2 (I)in which R.sup.1 represents a straight-chain or branched alkyl radical with 6 to 13 carbon atoms, R.sup.2 represents an alkyl radical with 1 to 3 carbon atoms and n is a number from 2 to 6, for low-foam, preferably sprayable cleaning agents.
    Type: Grant
    Filed: January 10, 1989
    Date of Patent: October 23, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Heinz Schmid, Alfred Meffert, Gilbert Schenker, Adolf Asbeck, Juergen Geke
  • Patent number: 4954283
    Abstract: The invention is cleaning compositions containing Polyethylene-glycol ethers of the formulaR.sub.1 --(CH.sub.2 CH.sub.2 O).sub.n --R.sub.2 (1)in whichR.sub.1 is a straight-chain or branched alkyl- or alkenyl radical having from 20 to 28 carbon atomsR.sub.2 is an alkyl radical having from 4 to 8 carbon atoms and n is an integer from about 6 to about 20as a foam-suppressing additive. The cleaning compositions are stable over a broad temperature range and having low foaming characteristics particularly at about ambient temperatures.
    Type: Grant
    Filed: January 11, 1989
    Date of Patent: September 4, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl H. Schmid, Alfred Meffert, Gilbert Schenker, Adolf Asbeck, Rolf Scharf
  • Patent number: 4942049
    Abstract: Terminally blocked polyethoxylated fatty alcohols of the formula:R--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.1 (I)wherein R is a linear or branched alkyl or alkenyl group having from 6 to 28 carbon atoms, R.sub.1 is a linear alkyl group having from 1 to 8 carbon atoms, and n is an integer having a value of from 2 to 12 are used as anti-foaming additives in the manufacture and/or processing of food stuffs as well as in fermentation processes.
    Type: Grant
    Filed: January 11, 1989
    Date of Patent: July 17, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl H. Schmid, Alfred Meffert, Gilbert Schenker, Adolf Asbeck
  • Patent number: 4937011
    Abstract: Alkaline dishwashing machine detergent compositions containing an active chlorine composition and a foam inhibiting amount of a ketone containing at least 25 carbon atoms. A process for their preparation wherein the ketone is introduced into the composition as a dispersion in a liquid.
    Type: Grant
    Filed: January 11, 1989
    Date of Patent: June 26, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Heinz Schmid, Adolf Asbeck, Christoph Breucker, Bernhard Gutsche, Alfred Meffert, Horst Rutzen
  • Patent number: 4932994
    Abstract: An evaporation inhibitor, having particular use with spray mixtures of agricultural chemicals applied by the low-volume method, in the form of a paraffin-containing aqueous dispersion or a self-emulsifying solution in an organic solvent, and having the following composition:______________________________________ from 15 to 40% by weight of paraffin waxes or a wax mixture containing paraffin waxes having a dropping point of from 35 to 80.degree. C., from 4 to 20% by weight of nonionic and/or anionic emulsifiers, from 35 to 81% by weight of water and/or an organic solvent which is one or more of a hydrocarbon, an ester and a ketone, which have boiling points of from 70 to 280.degree. C., and from 0 to 5.5% by weight of other auxiliaries.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: June 12, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Josef Koester, Adolf Asbeck, Holger Tesmann, Margarete Gruenert, Konrad Albrecht, Paul Bittner, Fritz Keim
  • Patent number: 4891154
    Abstract: Substantially water-insoluble silicic acid esters corresponding to the following general formula ##STR1## are used to foam inhibitors in foaming systems. In the above formula, X and Y represent the group --OR or a methyl group, R represents a polypropylene glycol ether group and, optionally, a polyethylene glycol ether group which may be substituted by alkoxyl, amino-alkyl, acyl, acylamino, dialkoxyl and oxyaminoalkyl groups containing from 4 to 24 carbon atoms. The total number of glycol ether groups amounts to between 1 and 100, the number of polypropylene glycol ether groups preferably being at least equal to or larger than the number of ethylene glycol ether groups.
    Type: Grant
    Filed: June 11, 1987
    Date of Patent: January 2, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Holger Tesmann, Hans U. Hempel, Heinz Mueller, Margarete Gruenert, Adolf Asbeck
  • Patent number: 4853145
    Abstract: Aqueous low-foam cleaning compositions containing at least one surfactant which is a water-soluble or water-emulsifiable polyalkylene glycol ether of a long-chain alcohol, and at least one diethanolamine derivative of the formula ##STR1## in which R.sub.1 and R.sub.2 are linear or branched alkyl or alkenyl radicals containing 8 to 14 carbon atoms for R.sub.1 and 9 to 17 carbon atoms for R.sub.2, andr, s, t, u, v and w are integers of from 1 to 3.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: August 1, 1989
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Heinz Schmid, Adolf Asbeck, Detlev Stanislowski
  • Patent number: 4797222
    Abstract: A foam inhibitor mixture of compounds corresponding to the following formulae: ##STR1## in which R represents a glycerol residue, trimethylol ethane residue, trimethylol propane residue or a polyglycerol residue having a degree of polymerization x of from 2 to 6 and the indices y=(x-z+2), z=(x-y+2), a=1 to 15, b=50 to 250, c=1 to 15, d=50 to 250 and e=1 to 15, with the proviso that the sums (a+c+e)=2 to 20, (b+d)=50 to 250 and (c+e)=1 to 15 and y has a value of at least 1; R.sup.1 represents a straight-chain or branched-chain alkyl or alkenyl radical containing from 8 to 20 C-atoms or an aromatic alkyl radical containing from 12 to 20 C-atoms, R.sup.2 represents an alkyl radical containing from 3 to 8 C-atoms and n is a number of from 4 to 30. The mixture preferably contains from 99 to 70% by weight of the block polymer (I) and from 1 to 30% by weight of the emulsifier (II).
