Patents by Inventor Akihisa Kajiyama

Akihisa Kajiyama has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11492266
    Abstract: Provided herein are processes for producing positive electrode active substance particles for non-aqueous electrolyte secondary batteries which is excellent in life characteristics of a battery with respect to a repeated charging and discharging performance thereof, as well as a non-aqueous electrolyte secondary battery. In particular, provided herein are processes for producing a positive electrode active substance for non-aqueous electrolyte secondary batteries comprising lithium transition metal layered oxide having a composition represented by the formula: Lia(NixCoyMn1-x-y)O2 wherein a is 1.0?a?1.15; x is 0<x<1; and y is 0<y<1, in which the positive electrode active substance is in the form of secondary particles formed by aggregating primary particles thereof, and a coefficient of variation of a compositional ratio: Li/Me wherein Me is a sum of Ni, Co and Mn as measured on a section of the secondary particle is not more than 25%.
    Type: Grant
    Filed: October 25, 2019
    Date of Patent: November 8, 2022
    Assignee: TODA KOGYO CORP.
    Inventors: Akihisa Kajiyama, Ryuta Masaki, Tsuyoshi Wakiyama, Tetsuya Kashima, Shoichi Fujino, Osamu Sasaki, Kazutoshi Matsumoto
  • Patent number: 11434421
    Abstract: A phosphor which has a main crystal phase having the same crystal structure as that of CaAlSiN3, wherein the phosphor satisfies conditions of a span value (d90?d10)/d50 of 1.70 or less and a d50 of 10.0 ?m or less, as represented with d10, d50, and d90 on a volume frequency measured according to a laser diffraction method; wherein the d10, d50, and d90 on a volume frequency in a particle distribution measured are each a measured by loading 0.5 g of a phosphor into 100 ml of a solution of 0.05% by weight of sodium hexametaphosphate mixed in ion exchange water, and subjecting the resultant to a dispersing treatment for 3 minutes with an ultrasonic homogenizer at an oscillation frequency of 19.5±1 kHz, a chip size of 20?, and an amplitude of vibration of 32±2 ?m, with a chip placed at a central portion.
    Type: Grant
    Filed: August 22, 2019
    Date of Patent: September 6, 2022
    Assignee: DENKA COMPANY LIMITED
    Inventors: Kazuya Sugita, Yusuke Takeda, Keita Kobayashi, Akihisa Kajiyama
  • Patent number: 11377594
    Abstract: A ?-type sialon phosphor represented by the following expression 1, in which D50 is 10 ?m or less, and values of D10, D50, and D90 satisfy a relationship of the following expression 2 with respect to D10, D50, and D90 (each unit is [?m]) on a volume frequency basis as measured according to a laser diffraction/scattering method. Expression 1: Si12-aAlaObN16-b:Eux (wherein 0<a?3; 0<b?3; 0<x?0.1), expression 2: (D90?D10)/D50<1.6 (wherein the D10, D50, and D90 (each unit is [?m]) on a volume frequency basis as measured according to the laser diffraction/scattering method.
    Type: Grant
    Filed: August 22, 2019
    Date of Patent: July 5, 2022
    Assignee: DENKA COMPANY LIMITED
    Inventors: Keita Kobayashi, Shunsuke Mitani, Ryousuke Kondo, Kazuya Sugita, Takuya Matsufuji, Akihisa Kajiyama
  • Publication number: 20210324267
    Abstract: A phosphor which has a main crystal phase having the same crystal structure as that of CaAlSiN3, wherein the phosphor satisfies conditions of a span value (d90?d10)/d50 of 1.70 or less and a d50 of 10.0 ?m or less, as represented with d10, d50, and d90 on a volume frequency measured according to a laser diffraction method; wherein the d10, d50, and d90 on a volume frequency in a particle distribution measured are each a measured by loading 0.5 g of a phosphor into 100 ml of a solution of 0.05% by weight of sodium hexametaphosphate mixed in ion exchange water, and subjecting the resultant to a dispersing treatment for 3 minutes with an ultrasonic homogenizer at an oscillation frequency of 19.5±1 kHz, a chip size of 20?, and an amplitude of vibration of 32±2 ?m, with a chip placed at a central portion.
