Abstract: The purpose of the present invention is to provide a method and an apparatus for producing carbon nanotube aggregates to improve the contact efficiency between a source gas and catalysts, thereby enabling the efficient production of high-quality CNT aggregates. A method for producing carbon nanotube aggregates according to the disclosure is a method including a growth step of growing the carbon nanotube aggregates on substrates with catalysts on surfaces. In the growth step, a source gas supply step of forming a substrate layer by stacking the substrates at a lower portion of a growth furnace configured to perform the growth step, and supplying a source gas to the substrate layer through a plurality of gas injection ports arranged at the lower portion of the growth furnace, and an in-growth furnace stir and conveyance step of mechanically stirring and/or conveying the substrate layer are performed at least in part in an overlapping manner.

Abstract: A production method for growing a carbon nanotube assembly on a substrate having a catalyst on a surface thereof. In this production method, in each of a formation unit that carries out a formation step of reducing a catalyst on the substrate and a growth unit that carries out a growth step of growing a carbon nanotube assembly, the substrate is continuously being conveyed using conveyance units that convey the substrate by screw rotations. In carrying out the formation step and the growth step, these steps are carried out while the gas environments in these steps are prevented from mixing with each other.

Abstract: A carbon nanotube assembly satisfies at least one of the following conditions (1) to (3): (1) an FT-IR spectrum of a CNT dispersion obtained by dispersing the CNT assembly has a peak based on plasmon resonance of the CNTs in a wave number range of greater than 300 cm?1 and 2000 cm?1 or less; (2) the highest peak in a differential pore capacity distribution of the CNT assembly is located within a pore size range of more than 100 nm and less than 400 nm; and (3) a two-dimensional spatial frequency spectrum of an electronic micrographic image of the CNT assembly has at least one peak within a range of 1 ?m?1 or more and 100 ?m?1 or less.

Abstract: A catalyst-adhered body production method comprising an adhesion process for arranging a mixed liquid comprising a catalyst raw material and/or a catalyst carrier raw material and target particles in a container having a porous plate and adhering a catalyst and/or a catalyst carrier to the surface of target particles to obtain adherence-treated particles, an excess solution removal process for removing via the porous plate, at least a portion of excess solution comprising excess components which did not adhere to the adherence-treated particles from the container, to form a filled layer of the adherence-treated particles on the porous plate, and a drying process for drying the filled layer in the container.

Abstract: A manufacturing method for supported catalysts comprising a step A of forming a mixed layer having a catalyst component and a catalyst carrier component on at least a portion of the surface of a support body having a catalytic layer by bringing a mixed solution comprising a catalyst raw material and a catalyst carrier raw material into contact with the support body having a catalytic layer on the surface. Furthermore, such a manufacturing method for supported catalysts preferably comprises a step B in which the catalyst component is made to segregate to a surface of the mixed layer after step A.

Abstract: A method of producing a carbon nanostructure is provided that enables production of a high-quality carbon nanostructure with a high yield. The method of producing a carbon nanostructure includes supplying a feedstock gas to a catalyst and growing a carbon nanostructure by chemical vapor deposition. A gas X that is derived from the feedstock gas and that comes into contact with the catalyst contains a hydrocarbon A having at least one cyclopentadiene skeleton and a hydrocarbon B having at least one acetylene skeleton. A total volume concentration [A] of the hydrocarbon A is at least 0.06%.

Abstract: A method for producing a carbon nanostructure aggregate having a large external specific surface area and a carbon nanostructure aggregate are provided. The method for producing a carbon nanostructure aggregate comprises supplying a source gas to a catalyst to grow a carbon nanostructure aggregate comprising a plurality of carbon nanostructures by a chemical vapor deposition method, wherein a gas derived from the source gas and brought into contact with the catalyst comprises: as a hydrocarbon to serve as a carbon source, at least one of: a hydrocarbon A having at least one acetylene skeleton, a hydrocarbon B having at least one 1,3 -butadiene skeleton, a hydrocarbon C having at least one cyclopentadiene skeleton, and a hydrocarbon D having at least one allene skeleton, and carbon monoxide and carbon dioxide; and satisfies 0.01?[CO]/[C]?15 where [C] is a total volume concentration of carbon contained in the hydrocarbons A, B, C, and D, and [CO] is a volume concentration of carbon monoxide.

