Abstract: A cathodic arc coating system includes alternating layers of at least one of titanium vanadium nitride (TiVN) and titanium silicon vanadium nitride (TiSiVN) disposed on a substrate; and alternating layers of titanium vanadium chromium nitride (TiVCrN) and titanium silicon vanadium nitride (TiSiVCrN) disposed on a substrate. A cathodic arc process includes a sub-hertz variable bias forming the alternating layers of alternating layers of at least one of titanium vanadium nitride (TiVN) and titanium silicon vanadium nitride (TiSiVN) disposed on a substrate; and alternating layers of titanium vanadium chromium nitride (TiVCrN) and titanium silicon vanadium nitride (TiSiVCrN) disposed on a substrate.

Abstract: Methods of protecting a metallic substrate from corrosion include introducing an aqueous or powder-form composition including at least one corrosion inhibitor into a crevice that traverses one or more layers covering the metallic substrate to deliver the composition via the crevice into contact with a surface of the metallic substrate. The corrosion inhibitors present in the composition bond to the surface of the metallic substrate, resulting in formation of a film on the surface of the metallic substrate. This film protects the surface of the metallic substrate against corrosion.