    Type: Application
    Filed: August 22, 2019
    Publication date: October 21, 2021
    Applicant: DENKA COMPANY LIMITED
    Inventors: Kazuya SUGITA, Yusuke TAKEDA, Keita KOBAYASHI, Akihisa KAJIYAMA
  • Patent number: 11072869
    Abstract: The present invention provides a precursor of positive electrode active substance particles for non-aqueous electrolyte secondary batteries which have a high discharge voltage and a high discharge capacity, hardly suffer from side reactions with an electrolyte solution, and are excellent in cycle characteristics, positive electrode active substance particles for non-aqueous electrolyte secondary batteries, and processes for producing these particles, and a non-aqueous electrolyte secondary battery.
    Type: Grant
    Filed: August 8, 2018
    Date of Patent: July 27, 2021
    Assignee: TODA KOGYO CORPORATION
    Inventors: Hiroyasu Watanabe, Daisuke Morita, Manabu Yamamoto, Kazumichi Koga, Akihisa Kajiyama, Hiroaki Masukuni, Hideaki Sadamura, Ryuta Masaki, Kazutoshi Matsumoto
  • Publication number: 20210189234
    Abstract: A ?-type sialon phosphor represented by the following expression 1, in which D50 is 10 ?m or less, and values of D10, D50, and D90 satisfy a relationship of the following expression 2 with respect to D10, D50, and D90 (each unit is [?m]) on a volume frequency basis as measured according to a laser diffraction/scattering method. Expression 1: Si12-aAlaObN16-b:Eux (wherein 0<a?3; 0<b?3; 0<x?0.1), expression 2: (D90?D10)/D50<1.6 (wherein the D10, D50, and D90 (each unit is [?m]) on a volume frequency basis as measured according to the laser diffraction/scattering method.
    Type: Application
    Filed: August 22, 2019
    Publication date: June 24, 2021
    Applicant: DENKA COMPANY LIMITED
    Inventors: Keita KOBAYASHI, Shunsuke MITANI, Ryousuke KONDO, Kazuya SUGITA, Takuya MATSUFUJI, Akihisa KAJIYAMA
  • Patent number: 11018339
    Abstract: A positive electrode active material comprises a Li-transition metal-layered oxide represented by the formula: Lia(NibCocAldMee)O2 (in which Me=Mn, Mg, Ti, Ru, Zr, Nb, Mo, W; 1.00?a?1.15; 0.25<b<1; 0<c?0.30; 0?d?0.05; 0?e?0.40), and is constituted of secondary particles formed by aggregation of primary particles. As to a compositional ratio of Li which is derived from unreacted substances or decomposed products in the secondary particles, a variation coefficient (Standard deviation value/Average value) of a Li-compositional ratio: Li/M (M=Ni+Co+Al+Me) is 30% or less. The positive electrode active material hardly deteriorates even if repeatedly charged/discharged, and enables stable charge/discharge, and then a non-aqueous electrolyte secondary battery is enabled to have an excellent output property and a long lifetime.
    Type: Grant
    Filed: October 1, 2018
    Date of Patent: May 25, 2021
    Assignee: BASF TODA Battery Materials LLC
    Inventors: Akihisa Kajiyama, Kazumichi Koga, Tsuyoshi Wakiyama, Ryuta Masaki, Takayuki Yamamura, Kazutoshi Matsumoto
  • Publication number: 20200058934
    Abstract: Provided positive electrode active substance particles for non-aqueous electrolyte secondary batteries which is excellent in life characteristics of a battery with respect to a repeated charging and discharging performance thereof, as well as a non-aqueous electrolyte secondary battery. A positive electrode active substance for non-aqueous electrolyte secondary batteries comprising lithium transition metal layered oxide having a composition represented by the formula: Lia(NixCoyMn1-x-y)O2 wherein a is 1.0•a•1.15; x is 0<x<1; and y is 0<y<1, in which the positive electrode active substance is in the form of secondary particles formed by aggregating primary particles thereof, and a coefficient of variation of a compositional ratio: Li/Me wherein Me is a sum of Ni, Co and Mn (Me=Ni+Co+Mn) as measured on a section of the secondary particle is not more than 25%.