Abstract: An apparatus for producing an aligned carbon nanotube includes: at least one injection section including at least one injection hole from which a raw material gas is injected to a base substrate; an exhaust vent for exhausting the raw material gas; and an exhaust section including a plurality of exhaust vents, the plurality of exhaust vents being provided so as to be closer to the exhaust vent than a plurality of injection holes included in the at least one injection hole of the at least one injection section.

Abstract: A method of producing a carbon nanostructure is provided that enables production of a high-quality carbon nanostructure with a high yield. The method of producing a carbon nanostructure includes supplying a feedstock gas to a catalyst and growing a carbon nanostructure by chemical vapor deposition. A gas X that is derived from the feedstock gas and that comes into contact with the catalyst contains a hydrocarbon A having at least one cyclopentadiene skeleton and a hydrocarbon B having at least one acetylene skeleton. A total volume concentration [A] of the hydrocarbon A is at least 0.06%.

Abstract: An apparatus of the present invention for producing an aligned carbon nanotube includes: at least one injection section including at least one injection hole from which a raw material gas is injected to a base substrate; an exhaust vent for exhausting the raw material gas; and an exhaust section including a plurality of exhaust vents, the plurality of exhaust vents being provided so as to be closer to the exhaust vent than a plurality of injection holes included in the at least one injection hole of the at least one injection section.

Abstract: A method of producing a carbon nanostructure is provided that enables production of a high-quality carbon nanostructure with a high yield. The method of producing a carbon nanostructure includes supplying a feedstock gas to a catalyst and growing a carbon nanostructure by chemical vapor deposition. A gas X that is derived from the feedstock gas and that comes into contact with the catalyst contains a hydrocarbon A having at least one cyclopentadiene skeleton and a hydrocarbon B having at least one acetylene skeleton. A total volume concentration [A] of the hydrocarbon A is at least 0.06%.

Abstract: This method improves a carbon nanotube growth environment. In this method of manufacturing carbon nanotubes, the supply amount of catalyst activating material supplied in a carbon nanotube growing step is adjusted to the supply amount of catalyst activating material supplied at the time of maximum concentration of a gas component among multiple measurements made in the growing step, the gas component being at least one selected from the group consisting of hydrogen, methane, and ethane.

Abstract: Provided is a production apparatus (100) for continuously producing aligned carbon nanotube aggregates on a substrate supporting a catalyst while continuously transferring the substrate. The production apparatus (100) includes gas mixing prevention means (12, 13) for preventing gas present outside a growth furnace (3a) from flowing into the growth furnace (3a). The gas mixing prevention means (12, 13) includes a seal gas ejection section (12b, 13b) so that the seal gas does not flow into the growth furnace through the openings of the growth furnace. The production apparatus prevents the outside air from flowing into the production apparatus, uniformly controls, within a range suitable to production of CNTs, a concentration distribution(s) and a flow rate distribution(s) of a raw material gas and/or a catalyst activation material on the substrate, and does not disturb gas flow as much as possible in the growth furnace.

Abstract: An apparatus of the present invention for producing aligned carbon nanotube aggregates is an apparatus for producing aligned carbon nanotube aggregates, the apparatus being configured to grow the aligned carbon nanotube aggregate by: causing a catalyst formed on a surface of a substrate to be surrounded by a reducing gas environment constituted by a reducing gas; heating at least either the catalyst or the reducing gas; causing the catalyst to be surrounded by a raw material gas environment constituted by a raw material gas; and heating at least either the catalyst or the raw material gas, at least either an apparatus component exposed to the reducing gas or an apparatus component exposed to the raw material gas being made from a heat-resistant alloy, and having a surface plated with molten aluminum.

