Abstract: A method of generating hydrogen in a subsurface formation, the method comprising injecting oxidizable metal particles into a subsurface formation comprising subsurface water and a geologic trap, wherein the subsurface water has a temperature of from 18° C. to 400° C. and a pressure of from 500 psi to 10,000 psi, the geologic trap comprises one or both of a structural trap or a stratigraphic trap, the geologic trap substantially prevents vertical migration of the subsurface water out of the subsurface formation, and the oxidizable metal particles react with the subsurface water to form hydrogen, metal oxides, metal hydroxides, or combinations thereof.

Abstract: Compositions, methods, and systems for treating a subterranean formation for carbon dioxide sequestration include introducing a ferrate(VI)-based hydraulic fracturing fluid into a subterranean formation. The ferrate(VI)-based hydraulic fracturing fluid comprises ferrate(VI) oxidizing agent having the formula M2FeO4, where M is an alkali metal or an alkaline earth metal, and an aqueous carrier fluid. Reacting the ferrate(VI) oxidizing agent with a surface of the subterranean formation increases a pore volume of pores therein and interacting the ferrate(VI) oxidizing agent with carbon dioxide (CO2) sequesters the CO2 with the ferrate(VI) oxidizing agent within the pores.

Abstract: Hydrogen may be produced by a method that includes a first reaction where methane is reacted with carbon dioxide to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

Abstract: Hydrogen may be produced by a method that includes a first reaction where methane is reacted with water to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

Abstract: Hydrogen may be produced by a method that includes a first reaction where methane is reacted with oxygen to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

Abstract: Compositions, methods, and systems for treating a subterranean formation for carbon dioxide sequestration, including introducing a ferrate(VI)-based hydraulic fracturing fluid into a subterranean formation. The ferrate(VI)-based hydraulic fracturing fluid comprises ferrate(VI) oxidizing agent having the formula M2FeO4, where M is an alkali earth metal or an alkaline earth metal, and an aqueous carrier fluid. Reacting the ferrate(VI) oxidizing agent with a surface of the subterranean formation so as to increase a pore volume of pores therein and interacting the ferrate(VI) oxidizing agent with carbon dioxide (CO2), so as to sequester the CO2 with the ferrate(VI) oxidizing agent within the pores.

Abstract: The present disclosure relates to methods for preparing a poly(crown ether). The present disclosure also relates to poly(crown ether)s prepared according to such methods.

Abstract: Disclosed herein are supramolecular porous organic nanocomposites for heterogenous photocatalysis as well as methods of making and using the same. The nanocomposite comprises an admixture of a polymeric matrix and a macrocycle.