Patents by Inventor Akinobu Hayakawa

Akinobu Hayakawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11387421
    Abstract: The present invention aims to provide a solar cell having high durability against deterioration due to moisture ingress from the side surfaces. The solar cell 10 of the present invention includes: first and second electrodes 12 and 17; a perovskite layer 14 provided between the first and second electrodes 12 and 17 and containing an organic-inorganic perovskite compound (A) represented by the formula RMX3 where R is an organic molecule, M is a metal atom, and X is a halogen atom; and a side-surface-protecting layer 15 provided on a peripheral side of the perovskite layer 14 to coat at least part of a side surface of the perovskite layer 14, the side-surface-protecting layer 15 containing at least one selected from the group consisting of a metal halide (B1) and an organometal halide (B2) or containing an organohalide (C).
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: July 12, 2022
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventors: Yuuichirou Fukumoto, Naohiro Fujinuma, Junichiro Anzai, Akinobu Hayakawa, Tetsuya Kurebayashi, Tetsuya Aita, Tomohito Uno
  • Patent number: 11335514
    Abstract: The present invention aims to provide a solar cell that includes a photoelectric conversion layer containing an organic-inorganic perovskite compound and that can exhibit high photoelectric conversion efficiency and high heat resistance. Provided is a solar cell including, in the stated order: a cathode; a photoelectric conversion layer; and an anode, the photoelectric conversion layer containing an organic-inorganic perovskite compound represented by the formula R-M-X3 where R is an organic molecule, M is a metal atom, and X is a halogen atom or a chalcogen atom, and a polymer having an acid dissociation constant pKa of 3 or less.
    Type: Grant
    Filed: September 20, 2018
    Date of Patent: May 17, 2022
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu Hayakawa, Tetsuya Kurebayashi, Naohiro Fujinuma, Masako Okamoto
  • Publication number: 20220140269
    Abstract: The present invention aims to provide a solar cell having high photoelectric conversion efficiency that is less likely to decrease even under prolonged application of a voltage.
    Type: Application
    Filed: March 16, 2020
    Publication date: May 5, 2022
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Takurou OKUMURA, Takeshi FUKUDA
  • Publication number: 20220140267
    Abstract: The present invention aims to provide a photoelectric conversion element having high photoelectric conversion efficiency, a method for producing the photoelectric conversion element, and a solar cell including the photoelectric conversion element. Provided is a photoelectric conversion element containing a perovskite compound represented by the formula AMX wherein A represents an organic base compound and/or an alkali metal, M represents a lead or tin atom, and X is a halogen atom, the photoelectric conversion element having an intensity ratio of a nitrate ion to a halogen ion (NO3/X) of 0.0010 or more and less than 0.2000 as determined by TOF-SIMS measurement.
    Type: Application
    Filed: March 25, 2020
    Publication date: May 5, 2022
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Masako OKAMOTO, Takamichi SHINOHARA, Shun ORII, Akinobu HAYAKAWA
  • Publication number: 20210288277
    Abstract: The present invention aims to provide a flexible solar cell having excellent high-temperature, high-humidity durability and excellent initial performance. The present invention relates to a flexible solar cell including, on a flexible substrate: an electrode; a transparent electrode; and a photoelectric conversion layer disposed between the electrode and the transparent electrode, the photoelectric conversion layer containing an organic-inorganic perovskite compound, the flexible substrate including an aluminum foil and an aluminum oxide film formed on the aluminum foil, the flexible substrate having a ratio of the thickness of the aluminum oxide film to the total thickness of the aluminum foil and the aluminum oxide film of 0.1% or higher and 15% or lower.
    Type: Application
    Filed: September 27, 2017
    Publication date: September 16, 2021
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Mayumi YUKAWA, Tomohito UNO, Motohiko ASANO, Yuuichirou FUKUMOTO, Tetsuya KUREBAYASHI, Tetsuya AlTA, Takeharu MORITA
  • Patent number: 11101079
    Abstract: The present invention aims to provide a solar cell in which a decrease in photoelectric conversion efficiency due to continuous exposure to light (photodegradation) is reduced, and a method of producing the solar cell.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: August 24, 2021
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu Hayakawa, Mayumi Horiki, Shunji Ohara, Tomohito Uno
  • Publication number: 20200395494
    Abstract: The present invention aims to provide a method for producing a solar cell in which a continuous long scribed line is provided along the machine direction of a substrate so that failures due to breakage of the scribed line are reduced.