Abstract: The disclosed method of manufacturing carbon nanotubes includes the steps of growing CNTs on a substrate 12 and cleaning the inside of a growth furnace 13 by supplying a cleaning gas that contains water into the growth furnace 13. In the cleaning step, the cleaning is performed such that 0.7?(2[CO2]+[CO])/[H2]?1.3 is satisfied, where [H2], [CO2], and [CO] denote the concentrations of hydrogen, carbon dioxide, and carbon monoxide, respectively, in a gas within the growth furnace 13.

Abstract: The disclosed method of manufacturing carbon nanotubes includes the steps of growing CNTs on a substrate 12 and cleaning the inside of a growth furnace 13 by supplying a cleaning gas that contains water into the growth furnace 13. In the cleaning step, the cleaning is performed such that 0.7?(2[CO2]+[CO])/[H2]?1.3 is satisfied, where [H2], [CO2], and [CO] denote the concentrations of hydrogen, carbon dioxide, and carbon monoxide, respectively, in a gas within the growth furnace 13.

Abstract: A method of producing a carbon nanostructure is provided that enables production of a high-quality carbon nanostructure with a high yield. The method of producing a carbon nanostructure includes supplying a feedstock gas to a catalyst and growing a carbon nanostructure by chemical vapor deposition. A gas X that is derived from the feedstock gas and that comes into contact with the catalyst contains a hydrocarbon A having at least one cyclopentadiene skeleton and a hydrocarbon B having at least one acetylene skeleton. A total volume concentration [A] of the hydrocarbon A is at least 0.06%.

Abstract: An apparatus of the present invention for producing aligned carbon nanotube aggregates is an apparatus for producing aligned carbon nanotube aggregates, the apparatus being configured to grow the aligned carbon nanotube aggregate by: causing a catalyst formed on a surface of a substrate to be surrounded by a reducing gas environment constituted by a reducing gas; heating at least either the catalyst or the reducing gas; causing the catalyst to be surrounded by a raw material gas environment constituted by a raw material gas; and heating at least either the catalyst or the raw material gas, at least either an apparatus component exposed to the reducing gas or an apparatus component exposed to the raw material gas being made from a heat-resistant alloy, and having a surface plated with molten aluminum.

Abstract: Provided is a production apparatus (100) for continuously producing aligned carbon nanotube aggregates on a substrate supporting a catalyst while continuously transferring the substrate. The production apparatus (100) includes gas mixing prevention means (12, 13) for preventing gas present outside a growth furnace (3a) from flowing into the growth furnace (3a). The gas mixing prevention means (12, 13) includes a seal gas ejection section (12b, 13b) so that the seal gas does not flow into the growth furnace through the openings of the growth furnace. The production apparatus prevents the outside air from flowing into the production apparatus, uniformly controls, within a range suitable to production of CNTs, a concentration distribution(s) and a flow rate distribution(s) of a raw material gas and/or a catalyst activation material on the substrate, and does not disturb gas flow as much as possible in the growth furnace.

Abstract: Provided is a production apparatus (100) for continuously producing aligned carbon nanotube aggregates on a substrate supporting a catalyst while continuously transferring the substrate. The production apparatus (100) includes gas mixing prevention means (12, 13) for preventing gas present outside a growth furnace (3a) from flowing into the growth furnace (3a). The gas mixing prevention means (12, 13) includes a seal gas ejection section (12b, 13b) so that the seal gas does not flow into the growth furnace through the openings of the growth furnace. The production apparatus prevents the outside air from flowing into the production apparatus, uniformly controls, within a range suitable to production of CNTs, a concentration distribution(s) and a flow rate distribution(s) of a raw material gas and/or a catalyst activation material on the substrate, and does not disturb gas flow as much as possible in the growth furnace.