Patents by Inventor Alain A. Schutz

Alain A. Schutz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10618836
    Abstract: A glass plate includes a first surface provided with a first film; and a second surface provided with a second film and opposite to the first surface. Each of the first film and the second film includes mainly tin oxide and has a sheet resistance value of 20 ?/? or less. When film thicknesses of the first and second films are ?1 nm and ?2 nm respectively, and when, in the glass plate, a haze value measured from the first surface side for a configuration provided with the first film only is H1 (%), and a haze value measured from the second surface side for a configuration provided with the second film only is H2 (%), a value of ?1 divided by H1 is 500 or more but 1200 or less, and a value of ?2 divided by H2 is 300 or more but 750 or less.
    Type: Grant
    Filed: September 22, 2017
    Date of Patent: April 14, 2020
    Assignee: AGC Glass Europe
    Inventors: Hideaki Hayashi, Bernard Monville, Koji Ushikubo, Eric Tixhon, Gaetan Di Stefano, Alain Schutz
  • Publication number: 20180009703
    Abstract: A glass plate includes a first surface provided with a first film; and a second surface provided with a second film and opposite to the first surface. Each of the first film and the second film includes mainly tin oxide and has a sheet resistance value of 20 ?/? or less. When film thicknesses of the first and second films are ?1 nm and ?2 nm respectively, and when, in the glass plate, a haze value measured from the first surface side for a configuration provided with the first film only is H1 (%), and a haze value measured from the second surface side for a configuration provided with the second film only is H2 (%), a value of ?1 divided by H1 is 500 or more but 1200 or less, and a value of ?2 divided by H2 is 300 or more but 750 or less.
    Type: Application
    Filed: September 22, 2017
    Publication date: January 11, 2018
    Applicants: Asahi Glass Company, Limited, AGC Glass Europe
    Inventors: Hideaki HAYASHI, Bernard MONVILLE, Koji USHIKUBO, Eric TIXHON, Gaetan DI STEFANO, Alain SCHUTZ
  • Patent number: 9487438
    Abstract: The present invention provides low-E thin film optical stacks with improved optical and infrared reflecting properties and methods of making the same. More specifically, the present invention provides for a metal oxide thin film coating that exhibits lower emissivity values than its predecessor due to the inclusion of an oxidizer in the metal oxide deposition process, such as a strong acid such as nitric acid. The present invention also provides for a method that increases the coating efficiencies of the thin films described herein.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: November 8, 2016
    Assignees: AGC FLAT GLASS NORTH AMERICA, INC., AGC GLASS EUROPE, S.A
    Inventors: Christopher R. Cording, Eric Tixhon, Alain Schutz
  • Patent number: 8153265
    Abstract: A transparent glass-type substrate coated with a stack of thin layers and a process for the production of the substrate coated with a stack of thin layers which are deposited by pyrolysis. The stack of thin layers includes at least one titanium oxide-based underlayer and a tin oxide-based main layer, the coated substrate having a very low haze, while also exhibiting a low emissivity or favourable electrical conductivity.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: April 10, 2012
    Assignee: AGC Flat Glass Europe
    Inventors: Alain Schutz, Pieter Jacot, Fabian Mariage
  • Publication number: 20110020621
    Abstract: A transparent glass-type substrate coated with a stack of thin layers, constituting for example a conductive substrate for solar cells, for example photovoltaic cells, and a method for producing such a substrate. The stack of thin layers includes an underlayer, a conductive layer of which has a thickness between 200 and 1000 nm, an upper layer of which has a refractive index between 1.45 and 2.2 and a thickness between 5 and 300 nm. The substrate and the stack are such that the haze is lower than 5%, the transmission value between 450 and 850 nm minus the haze being greater than 70% or even 74%. The substrates combine contradictory electrical and optical properties of: high electrical conductivity, the presence of a buffer layer, and high light and solar transmission.