    Type: Application
    Filed: March 13, 2019
    Publication date: December 17, 2020
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Tetsuya AITA, Motohiko ASANO, Akinobu HAYAKAWA, Tomohito UNO, Tetsuya KUREBAYASHI, Shunsuke KUNUGI, Takeharu MORITA
  • Publication number: 20200251674
    Abstract: The present invention aims to provide a solar cell excellent in photoelectric conversion efficiency, in which reduction in the photoelectric conversion efficiency due to continuous irradiation with light (photodegradation) is suppressed and the photoelectric conversion layer is less likely to suffer corrosion. The present invention provides a solar cell having a structure including: a cathode; an electron transport layer; a photoelectric conversion layer; and an anode stacked in the stated order, the photoelectric conversion layer including an organic-inorganic perovskite compound represented by the formula: R-M-X3 where R represents an organic molecule, M represents a metal atom, and X represents a halogen or chalcogen atom, the cathode being formed of a titanium material and having an oxide layer on at least one surface.
    Type: Application
    Filed: February 1, 2017
    Publication date: August 6, 2020
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Yuuichirou FUKUMOTO, Motohiko ASANO, Mayumi YUKAWA, Tomohito UNO, Tetsuya KUREBAYASHI
  • Publication number: 20200161060
    Abstract: The present invention aims to provide a solar cell that includes a photoelectric conversion layer containing an organic-inorganic perovskite compound and that can exhibit high photoelectric conversion efficiency and high heat resistance. Provided is a solar cell including, in the stated order: a cathode; a photoelectric conversion layer; and an anode, the photoelectric conversion layer containing an organic-inorganic perovskite compound represented by the formula R-M-X3 where R is an organic molecule, M is a metal atom, and X is a halogen atom or a chalcogen atom, and a polymer having an acid dissociation constant pKa of 3 or less.
    Type: Application
    Filed: September 20, 2018
    Publication date: May 21, 2020
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Tetsuya KUREBAYASHI, Naohiro FUJINUMA, Masako OKAMOTO
  • Publication number: 20200013974
    Abstract: The present invention aims to provide a solar cell having high durability against deterioration due to moisture ingress from the side surfaces. The solar cell 10 of the present invention includes: first and second electrodes 12 and 17; a perovskite layer 14 provided between the first and second electrodes 12 and 17 and containing an organic-inorganic perovskite compound (A) represented by the formula RMX3 where R is an organic molecule, M is a metal atom, and X is a halogen atom; and a side-surface-protecting layer 15 provided on a peripheral side of the perovskite layer 14 to coat at least part of a side surface of the perovskite layer 14, the side-surface-protecting layer 15 containing at least one selected from the group consisting of a metal halide (B1) and an organometal halide (B2) or containing an organohalide (C).
    Type: Application
    Filed: March 29, 2018
    Publication date: January 9, 2020
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Yuuichirou FUKUMOTO, Naohiro FUJINUMA, Junichiro ANZAI, Akinobu HAYAKAWA, Tetsuya KUREBAYASHI, Tetsuya AlTA, Tomohito UNO
  • Publication number: 20190379000
    Abstract: A first object of the present invention is to provide a solar cell having excellent photoelectric conversion efficiency and produced through a process including favorable scribing (e.g., mechanical patterning), and a method for producing the solar cell. A first aspect of the present invention provides a solar cell including, above a flexible substrate, an electrode, a transparent electrode, and a photoelectric conversion layer disposed between the electrode and the transparent electrode, the solar cell further including a hard film disposed between the flexible substrate and the electrode, the hard film containing a nitride, carbide, or boride, the nitride, carbide, or boride containing at least one element selected from the group consisting of titanium, zirconium, aluminum, silicon, magnesium, vanadium, chromium, molybdenum, tantalum, and tungsten.