    Type: Application
    Filed: October 25, 2019
    Publication date: February 20, 2020
    Inventors: Akihisa KAJIYAMA, Ryuta MASAKI, Tsuyoshi WAKIYAMA, Tetsuya KASHIMA, Shoichi FUJINO, Osamu SASAKI, Kazutoshi MATSUMOTO
  • Publication number: 20190157667
    Abstract: The present invention relates to lithium composite oxide particles which can be produced by mixing nickel-cobalt-manganese-based compound particles, a zirconium raw material and a lithium raw material with each other and then calcining the resulting mixture, and comprise a Zr compound that is allowed to be present on a surface thereof, in which the Zr compound is represented by the chemical formula: Lix(Zr1-yAy)Oz wherein x, y and z are 2.0?x?8.0; 0?y?1.0; and 2.0?z?6.0, respectively, and a content of Zr in the lithium composite oxide particles is 0.05 to 1.0% by weight. By using the lithium composite oxide particles as a positive electrode active substance, it is possible to produce a lithium ion secondary battery that has a low electric resistance at a high temperature, and is excellent in cycle characteristic at a high temperature as well as high-temperature rate characteristic.
    Type: Application
    Filed: December 18, 2018
    Publication date: May 23, 2019
    Inventors: Minoru Yamazaki, Osamu Sasaki, Shoichi Fujino, Hideharu Mitsui, Takayuki Yamamura, Kunihiro Uramatsu, Akihisa Kajiyama, Ryuta Masaki
  • Publication number: 20190115596
    Abstract: A positive electrode active material comprises a Li-transition metal-layered oxide represented by the formula: Lia(NibCocAldMee)O2 (in which Me=Mn, Mg, Ti, Ru, Zr, Nb, Mo, W; 1.00?a?1.15; 0.25<b<1; 0<c?0.30; 0?d?0.05; 0?e?0.40), and is constituted of secondary particles formed by aggregation of primary particles. As to a compositional ratio of Li which is derived from unreacted substances or decomposed products in the secondary particles, a variation coefficient (Standard deviation value/Average value) of a Li-compositional ratio: Li/M (M=Ni+Co+Al+Me) is 30% or less. The positive electrode active material hardly deteriorates even if repeatedly charged/discharged, and enables stable charge/discharge, and then a non-aqueous electrolyte secondary battery is enabled to have an excellent output property and a long lifetime.
    Type: Application
    Filed: October 1, 2018
    Publication date: April 18, 2019
    Inventors: Akihisa KAJIYAMA, Kazumichi KOGA, Tsuyoshi WAKIYAMA, Ryuta MASAKI, Takayuki YAMAMURA, Kazutoshi MATSUMOTO
  • Patent number: 10193141
    Abstract: An object of the present invention is to provide a positive electrode mixture capable of conducting stable charging and discharging with a less amount of gasses generated which has an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium. The present invention relates to a positive electrode mixture comprising carbon black having a bulk density of not more than 0.1 g/cm3, a crystallite size of 10 to 40 ?, an iodine adsorption of 1 to 150 mg/g, a volatile content of not more than 0.1% and a metal impurity content of not more than 20 ppm, and a positive electrode active substance having an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium.
