Abstract: Methods for making a substrate comprising structured organic film nano- to micro-features are disclosed. The methods for forming SOF micro-features may include: providing a substrate; discharging at least one droplet toward the substrate by an ink jet method, the at least one droplet including a plurality of molecular building blocks each comprising a segment and a number of functional groups; depositing the at least one droplet on the substrate; promoting a change in the deposited at least one droplet and forming at least one dry structured organic film (SOF) on the substrate.

Abstract: A porous structured organic film including a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein at a macroscopic level the covalent organic framework is a film and contains a plurality of sites accessible to one or more entity.