    Type: Application
    Filed: March 2, 2018
    Publication date: December 12, 2019
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Tetsuya AITA, Akinobu HAYAKAWA, Motohiko ASANO, Mayumi YUKAWA, Tomohito UNO, Tetsuya KUREBAYASHI, Takeharu MORITA
  • Publication number: 20190198256
    Abstract: The present invention aims to provide a solar cell having high photoelectric conversion efficiency that is less likely to decrease even under application of a voltage for a long period of time. Provided is a solar cell including: a cathode; a photoelectric conversion layer; and an anode in the stated order, the photoelectric conversion layer including an organic-inorganic perovskite compound represented by the formula: R-M-X3 wherein R represents an organic molecule, M represents a metal atom, and X represents a halogen or chalcogen atom, the solar cell further including, between the photoelectric conversion layer and the anode layer, a diffusion prevention layer including at least one selected from the group consisting of: metal oxides, metal nitrides, and metal oxynitrides each containing a group 6 to 15 metal in the periodic table; and carbon.
    Type: Application
    Filed: September 20, 2017
    Publication date: June 27, 2019
    Applicant: SEKISUI CHEMICAL CO. LTD.
    Inventors: Akinobu HAYAKAWA, Mayumi YUKAWA, Tetsuya KUREBAYASHI, Tomohito UNO, Motohiko ASANO, Yuuichirou FUKUMOTO, Tetsuya AlTA, Takeharu MORITA
  • Patent number: 10297395
    Abstract: An object of the present invention is to provide a solar cell that is excellent in photoelectric conversion efficiency, suffers little degradation during encapsulation (initial degradation), has high-humidity durability, and is excellent in temperature cycle resistance. The present invention provides a solar cell including: a laminate having an electrode, a counter electrode, and a photoelectric conversion layer disposed between the electrode and the counter electrode; and an encapsulation material covering the counter electrode to encapsulate the laminate, the photoelectric conversion layer including an organic-inorganic perovskite compound represented by the formula: R-M-X3, R representing an organic molecule, M representing a metal atom, X representing a halogen atom or a chalcogen atom, the encapsulation material including a resin having at least one skeleton selected from the group consisting of polyisobutylene, polyisoprene, and polybutadiene.
    Type: Grant
    Filed: October 14, 2015
    Date of Patent: May 21, 2019
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu Hayakawa, Motohiko Asano, Tomohito Uno, Mayumi Horiki, Yuuichirou Fukumoto, Tetsuya Kurebayashi, Shunji Ohara
  • Publication number: 20180212086
    Abstract: The present invention aims to provide a solar cell having high photoelectric conversion efficiency and excellent high-temperature, high-humidity durability. The present invention relates to a solar cell including at least: a photoelectric conversion layer; a hole transport layer; and an anode, the hole transport layer being disposed between the photoelectric conversion layer and the anode, the hole transport layer containing a polymer containing a halogen atom and an organic semiconductor component (1), the polymer containing a halogen atom having a structure that contains a halogen atom and an electron-withdrawing group bonded to a hetero atom.
    Type: Application
    Filed: July 29, 2016
    Publication date: July 26, 2018
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Tetsuya KUREBAYASHI, Tetsuya AITA, Mayumi YUKAWA, Motohiko ASANO, Tomohito UNO, Akinobu HAYAKAWA, Takeharu MORITA, Yuuichirou FUKUMOTO
  • Publication number: 20180175222
    Abstract: The present invention aims to provide a solar cell having high photoelectric conversion efficiency and excellent high-temperature durability, and an organic semiconductor material. The present invention relates to a solar cell having: an electrode; a counter electrode; a photoelectric conversion layer disposed between the electrode and the counter electrode; and a hole transport layer disposed between the photoelectric conversion layer and the counter electrode, the hole transport layer containing an ionic compound that contains an organic semiconductor cation and a fluorine-containing compound anion, the hole transport layer having a metal concentration of 1,000 ppm or lower.