    Type: Grant
    Filed: February 24, 2015
    Date of Patent: January 29, 2019
    Assignees: TODA KOGYO CORPORATION, DENKA COMPANY LIMITED
    Inventors: Akihisa Kajiyama, Teruaki Santoki, Daisuke Morita, Ryuta Masaki, Takahiko Sugihara, Tsuyoshi Wakiyama, Kazutoshi Matsumoto, Akira Yoda, Taro Inada, Hiroshi Yokota, Takashi Kawasaki
  • Patent number: 10161057
    Abstract: The present invention provides a precursor of positive electrode active substance particles for non-aqueous electrolyte secondary batteries which have a high discharge voltage and a high discharge capacity, hardly suffer from side reactions with an electrolyte solution, and are excellent in cycle characteristics, positive electrode active substance particles for non-aqueous electrolyte secondary batteries, and processes for producing these particles, and a non-aqueous electrolyte secondary battery.
    Type: Grant
    Filed: December 26, 2011
    Date of Patent: December 25, 2018
    Assignee: TODA KOGYO CORPORATION
    Inventors: Hiroyasu Watanabe, Daisuke Morita, Manabu Yamamoto, Kazumichi Koga, Akihisa Kajiyama, Hiroaki Masukuni, Hideaki Sadamura, Ryuta Masaki, Kazutoshi Matsumoto
  • Publication number: 20180347068
    Abstract: The present invention provides a precursor of positive electrode active substance particles for non-aqueous electrolyte secondary batteries which have a high discharge voltage and a high discharge capacity, hardly suffer from side reactions with an electrolyte solution, and are excellent in cycle characteristics, positive electrode active substance particles for non-aqueous electrolyte secondary batteries, and processes for producing these particles, and a non-aqueous electrolyte secondary battery.
    Type: Application
    Filed: August 8, 2018
    Publication date: December 6, 2018
    Inventors: Hiroyasu WATANABE, Daisuke MORITA, Manabu YAMAMOTO, Kazumichi KOGA, Akihisa KAJIYAMA, Hiroaki MASUKUNI, Hideaki SADAMURA, Ryuta MASAKI, Kazutoshi MATSUMOTO
  • Publication number: 20180026265
    Abstract: In accordance with the present invention, there are provided positive electrode active substance particles for non-aqueous electrolyte secondary batteries which is excellent in life characteristics of a battery with respect to a repeated charging and discharging performance thereof, as well as a non-aqueous electrolyte secondary battery. The present invention relates to a positive electrode active substance for non-aqueous electrolyte secondary batteries comprising lithium transition metal layered oxide having a composition represented by the formula: Lia(NixCoyMn1-x-y)O2 wherein a is 1.0?a?1.15; x is 0<x<1; and y is 0<y<1, in which the positive electrode active substance is in the form of secondary particles formed by aggregating primary particles thereof, and a coefficient of variation of a compositional ratio: Li/Me wherein Me is a sum of Ni, Co and Mn (Me=Ni+Co+Mn) as measured on a section of the secondary particle is not more than 25%.
    Type: Application
    Filed: February 15, 2016
    Publication date: January 25, 2018
    Inventors: Akihisa KAJIYAMA, Ryuta MASAKI, Tsuyoshi WAKIYAMA, Tetsuya KASHIMA, Shoichi FUJINO, Osamu SASAKI, Kazutoshi MATSUMOTO
  • Patent number: 9847526
    Abstract: According to the present invention, there are provided lithium titanate particles which exhibit an excellent initial discharge capacity and an enhanced high-efficiency discharge capacity retention rate as an active substance for non-aqueous electrolyte secondary batteries and a process for producing the lithium titanate particles, and Mg-containing lithium titanate particles.
    Type: Grant
    Filed: February 9, 2016
    Date of Patent: December 19, 2017
    Assignee: TODA KOGYO CORPORATION
    Inventors: Akinori Yamamoto, Tomoko Okita, Hiroshi Yamamoto, Kohji Mori, Kazumichi Koga, Akihisa Kajiyama
  • Publication number: 20160372740
    Abstract: An object of the present invention is to provide a positive electrode mixture capable of conducting stable charging and discharging with a less amount of gasses generated which has an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium. The present invention relates to a positive electrode mixture comprising carbon black having a bulk density of not more than 0.1 g/cm3, a crystallite size of 10 to 40 ?, an iodine adsorption of 1 to 150 mg/g, a volatile content of not more than 0.1% and a metal impurity content of not more than 20 ppm, and a positive electrode active substance having an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium.
