Patent number: 5725791
Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.
Type:
Grant
Filed:
August 9, 1993
Date of Patent:
March 10, 1998
Assignee:
E. I. du pont de Nemours and Company
Inventors:
Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
Patent number: 5648017
Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
July 15, 1997
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Philip Lee Bartlett, Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
Patent number: 5635099
Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane, along with their use as refrigerants.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
June 3, 1997
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Donald B. Bivens, Mark B. Shiflett, Akimichi Yokozeki
Patent number: 5616276
Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane, along with their use as refrigerants.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
April 1, 1997
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Donald B. Bivens, Mark B. Shiflett, Akimichi Yokozeki
Patent number: 5277834
Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane,along with their use as refrigerants.
Type:
Grant
Filed:
December 22, 1992
Date of Patent:
January 11, 1994
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Donald B. Bivens, Mark B. Shiflett, Akimichi Yokozeki