Patents by Inventor Alain Bouilloux

Alain Bouilloux has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11555116
    Abstract: Provided herein is a copolymer of ethylene and acrylate(s) having a melt flow index (MFI) greater than or equal to 50 g/10 minutes, obtained by free-radical copolymerisation under high pressure carried out in a tubular reactor, and methods of using the same. Also provided herein is a thermoplastic composition, particularly intended to be extruded or injection moulded, having one or more copolymers of ethylene and acrylate(s) at a content ranging from 0.1 to 20 wt. %, and one or more thermoplastic polymers.
    Type: Grant
    Filed: March 26, 2019
    Date of Patent: January 17, 2023
    Assignee: SK Global Chemical Co., Ltd.
    Inventors: Paul Coupillaud, Sebastien Quinebeche, Alain Bouilloux
  • Patent number: 11396618
    Abstract: An adhesive composition of at least one ethylene polymer or copolymer, wherein at least one first polymer or copolymer including the unsaturated carboxylic acid ester type comonomer is copolymerized in a continuous high-pressure tubular reactor, while a second polymer or copolymer including the functional comonomer is copolymerized by either autoclave or tubular continuous high-pressure radical means; the first and second polymer or copolymer possibly being of one and the same polymer/copolymer. Also, a multilayer structure that incorporates the adhesive composition and a particular process for obtaining this composition.
    Type: Grant
    Filed: May 11, 2016
    Date of Patent: July 26, 2022
    Assignee: SK GLOBAL CHEMICAL CO., LTD.
    Inventors: Clio Cocquet, Betty Laurent, Claire Michalowicz, Mathieu Bodiguel, Alain Bouilloux
  • Patent number: 11292896
    Abstract: A rubber composition is based on at least: a copolymer A, with a content of greater than or equal to 50 phr, said copolymer A being a copolymer based on at least one ethylene monomer and on at least one vinyl acetate monomer a reinforcing inorganic filler as agent for coupling between said copolymer A and said reinforcing inorganic filler, a copolymer B different from said copolymer A, said copolymer B being a copolymer based on at least one alpha-olefin monomer and on at least one functional monomer Y; and a peroxide crosslinking system. This composition is especially intended for the manufacture of semi-finished products for tires or for the manufacture of tires.
    Type: Grant
    Filed: December 21, 2017
    Date of Patent: April 5, 2022
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, SK GEO CENTRIC CO., LTD.
    Inventors: Corentin Pavageau, Benoit Schnell, Alain Bouilloux, Sebastien Quinebeche
  • Publication number: 20210163739
    Abstract: Provided herein is a copolymer of ethylene and acrylate(s) having a melt flow index (MFI) greater than or equal to 50 g/10 minutes, obtained by free-radical copolymerisation under high pressure carried out in a tubular reactor, and methods of using the same. Also provided herein is a thermoplastic composition, particularly intended to be extruded or injection moulded, having one or more copolymers of ethylene and acrylate(s) at a content ranging from 0.1 to 20 wt. %, and one or more thermoplastic polymers.
    Type: Application
    Filed: March 26, 2019
    Publication date: June 3, 2021
    Inventors: Paul Coupillaud, Sebastien Quinebeche, Alain Bouilloux
  • Publication number: 20190375926
    Abstract: A rubber composition is based on at least: a copolymer A, with a content of greater than or equal to 50 phr, said copolymer A being a copolymer based on at least one ethylene monomer and on at least one vinyl acetate monomer a reinforcing inorganic filler as agent for coupling between said copolymer A and said reinforcing inorganic filler, a copolymer B different from said copolymer A, said copolymer B being a copolymer based on at least one alpha-olefin monomer and on at least one functional monomer Y; and a peroxide crosslinking system. This composition is especially intended for the manufacture of semi-finished products for tires or for the manufacture of tires.
    Type: Application
    Filed: December 21, 2017
    Publication date: December 12, 2019
    Inventors: CORENTIN PAVAGEAU, BENOIT SCHNELL, ALAIN BOUILLOUX, SEBASTIEN QUINEBECHE
  • Publication number: 20180134928
    Abstract: An adhesive composition of at least one ethylene polymer or copolymer, wherein at least one first polymer or copolymer including the unsaturated carboxylic acid ester type comonomer is copolymerized in a continuous high-pressure tubular reactor, while a second polymer or copolymer including the functional comonomer is copolymerized by either autoclave or tubular continuous high-pressure radical means; the first and second polymer or copolymer possibly being of one and the same polymer/copolymer. Also, a multilayer structure that incorporates the adhesive composition and a particular process for obtaining this composition.