    Type: Application
    Filed: February 24, 2015
    Publication date: December 22, 2016
    Inventors: Akihisa KAJIYAMA, Teruaki SANTOKI, Daisuke MORITA, Ryuta MASAKI, Takahiko SUGIHARA, Tsuyoshi WAKIYAMA, Kazutoshi MATSUMOTO, Akira YODA, Taroh INADA, Hiroshi YOKOTA, Takashi KAWASAKI
  • Patent number: 9515315
    Abstract: The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries, comprising an oxide having a spinel structure and comprising at least Li and Mn as main components and an oxide comprising at least Li and Zr, in which the oxide comprising at least Li and Zr forms a mixed phase comprising two or more phases, and a content of the oxide comprising at least Li and Zr in the positive electrode active substance particles is 0.1 to 4% by weight. The present invention provides positive electrode active substance particles for non-aqueous electrolyte secondary batteries which are excellent in high-temperature characteristics and a process for producing the positive electrode active substance particles, and a non-aqueous electrolyte secondary battery.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: December 6, 2016
    Assignee: TODA KOGYO CORP.
    Inventors: Kazumichi Koga, Ryuta Masaki, Akihisa Kajiyama, Hiroaki Masukuni
  • Patent number: 9496551
    Abstract: The present invention relates to lithium manganate particles having a primary particle diameter of not less than 1 ?m and an average particle diameter (D50) of not less than 2 ?m and not more than 10 ?m as measured by a particle size distribution meter, and forming particles having substantially a single phase, which have a composition represented by the following chemical formula: Li1+xMn2?x?yY1yO4+Y2 where Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is at least one element constituting a sintering aid having a melting point of not higher than 800° C., x and y satisfy 0.03?x?0.15 and 0.05?y?0.20, respectively, and Y2 is present in an amount of 0.1 to 2.5 mol % based on Mn; the Y1 element being dispersed within the respective particles, and an X-ray diffraction intensity ratio of I(400)/I(111) of the particles being not less than 38% and an X-ray diffraction intensity ratio of I(440)/I(111) thereof being not less than 18%.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: November 15, 2016
    Assignee: TODA KOGYO CORPORATION
    Inventors: Kazumichi Koga, Masayuki Uegami, Akihisa Kajiyama, Kazutoshi Ishizaki, Hideaki Sadamura
  • Publication number: 20160164086
    Abstract: According to the present invention, there are provided lithium titanate particles which exhibit an excellent initial discharge capacity and an enhanced high-efficiency discharge capacity retention rate as an active substance for non-aqueous electrolyte secondary batteries and a process for producing the lithium titanate particles, and Mg-containing lithium titanate particles.
    Type: Application
    Filed: February 9, 2016
    Publication date: June 9, 2016
    Inventors: Akinori YAMAMOTO, Tomoko OKITA, Hiroshi YAMAMOTO, Kohji MORI, Kazumichi KOGA, Akihisa KAJIYAMA
  • Publication number: 20160126547
    Abstract: The present invention relates to lithium manganate particles for non-aqueous electrolyte secondary batteries, having a spinel structure, an average primary particle diameter of 0.4 to 1.8 ?m and an average secondary particle diameter (D50) of 8 to 20 ?m, a ratio of the average secondary particle diameter (D50) to the average primary particle diameter (D50/average primary particle diameter) being in the range of 10 to 30, and pore diameters of pores in the lithium manganate particles as measured by a mercury intrusion porosimetry method being in the range of 100 to 500 nm, and a process for producing the lithium manganate particles, and a non-aqueous electrolyte secondary battery. The lithium manganate particles according to the present invention are excellent in high-temperature storage characteristics.
    Type: Application
    Filed: November 12, 2013
    Publication date: May 5, 2016
    Inventors: Kazumichi KOGA, Hiroaki MASUKUNI, Akihisa KAJIYAMA, Masayuki UEGAMI, Kazutoshi MATSUMOTO