    Type: Application
    Filed: July 29, 2016
    Publication date: June 21, 2018
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Mayumi YUKAWA, Tomohito UNO, Motohiko ASANO, Yuuichirou FUKUMOTO, Tetsuya KUREBAYASHI
  • Publication number: 20180062096
    Abstract: The present invention aims to provide a solar cell excellent in high-temperature, high-humidity durability. The present invention aims to provide a solar cell including: a cathode; an anode; and a photoelectric conversion layer disposed between the cathode and the anode, the photoelectric conversion layer containing an organic-inorganic perovskite compound represented by the formula R-M-X3 where R is an organic molecule, M is a metal atom, and X is a halogen atom or a chalcogen atom, at least one of the cathode and the anode having a resin layer disposed thereon, the resin layer having an inorganic layer disposed thereon, the resin layer having a glass transition temperature of 70° C. or higher and 200° C. or lower, and having a coefficient of linear expansion of 9.0×10?6K?1 or greater and 1.5×10?4K?1 or smaller.
    Type: Application
    Filed: March 16, 2016
    Publication date: March 1, 2018
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Tomohito UNO, Akinobu HAYAKAWA, Shunji OHARA, Mayumi YUKAWA, Motohiko ASANO, Yuuichirou FUKUMOTO
  • Publication number: 20180040841
    Abstract: There is provided a solar cell which is excellent in gas barrier properties and in which the deterioration of wirings does not easily occur. The solar cell (1) comprises: a first electrode (2); a second electrode (7) arranged so as to face the first electrode (2); a photoelectric conversion layer (5) which is arranged between the first electrode (2) and the second electrode (7) and contains an organic-inorganic perovskite compound; a plurality of auxiliary wirings (8) provided on the second electrode (7); a resin layer (9) provided on the second electrode (7) so as to fill a space between the plurality of auxiliary wirings (8); and an inorganic layer (10) provided so as to cover the plurality of auxiliary wirings (8) and the resin layer (9).
    Type: Application
    Filed: March 17, 2016
    Publication date: February 8, 2018
    Inventors: Motohiko Asano, Akinobu Hayakawa, Yuuichirou Fukumoto, Shunji Ohara, Mayumi Yukawa, Tomohito Uno
  • Publication number: 20180040840
    Abstract: The present invention aims to provide a flexible solar cell including a photoelectric conversion layer that contains an organic-inorganic perovskite compound and being excellent in light resistance and photoelectric conversion efficiency. The present invention relates to a flexible solar cell having a structure including: a metal foil; an electron transport layer; a photoelectric conversion layer; a hole transport layer; and a transparent electrode stacked in the stated order, the photoelectric conversion layer containing an organic-inorganic perovskite compound represented by the formula: R-M-X3 where R represents an organic molecule, M represents a metal atom, and X represents a halogen atom or a chalcogen atom.
    Type: Application
    Filed: March 18, 2016
    Publication date: February 8, 2018
    Applicant: Sekisui Chemical Co., Ltd.
    Inventors: Akinobu HAYAKAWA, Motohiko ASANO, Shunji OHARA, Mayumi YUKAWA, Tomohito UNO, Junnosuke MURAKAMI
  • Publication number: 20180019066
    Abstract: The present invention aims to provide a solar cell in which a decrease in photoelectric conversion efficiency due to continuous exposure to light (photodegradation) is reduced, and a method of producing the solar cell.
    Type: Application
    Filed: January 29, 2016
    Publication date: January 18, 2018
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Mayumi HORIKI, Shunji OHARA, Tomohito UNO
  • Publication number: 20170309408
    Abstract: The present invention aims to provide a solar cell that is excellent in photoelectric conversion efficiency, suffers little degradation during encapsulation (initial degradation), and has excellent durability. The present invention relates to a solar cell including: a laminate having an electrode, a counter electrode, and a photoelectric conversion layer disposed between the electrode and the counter electrode; and an inorganic layer covering the counter electrode to encapsulate the laminate, the photoelectric conversion layer including an organic-inorganic perovskite compound represented by the formula: R-M-X3, R representing an organic molecule, M representing a metal atom, X representing a halogen atom or a chalcogen atom, the inorganic layer containing a metal oxide, a metal nitride, or a metal oxynitride.
    Type: Application
    Filed: October 14, 2015
    Publication date: October 26, 2017
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Akinobu HAYAKAWA, Motohiko ASANO, Tomohito UNO, Mayumi HORIKI, Yuuichirou FUKUMOTO, Tetsuya KUREBAYASHI, Shunji OHARA