Abstract: A zinc anode can is formed of a zinc based alloy material including 0.004-0.800 wt % of indium, 0.001-0.25 wt % of titanium or 0.002-0.500 wt % of zirconium, without containing significant amounts of harmful substances such as mercury, cadmium, or lead, is provided. A method of manufacturing of such zinc anode can enabling addition of up to 0.800 wt % of indium includes hot rolling of the zinc base alloy in a temperature range of 270-370.degree. C. A manganese dry battery includes a separator on which is coated a paste having 0.1-8 wt % of InCl.sub.3. The separator is disposed on the inner surface of the zinc can. An interior of the separator is filled with a cathode mixture containing conductive carbonaceous material such as manganese dioxide, and acetylene black and electrolyte with a ZnCl.sub.2 concentration of 35-50 wt %. A carbon rod as a collector is inserted into the center of the cathode mixture.

Abstract: A gel form negative electrode of an alkaline battery is produced without mercury and enables uniform dispersion of zinc or zinc alloy powder and an effective metal which can be one or more of an oxide or hydroxide of indium, lead, gallium, bismuth. The zinc or zinc alloy powder and the effective metal are drymixed in advance of mixing with a gel form alkaline electrolyte. In order to obtain satisfactorily high vibration strength and impact resistance, fiber material can be added to the gel form negative electrode. The fiber material may be selected among rayon, vinylon, acryl, vinyon, polyamide, polypropylene, polyethylene, mercerized pulp, linter pulp.

Abstract: A method for producing a gel form negative electrode of an alkaline battery while avoiding use of mercury enables uniform dispersion of zinc or zinc alloy powder and an effective metal which can be one or more of an oxide or hydroxide of indium, lead, gallium, bismuth, by stirring for a substantially reduced period. The method employs dry mixing of the zinc or zinc alloy powder and the effective metal in advance of mixing with a gel form alkaline electrolyte. Also, in order to obtain satisfactorily high vibration strength and impact resistance, fiber material can be added to the gel form negative electrode. The fiber material may be selected among rayon, vinylon, acryl, vinyon, polyamide, polypropylene, polyethylene, mercerized pulp, linter pulp.