Patents by Inventor Akio Koyama

Akio Koyama has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8999878
    Abstract: According to the present invention, an exhaust gas purifying catalyst is provided. The catalyst comprises a porous silica support comprising silica having a pore structure, and a perovskite-type composite metal oxide particle supported in the pore structure of the porous silica support. Further, the peak attributable to the space between silica primary particles is in the range of 3 to 100 nm in the pore distribution of the porous silica support.
    Type: Grant
    Filed: July 3, 2007
    Date of Patent: April 7, 2015
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 8574524
    Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.
    Type: Grant
    Filed: February 17, 2012
    Date of Patent: November 5, 2013
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Kohei Yoshida, Akio Koyama
  • Patent number: 8382905
    Abstract: Cellulose contained in plant fiber material is hydrolyzed with the use of a pseudo-molten cluster acid as a hydrolysis catalyst to produce saccharide, most of which is glucose. After the glucose is produced, the saccharide is precipitated with the use of an organic solvent, and the saccharide including a solidified saccharide during the hydrolysis and the precipitated saccharide is separated from residues and the cluster acid.
    Type: Grant
    Filed: April 25, 2008
    Date of Patent: February 26, 2013
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 8298983
    Abstract: A process for producing a composite metal oxide of an acidic metal oxide and a basic metal oxide, wherein the process comprises (a) providing an aqueous solution containing a colloidal particle of the acidic metal oxide and a salt of the basic metal, (b) adjusting the pH of the aqueous solution to a pH at which a part of the basic metal dissolves in the aqueous solution, the remaining of the basic metal precipitates as a hydroxide and has a positive zeta potential, and the colloidal particle of the acidic metal oxide is not dissolved and has a negative surface potential, and then maintaining this pH over a predetermined time to obtain a precursor of the composite metal oxide, and (c) drying and firing the precursor of the composite metal oxide obtained.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: October 30, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 8288310
    Abstract: An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2 in which Rh is supported as a catalyst metal preventing sintering of the support, raising the supporting efficiency, and raising the low temperature activity and a method of production of the same are provided. An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2, sintered under firing conditions where the as fired ZrO2 will substantially not be charged in a catalyst metal supporting treatment solution, in which Rh is supported as a catalyst metal in a particle state. The method of production includes a step of charging the support mainly comprised of ZrO2 fired under the above firing conditions by applying at least one treatment of an acid treatment and a base treatment and a step of dipping the charged state support in the catalyst supporting treatment solution including a colloid of Rh as the catalyst metal to make the Rh colloid be adsorbed on the support.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: October 16, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 8206671
    Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: June 26, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Kohei Yoshida, Akio Koyama
  • Publication number: 20120148469
    Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.
    Type: Application
    Filed: February 17, 2012
    Publication date: June 14, 2012
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinichi TAKESHIMA, Kohei YOSHIDA, Akio KOYAMA
  • Patent number: 8093931
    Abstract: In a semiconductor integrated circuit device generating internal power from external power, an abnormal operation may occur due to an indefinite state of a control signal when the external power is applied and the internal power rises. The semiconductor integrated circuit includes an internal power generating circuit, a control circuit receiving internal power and supplying a first control signal, and a power-on reset circuit generating a reset signal at rising of the internal power. When internal power rises, the reset signal masks an indefinite state of the first control signal supplied from the control circuit.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: January 10, 2012
    Assignee: Hitachi, Ltd.
    Inventors: Toshio Shinomiya, Akio Koyama, Yuji Yokoyama
  • Patent number: 8034743
    Abstract: To provide a method of production of an exhaust gas purification catalyst support preventing a drop in the heat resistance of alumina or other catalyst support due to the presence of titania and provided with a sulfur poisoning suppression action by titania and an exhaust gas purification catalyst support produced by the same. A method of production of an exhaust gas purification catalyst support comprising, in a basic solution, making alumina particles adsorb ammonium ions and then bringing titania sol into contact with the alumina particle so as to make the alumina particles adsorb the titania particles. An exhaust gas purification catalyst support where at least base points on the alumina particle surfaces adsorb titania particles and the pH does not rise when immersed in an ammonium nitrate solution.
    Type: Grant
    Filed: June 25, 2008
    Date of Patent: October 11, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7968490
    Abstract: A porous substance producing method for producing a porous substance; by holding particles for precursors of the porous substance in micelles or inverse micelles kept in a dispersed state in a solvent with a surfactant; by agglomerating the particles of the micelles or inverse micelles to each other; and by baking the agglomerated particles. The method comprises the step of agglomerating the particles of the micelles or inverse micelles to each other by performing a treatment to resolve the dispersed state of the micelles or inverse micelles containing the particles for the precursors, with the surfactant.
    Type: Grant
    Filed: July 11, 2005
    Date of Patent: June 28, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7915195
    Abstract: An exhaust gas purifying catalyst is disclosed, comprising a ceria-zirconia solid solution and an iron oxide dispersed and at least partially solid-dissolved in the ceria-zirconia solid solution. A process for producing the exhaust gas purifying catalyst of the present invention is also disclosed.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: March 29, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7910084
    Abstract: A compound oxide manufacturing method includes: dispersing micelles, in each of which an aqueous phase is formed, in an oil phase; producing primary particles of a precursor of compound oxide in the aqueous phases in the micelles; synthesizing secondary particles by causing the primary particles to aggregate; and causing the secondary particles to aggregate by breaking the dispersion state of the micelles, or by causing the micelles to coalesce. In particular, polarization is produced in each of the micelles with the use of a cation having an ionic radius larger than that of a metal ion at least when the secondary particles are synthesized in the micelles.