    Type: Application
    Filed: March 17, 2009
    Publication date: January 27, 2011
    Applicant: AGC Glass Europe
    Inventors: Dominique Coster, Alain Schutz, Pieter Jacot, Jean-Francois Ruelle, Xavier Dognies, Daniel Decroupet
  • Publication number: 20100255225
    Abstract: The present invention provides low-E thin film optical stacks with improved optical and infrared reflecting properties and methods of making the same. More specifically, the present invention provides for a metal oxide thin film coating that exhibits lower emissivity values than its predecessor due to the inclusion of an oxidizer in the metal oxide deposition process, such as a strong acid such as nitric acid. The present invention also provides for a method that increases the coating efficiencies of the thin films described herein.
    Type: Application
    Filed: March 18, 2010
    Publication date: October 7, 2010
    Applicants: AGC FLAT GLASS NORTH AMERICA, INC., AGC GLASS EUROPE, S.A.
    Inventors: Christopher R. CORDING, Eric TIXHON, Alain SCHUTZ
  • Patent number: 7803463
    Abstract: A glazing panel having beneficial anti-solar properties comprises a vitreous substrate carrying a tin/antimony oxide coating layer containing tin and antimony in a Sb/Sn molar ratio of from 0.01 to 0.14. In one application the coated substrate has a solar factor FS of less than 70% and the panel is formed by chemical vapor deposition from a reactant mixture comprising a source of tin and a source of antimony. In another application it is particularly suitable for use in vehicle glazing, in particular in vehicle roof windows, and the coated substrate has a spray-formed pyrolytic tin/antimony oxide coating having a thickness of at least 400 nm and, whereby the coated substrate has a luminous transmittance (TL) of less than 35% and a selectivity (TL/TE) of at least 1.3.
    Type: Grant
    Filed: October 25, 2007
    Date of Patent: September 28, 2010
    Assignee: AGC Flat Glass Europe SA
    Inventors: Robert Terneu, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Patent number: 7622186
    Abstract: A glazing panel having beneficial anti-solar properties comprises a vitreous substrate carrying a tin/antimony oxide coating layer containing tin and antimony in a Sb/Sn molar ratio of from 0.01 to 0.14. In one application the coated substrate has a solar factor FS of less than 70% and the panel is formed by chemical vapor deposition from a reactant mixture comprising a source of tin and a source of antimony. In another application it is particularly suitable for use in vehicle glazing, in particular in vehicle roof windows, and the coated substrate has a spray-formed pyrolytic tin/antimony oxide coating having a thickness of at least 400 nm and, whereby the coated substrate has a luminous transmittance (TL) of less than 35% and a selectivity (TL/TE) of at least 1.3.
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: November 24, 2009
    Assignee: AGC Flat Glass Europe SA
    Inventors: Robert Terneu, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Publication number: 20090011206
    Abstract: A transparent glass-type substrate coated with a stack of thin layers and a process for the production of the substrate coated with a stack of thin layers which are deposited by pyrolysis. The stack of thin layers includes at least one titanium oxide-based underlayer and a tin oxide-based main layer, the coated substrate having a very low haze, while also exhibiting a low emissivity or favourable electrical conductivity.
    Type: Application
    Filed: April 28, 2006
    Publication date: January 8, 2009
    Applicant: AgC Flat, Glass Europe
    Inventors: Alain Schutz, Pieter Jacot, Fabian Mariage
  • Publication number: 20080044665
    Abstract: A glazing panel having beneficial anti-solar properties comprises a vitreous substrate carrying a tin/antimony oxide coating layer containing tin and antimony in a Sb/Sn molar ratio of from 0.01 to 0.14. In one application the coated substrate has a solar factor FS of less than 70% and the panel is formed by chemical vapor deposition from a reactant mixture comprising a source of tin and a source of antimony. In another application it is particularly suitable for use in vehicle glazing, in particular in vehicle roof windows, and the coated substrate has a spray-formed pyrolytic tin/antimony oxide coating having a thickness of at least 400 nm and, whereby the coated substrate has a luminous transmittance (TL) of less than 35% and a selectivity (TL/TE) of at least 1.3.
    Type: Application
    Filed: October 25, 2007
    Publication date: February 21, 2008
    Applicant: Glaverbel
    Inventors: Robert TERNEU, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Publication number: 20060154090
    Abstract: A glazing panel having beneficial anti-solar properties comprises a vitreous substrate carrying a tin/antimony oxide coating layer containing tin and antimony in a Sb/Sn molar ratio of from 0.01 to 0.14. In one application the coated substrate has a solar factor FS of less than 70% and the panel is formed by chemical vapor deposition from a reactant mixture comprising a source of tin and a source of antimony. In another application it is particularly suitable for use in vehicle glazing, in particular in vehicle roof windows, and the coated substrate has a spray-formed pyrolytic tin/antimony oxide coating having a thickness of at least 400 nm and, whereby the coated substrate has a luminous transmittance (TL) of less than 35% and a selectivity (TL/TE) of at least 1.3.
    Type: Application
    Filed: March 13, 2006
    Publication date: July 13, 2006
    Applicant: Glaverbel
    Inventors: Robert Terneu, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Patent number: 7037555
    Abstract: A method of manufacturing a glazing panel having a solar factor (FS) of less than 70% and being composed of a vitreous substrate and a tin/antimony oxide coating layer provided on the vitreous substrate and having a Sb/Sn molar ratio ranging from 0.01 to 0.5, preferable 0.03 to 0.5, the method including the steps of providing reactants in gaseous phase which comprise tin and antimony compounds, which are present in an amount effective to form the tin/antimony oxide coating layer; and forming the tin/antimony oxide coating layer pyrolytically on the vitreous substrate from the reactants in gaseous phase to provide the glazing panel having a solar factor (FS) of less than 70%.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: May 2, 2006
    Assignee: Glaverbel
    Inventors: Robert Terneu, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Publication number: 20010031366
    Abstract: A glazing panel having beneficial anti-solar properties comprises a vitreous substrate carrying a tin/antimony oxide coating layer containing tin and antimony in a Sb/Sn molar ratio of from 0.01 to 0.14. In one application the coated substrate has a solar factor FS of less than 70% and the panel is formed by chemical vapor deposition from a reactant mixture comprising a source of tin and a source of antimony. In another application it is particularly suitable for use in vehicle glazing, in particular in vehicle roof windows, and the coated substrate has a spray-formed pyrolytic tin/antimony oxide coating having a thickness of at least 400 nm and, whereby the coated substrate has a luminous transmittance (TL) of less than 35% and a selectivity (TL/TE) of at least 1.3.
    Type: Application
    Filed: April 10, 2001
    Publication date: October 18, 2001
    Inventors: Robert Terneu, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Patent number: 6231971
    Abstract: A glazing panel having a solar factor (FS) of less than 70% includes a sheet of glass; and at least two coating layers provided on the sheet of glass including first and second coating layers, the first coating layer being composed of tin and antimony oxides and having a Sb/Sn molar ratio ranging from 0.01 to 0.5 and being one of (A) pyrolytically formed from reactants in a gaseous phase or (B) pyrolytically spray formed, and the second coating layer being composed of tin oxide doped with fluorine.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: May 15, 2001
    Assignee: Glaverbel
    Inventors: Robert Terneu, Philippe Legrand, Michel Hannotiau, Alain Schutz
  • Patent number: 5877354
    Abstract: The present invention is a process for the production of isophorone having improved color and color stability. Crude isophorone is selectively hydrogenated to remove color forming impurities. The product isophorone will have an APHA color of about 10 or less.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: March 2, 1999
    Assignee: Aristech Chemical Corporation
    Inventors: Chandrashekhar P. Kelkar, Alain A. Schutz
  • Patent number: 5518704