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: January 10, 1989
    Assignee: Henkel Kommaditgesellschaft auf Aktien
    Inventors: Rainer Hoefer, Karl H. Schmid, Adolf Asbeck, Uwe Held
  • Patent number: 4780237
    Abstract: Low-foam or foam-depressing surfactant mixtures based on water-soluble and/or water-emulsifiable polyalkylene glycol ethers of relatively long-chain alcohols containing components I, II and, if desired, III in the quantities indicated:(I) from 20 to 80% by weight of polyethylene glycol ethers corresponding to the following general formulaR.sub.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sub.2 (I)in which R.sub.1 is a straight-chain or branched C.sub.8 -C.sub.18 alkyl or alkenyl radical, R.sub.2 is a C.sub.4 -C.sub.8 alkyl radical and n is a number of from 3 to 7,(II) from 10 to 40% by weight of alkyl polyalkylene glycol mixed ethers corresponding to the following general formula ##STR1## in which R.sub.3 is a straight-chain or branched C.sub.8 -C.sub.18 alkyl radical, x is a number of from 1 to 3 and y is a number of from 3 to 6, and(III) from 0 to 40% by weight of alkyl (poly)propylene glycol ethers corresponding to the following general formula ##STR2## in which R.sub.4 is a straight-chain or branched C.sub.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: October 25, 1988
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Heinz Schmid, Adolf Asbeck, Detlev Stanislowski
  • Patent number: 4745231
    Abstract: Block polymers usable as defoamers have the following formula ##STR1## in which R represents a glycerol or polyglycerol function having a degree of polymerization x of from 1 to 6 and the indices y is equal to (x-z+2), z is equal to (x-y+2), a is equal to 1 to 15, b is equal to 50 to 200 c is equal to 1 to 15, d is equal to 20 to 150 and e is equal to 1 to 15, with the proviso that the sums (a+c+e) is equal to 2 to 20, (b+d) is equal to 50 to 250 and (c+e) is equal to 1 to 15, and y has a value of at least 1.The block polymers are prepared by reaction of glycerol or polyglycerol having a degree of polymerization x with ethylene oxide, then with propylene oxide and, finally, again with ethylene oxide, preferably in the presence of alkaline etherification catalysts.
    Type: Grant
    Filed: August 6, 1986
    Date of Patent: May 17, 1988
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Fritz Lange, Rainer Hoefer, Karl-Heinz Schmid, Adolf Asbeck, Klaus Herrmann
  • Patent number: 4655960
    Abstract: The formation of troublesome microfoams in aqueous lacquer and synthetic resin dispersions, particularly in gloss lacquers, is prevented by the addition of from about 0.01 to about 1.5% by weight of a silicone-free foam inhibitor mixture. This mixture consists of (a) from about 70 to about 98% by weight of a mineral oil liquid at room temperature or a mixture of such mineral oil with a C.sub.16 -C.sub.30 branched alcohol of the following formulaR.sup.1 --CH.sub.2 --CH.sub.2 --CHR.sup.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 OH (I)in which R.sup.1 and R.sup.2 are C.sub.4 -C.sub.16 alkyl radicals, (b) from about 0.2 to about 5% by weight of a microcrystalline wax, (c) from about 0.5 to about 20% by weight of hard paraffin, (d) from 0.05 to 5% by weight of hydrophobized finely divided silica, and (e) from 0 to about 10% by weight of a soft paraffin (M.p. 32.degree.-42.degree. C.). Component (a) preferably consists of a mixture of mineral oil and branched alcohol (I) in a ratio of from 50:1 to 1:1.
    Type: Grant
    Filed: January 2, 1985
    Date of Patent: April 7, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Juan C. Wuhrmann, Heinz Mueller, Karl-Dieter Brands, Adolf Asbeck, Jochen Heidrich
  • Patent number: 4655961
    Abstract: The formation of troublesome microfoams in aqueous lacquer and synthetic resin dispersions, particularly in gloss lacquers, is prevented by the addition of from 0.01 to 1.5% by weight of a silicone-free foam inhibitor mixture. These foam inhibitor mixtures contain (a) from 70 to 98% by weight of a liquid, branched C.sub.16 -C.sub.30 alcohol, (b) from 0.5 to 20% by weight of hard paraffin, and (c) from 0.05 to 5% by weight of hydrophobized finely divided silica, and, optionally, small quantities of other ingredients.