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: March 22, 2011
    Assignee: Toyota Jidoshi Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Publication number: 20100248957
    Abstract: To provide a method of production of an exhaust gas purification catalyst support preventing a drop in the heat resistance of alumina or other catalyst support due to the presence of titania and provided with a sulfur poisoning suppression action by titania and an exhaust gas purification catalyst support produced by the same. A method of production of an exhaust gas purification catalyst support comprising, in a basic solution, making alumina particles adsorb ammonium ions and then bringing titania sol into contact with the alumina particle so as to make the alumina particles adsorb the titania particles. An exhaust gas purification catalyst support where at least base points on the alumina particle surfaces adsorb titania particles and the pH does not rise when immersed in an ammonium nitrate solution.
    Type: Application
    Filed: June 25, 2008
    Publication date: September 30, 2010
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7790649
    Abstract: The present invention relates to a production process of an exhaust gas purifying catalyst, comprising impregnating a support with a solution containing a metal salt and then drying it to load a particle of the metal salt on the support, (a) wherein a base having a less tendency to adsorb and coordinate to the metal salt particle than ammonia is incorporated into the solution to make the solution basic, and thereby the metal salt particle is caused to have a negative zeta potential; or (b) wherein an acid and a base that adsorbs and coordinates to the metal salt particle are incorporated into the solution to make the solution acidic, and thereby the metal salt particle is caused to have a positive zeta potential.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: September 7, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7776783
    Abstract: A catalyst carrier and exhaust gas purification catalyst superior in sintering inhibiting effect of precious metal catalyst particles are provided, that is, a catalyst carrier for carrying a precious metal comprised of a composite oxide of an electron accepting element (La) having an electron accepting property of accepting electrons from a precious metal element by approach or contact with the precious metal element (Pt) and not changing in atomic valence in an oxidation reduction reaction and of another element (Si) and, further, an exhaust gas purification catalyst comprised of this catalyst carrier on which precious metal catalyst particles are carried.
    Type: Grant
    Filed: October 24, 2006
    Date of Patent: August 17, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7758840
    Abstract: A method for producing a compound, in which carrier particles are made to adsorb and carry carried fine particles having a diameter smaller than that of the carrier particles. The method is characterized by comprising: a first step of charging the carrier particles or their precursors to a potential inverse to that of the carried fine particles or their precursors to adsorb the carrier particles or their precursors; and a second step of synthesizing the carried fine particles hardly soluble or their precursors, and causing the carrier particles or their precursors immediately after or during the synthesization to adsorb the hardly soluble carried fine particles or their precursors.
    Type: Grant
    Filed: April 7, 2006
    Date of Patent: July 20, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Publication number: 20100176034
    Abstract: A powder separation apparatus and method are provided so as to be able to accurately separate a raw powder material. This apparatus has a container into which a raw powder material containing a heavy powder and a light powder, and medium particles having a larger particle size than the raw powder material, are supplied; a container shaker for shaking the container; and a gas blower unit for blowing a gas into an interior of a medium particle layer in the container to discharge the light powder with the gas to the outside of the medium particle layer.
    Type: Application
    Filed: February 8, 2007
    Publication date: July 15, 2010
    Applicant: MEIJI UNIVERSITY LEGAL PERSON
    Inventors: Masafumi Kikuchi, Akio Koyama, Kichinosuke Amimoto, Takao Nishishita, Yutaka Akahoshi, Kazuko Ito
  • Publication number: 20100126501
    Abstract: Cellulose contained in plant fiber material is hydrolyzed with the use of a pseudo-molten cluster acid as a hydrolysis catalyst to produce saccharide, most of which is glucose. After the glucose is produced, the saccharide is precipitated with the use of an organic solvent, and the saccharide including a solidified saccharide during the hydrolysis and the precipitated saccharide is separated from residues and the cluster acid.
    Type: Application
    Filed: April 25, 2008
    Publication date: May 27, 2010
    Inventors: Shinichi Takeshima, Akio Koyama
  • Publication number: 20100069232
    Abstract: An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2 in which Rh is supported as a catalyst metal preventing sintering of the support, raising the supporting efficiency, and raising the low temperature activity and a method of production of the same are provided. An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2, sintered under firing conditions where the as fired ZrO2 will substantially not be charged in a catalyst metal supporting treatment solution, in which Rh is supported as a catalyst metal in a particle state. The method of production includes a step of charging the support mainly comprised of ZrO2 fired under the above firing conditions by applying at least one treatment of an acid treatment and a base treatment and a step of dipping the charged state support in the catalyst supporting treatment solution including a colloid of Rh as the catalyst metal to make the Rh colloid be adsorbed on the support.
    Type: Application
    Filed: November 1, 2007
    Publication date: March 18, 2010
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7678733
    Abstract: A method for producing a heat-resisting compound oxide in which first oxide particles are made to carry second fine particles having near charging characteristics. Said first oxide particles or their precursors are caused, before said first oxide particles or their precursors are caused to adsorb said first oxide particles or their precursors, to adsorb a predetermined acid or base so that they may be charged inversely of said second fine particles or their precursors to be adsorbed thereby. Said first oxide particles are caused to adsorb said second fine particles through said acid or base and are sintered to carry the same.
    Type: Grant
    Filed: April 7, 2006
    Date of Patent: March 16, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama