Abstract: This process enables the recovery of mercury from waste containing plastic material, e.g. batteries. The waste is slowly heated while an inert gas is being introduced in a vacuum for fractionating extraction of the products of the decomposition of the plastic. The waste gases must pass through an afterburner chamber incorporating a specially shaped burner where the plastic vapors are fully combusted. The waste gases are conducted from the afterburner chamber through a cooling trap and then through a cold trap in which the mercury is condensed and can be drained off. The final stage of the process is carried out in a pulsating vacuum by the inert gas.The device in which the process takes place consists of a heated heat isolated treatment chamber (2), an afterburner chamber (6), a cooling trap (7), a cold trap (18) and a vacuum pump (23, 24) connected with pipelines (5, 12, 21).