    Type: Grant
    Filed: January 2, 1985
    Date of Patent: April 7, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Juan C. Wuhrmann, Heinz Mueller, Karl-Dieter Brands, Adolf Asbeck, Jochen Heidrich
  • Patent number: 4622303
    Abstract: Troublesome foaming in the fermentation of yeast is suppressed by the addition of polyglycol ethers which are derived from saturated and monounsaturated C.sub.16 -C.sub.18 fatty alcohols and which contain on an average of from 1 to 4 ethylene and/or propylene glycol ether groups. Preferred defoamers contain oleyl and cetyl alcohol residues in a ratio of from 3:1 to 1:1, and on average 2 ethylene glycol ether groups. The defoamers do not inhibit yeast growth or lead to premature softening and liquefaction of the compressed yeast.
    Type: Grant
    Filed: January 29, 1985
    Date of Patent: November 11, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Joachim Schindler, Adolf Asbeck
  • Patent number: 4299975
    Abstract: Sulfosuccinic acid derivatives having the formula: ##STR1## where R.sub.1 is a member selected from the group consisting of hydrogen and alkyl having from 1 to 16 carbon atoms, R.sub.2 is alkyl having from 1 to 16 carbon atoms, and the sum of the carbon atoms in R.sub.1 and R.sub.2 is from 9 to 16, R.sub.3 is a member selected from the group consisting of hydrogen and methyl, M.sub.1 and M.sub.2 are cations selected from the group consisting of alkali metals, ammonium, alkylammonium having 1 to 4 carbon atoms in the alkyl and alkylolammonium having 2 to 4 carbon atoms in the alkylol and m is an integer from 1 to 10. These sulfosuccinic acid derivatives are useful as emulsifying agents, particularly in the production of freeze-stable emulsion polymers.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: November 10, 1981
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Adolf Asbeck, Michael Eckelt, Werner Erwied, Rudi Heyden, Manfred Petzold
  • Patent number: 4260686
    Abstract: The present invention concerns a process for the softening of furs while at the same time taking the greatest possible care of the appearance of the hair. The process of this invention comprises contacting a fur with an acid aqueous liquor containing an acid protease from a fungus strain of the genus Rhizopus rhizopodiformis, said acid protease being effective in the pH range of from about 2.5 to 6.5.
    Type: Grant
    Filed: August 17, 1979
    Date of Patent: April 7, 1981
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Adolf Asbeck, Hans F. Pfeiffer, Juergen Plapper, Rolf Schmid
  • Patent number: 4250050
    Abstract: Sulfosuccinic acid derivatives having the formula: ##STR1## wherein R is a member selected from the group consisting of: ##STR2## where R.sub.1 and R.sub.2 are members selected from the group consisting of hydrogen and alkyl having from 1 to 16 carbon atoms, and the sum of the carbon atoms in R.sub.1 and R.sub.2 is from from 9 to 16, R.sub.3 is a member selected from the group consisting of hydrogen and methyl, R.sub.4 is alkyl having 1 to 5 carbon atoms, M.sub.1 and M.sub.2 are cations selected from the group consisting of alkali metals, ammonium, alkylammonium having 1 to 4 carbon atoms in the alkyl and alkylolammonium having 2 to 4 carbon atoms in the alkylol and m is an integer from 1 to 10. These sulfosuccinic acid derivatives are useful as emulsifying agents, particularly in the production of emulsion polymers.
    Type: Grant
    Filed: December 30, 1977
    Date of Patent: February 10, 1981
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Adolf Asbeck, Michael Eckelt, Werner Erwied, Rudi Heyden, Manfred Petzold
  • Patent number: 4132694
    Abstract: Method for improving the latent gloss of latex paints comprising incorporating therein liquid antifoam dispersions based on antifoam waxes containing a 1:1/2-3:1/2-4 molar ratio castor oil: ethylene oxide: propylene oxide adduct, which acts as fortifying agent for the first-mentioned wax.
    Type: Grant
    Filed: December 9, 1976
    Date of Patent: January 2, 1979
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Rudi Heyden, Adolf Asbeck, Michael Eckelt, Wolfgang Gress
  • Patent number: 4127512
    Abstract: Foam inhibitor compositions comprising a mixture of(A) at least one monoester of a saturated fatty acid having 18 to 26 carbon atoms with an alkanediol having 16 to 20 carbon atoms, and(B) at least one carboxylic acid amide of the formula ##STR1## WHEREIN R.sub.1 and R.sub.2 are saturated, linear or branched hydrocarbon radicals having 10 to 26 carbon atoms, and m and n are integers from 0 to 2 with the sum of m + n being an integer from 1 to 4, the weight ratio of component A to component B being from 5:1 to 1:5; as well as low-foaming washing agent compositions containing at least 0.2% by weight of said foam inhibitor composition together with at least one surface-active compound and at least one inorganic or organic builder salt.
    Type: Grant
    Filed: August 3, 1976
    Date of Patent: November 28, 1978
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rudi Heyden, Michael Eckelt, Adolf Asbeck, Jurgen Hoffmeister, Edmund Schmadel