    Abstract: A synthetic nickel (or cobalt) containing hydrotalcite-like material having a sheet-like morphology and a sheet broadness to thickness ratio of at least 50 and a formula M.sub.1-x Al.sub.x (OH).sub.2 .multidot.xA.multidot.mH.sub.2 O where M is Ni or Co, A is a mono carboxylic anion of the form RCOO.sup.- where R is C.sub.n H.sub.2n+1 and n=0-5, and x and m are numbers satisfying the following conditions:0.2<=x<=0.40.0<=m<=4It is made by starting with a synthesis mixture having Ni or Co (divalent cation) to aluminum (trivalent cation) molar ratio between 1:1 and 10:1, mono carboxylic anion to aluminum (trivalent cation) molar ratio between 0.1:1 to 1.2:1 and optionally added other anions. The process comprises of reacting a mixture comprising nickel (or cobalt) and aluminum cations and mono carboxylic anions in an aqueous slurry at a temperature of at least 40.degree. C. and a pH of at least 7.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: May 21, 1996
    Assignee: Aristech Chemical Corporation
    Inventors: Chandrashekhar P. Kelkar, Alain A. Schutz, Leonard A. Cullo
  • Patent number: 5507980
    Abstract: The present invention relates to a process for making novel catalysts, catalyst supports, and adsorbers comprising synthetic hydrotalcite-like binders, having a sheet-like morphology and a sheet broadness to thickness ratio of at least 50 and a formula Mg.sub.1-x Al.sub.x (OH).sub.2.xA.sup.-. mH.sub.2 O where A.sup.- is a mono carboxylic anion of the form RCOO.sup.- where R is C.sub.n H.sub.2n+1 and n=0-5, and x and m are numbers satisfying the following conditions:0.2<=x<=0.40.0<=m<=4This hydrotalcite-like material is combined with an inorganic material to form shapes which have good mechanical strength. The process includes starting with a synthesis mixture having magnesium (divalent cation) to aluminum (trivalent cation) molar ratio between 1:1 and 10:1, mono carboxylic anion to aluminum (trivalent cation) molar ratio between 0.1:1 to 1.2:1 and optionally added other anions.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: April 16, 1996
    Assignee: Aristech Chemical Corporation
    Inventors: Chandrashekhar P. Kelkar, Alain A. Schutz, Leonard A. Cullo
  • Patent number: 5399329
    Abstract: A synthetic hydrotalcite-like material having a sheet-like morphology and a sheet broadness to thickness ratio of at least 50 and a formula Mg.sub.1-x Al.sub.x (OH).sub.2.xA.mH.sub.2 O where A is a mono carboxylic anion of the form RCOO.sup.- where R is C.sub.n H.sub.2n+1 and n=0-5, and x and m are numbers satisfying the following conditions:0.2<=x<=0.40.0<=m<=4It is made by starting with a synthesis mixture having magnesium (divalent cation) to aluminum (trivalent cation) molar ratio between 1:1 and 10:1, mono carboxylic anion to aluminum (trivalent cation) molar ratio between 0.1:1 to 1.2:1 and optionally added other anions. The process comprises of reacting a mixture comprising magnesium and aluminum cations and mono carboxylic anions in an aqueous slurry at a temperature of at least 40.degree. C. and a pH of at least 7.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: March 21, 1995
    Assignee: Aristech Chemical Corporation
    Inventors: Alain A. Schutz, Leonard A. Cullo, Chandrashekhar P. Kelkar
  • Patent number: 5352839
    Abstract: Isophorone is made by the aldol condensation of acetone followed by separate steps to remove acetone, mesityloxide, and beta isophorone. Variations include recycling of mesityloxide and/or beta isophorone.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: October 4, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Michael C. Grebinoski, Donald Glassman, Carole L. Elias, Alain A. Schutz
  • Patent number: 5245090
    Abstract: This invention is an improved two-stage method for producing phenol and acetone from cumene hydroperoxide (CHP) comprising decomposing cumene hydroperoxide in a first stage, and subjecting the product of the first stage to hydrogenation in a second stage; residual cumene hydroperoxide may be decomposed in the second stage, with or without recycling of acetone and/or part of the effluent of the second stage back to the first stage; cumene is also desirably recycled.
    Type: Grant
    Filed: September 11, 1992
    Date of Patent: September 14, 1993
    Assignee: Aristech Chemical Corporation
    Inventors: Anthony J. DeCaria, Alain A. Schutz