    Type: Application
    Filed: May 11, 2016
    Publication date: May 17, 2018
    Applicant: ARKEMA FRANCE
    Inventors: Clio COCQUET, Betty LAURENT, Claire MICHALOWICZ, Mathieu BODIGUEL, Alain BOUILLOUX
  • Patent number: 8653192
    Abstract: A method for manufacturing a thermoplastic composition including: a polyester resin (c); a mixture including a copolymer (a) of an ?-olefin and of a monomer having an ethylenic unsaturation and an epoxy function, as well as a core-shell compound (b); characterized in that said method includes a first step of manufacture the mixture of (a) and (b) by extrusion at a temperature at which the copolymer (a) is in the molten state and at a maximum temperature of 60 to 180° C.; a second step of manufacturing the thermoplastic composition by extrusion or by mixing the polyester resin (c) with the mixture of (a) and (b) produced in the first step.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: February 18, 2014
    Assignee: Arkema France
    Inventors: Sebastien Quinebeche, Alexander Korzhenko, Alain Bouilloux, Stephane Girois
  • Patent number: 8642703
    Abstract: A composition including polyhydroxyalkanoic acid (PHA), an elastomeric compound of core-shell type, and an olefinic copolymer including an ethylenic monomer bearing an epoxy function. The PHA composition exhibits improved impact strength.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: February 4, 2014
    Assignee: Arkema France
    Inventors: Alain Bouilloux, Sébastien Quinebeche, Stephane Girois
  • Patent number: 8410216
    Abstract: The invention relates to a composition based on an impact-resistant thermoplastic polyamide resin, comprising, as a blend—from 60 to 98 wt % of polyamide resin (A) and—from 2 to 40 wt % of a blend of at least one graft copolymer with polyamide blocks (B) composed of a polyolefin backbone and at least one polyamide graft in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a functional group capable of reacting with an amine-terminated polyamide, the residues of the unsaturated monomer (X) being attached to the backbone by grafting or copolymerization via its double bond, and of a non-reactive ethylenic polymer (C) that is miscible with (B) and has a density of below 0.960 g/cm3.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: April 2, 2013
    Assignee: Arkema France
    Inventors: Marius Hert, Alain Bouilloux, Thibaut Montanari, Thomas Fine
  • Publication number: 20120316293
    Abstract: A composition including polyhydroxyalkanoic acid (PHA), an elastomeric compound of core-shell type, and an olefinic copolymer including an ethylenic monomer bearing an epoxy function. The PHA composition exhibits improved impact strength.
    Type: Application
    Filed: January 17, 2012
    Publication date: December 13, 2012
    Applicant: Arkema France
    Inventors: Alain Bouilloux, Sébastien Quinebeche, Stephane Girois
  • Publication number: 20120271004
    Abstract: The invention relates to a method for manufacturing a thermoplastic composition including: a polyester resin (c); a mixture including a copolymer (a) of an ?-olefin and of a monomer having an ethylenic unsaturation and an epoxy function, as well as a core-shell compound (b); characterized in that said method includes a first step of manufacture the mixture of (a) and (b) by extrusion at a temperature at which the copolymer (a) is in the molten state and at a maximum temperature of 60 to 180° C.; a second step of manufacturing the thermoplastic composition by extrusion or by mixing the polyester resin (c) with the mixture of (a) and (b) produced in the first step.
    Type: Application
    Filed: July 13, 2010
    Publication date: October 25, 2012
    Applicant: Arkema France
    Inventors: Sébastien Quinebeche, Alexander Korzhenko, Alain Bouilloux, Stephane Girois
  • Publication number: 20110251331
    Abstract: The present invention pertains to the use of nanotubes of at least one chemical element chosen from elements of groups IHa, IVa and Va of the periodic table to improve the high temperature mechanical properties of a polymeric matrix comprising at least one semi-crystalline thermoplastic polymer.
    Type: Application
    Filed: June 25, 2008
    Publication date: October 13, 2011
    Inventors: Thomas Page Mcandrew, Gilles Hochstetter, Michael Werth, Alain Bouilloux, Benoit Brule, Patrickm. M. piccione, Nour Eddine El Bounia, Christophe Roger, Emily Bressand
  • Publication number: 20100137516
    Abstract: The invention relates to a composition based on an impact-resistant polyamide thermoplastic resin, comprising, as a blend: from 60 to 98% by weight of polyamide resin (A) and from 2 to 40% by weight of a blend of at least one polyamide-block graft copolymer (B) composed of a polyolefin backbone and of at least one polyamide graft in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a functional group capable of reacting with an amine-terminated polyamide, the residues of the unsaturated monomer (X) being attached to the backbone by grafting or copolymerization via its double bond, and of a non-reactive ethylenic polymer (C) that is miscible with (B) and has a density of less than 0.960 g/cm3. This composition has improved impact resistance properties and also satisfactory melt flow. The invention also relates to the method of obtaining said composition and also to its use for manufacturing products or parts obtained by injection moulding or extrusion.
    Type: Application
    Filed: October 11, 2007
    Publication date: June 3, 2010
    Applicant: ARKEMA FRANCE
    Inventors: Marius Hert, Alain Bouilloux, Thibaut Montanari, Thomas Fine
  • Publication number: 20070167568
    Abstract: The invention relates to a tie comprising a blend of grafted polyethylene (PE), of grafted or ungrafted high-impact or crystal polystyrene and optionally of ungrafted PE. The grafted PE is preferably composed of two different cografted PEs. This tie is of use in the manufacture of multilayer structures intended for the field of Civil Engineering Works (CEW), more particularly for the fields of aluminium panels, of multilayer pipes, but also for the field of packaging.
    Type: Application
    Filed: December 20, 2006
    Publication date: July 19, 2007
    Inventors: Arnaud Gerbaulet, Fabrice Chopinez, Alain Bouilloux
  • Patent number: 7151136
    Abstract: The invention relates to a polyamide-based thermoplastic composition comprising, by weight: 50 to 98 parts of a polyamide (A1) nondiamine; 0.2 to 40 parts, preferably 0.2 to 9 parts, of a polyamide (A2) diamine, said polyamide (A2) being different from the polyamide (A1) and the ratio by mass (A2)/(A1) being less than 1; 1 to 60 parts, preferably 1 to 30 parts, of a reactive impact modifier (B) or of a blend of modifiers comprising at least one reactive impact modifier (B) or of a blend (B?) comprising at least one impact modifier and at least one reactive modifier. It also relates to an impact modifier composition and to the process for the preparation of a thermoplastic composition according to the invention using such an impact modifier composition.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: December 19, 2006
    Assignee: Arkema
    Inventors: Thibaut Montanari, Philippe Bussi, Alain Bouilloux
  • Patent number: 7119152
    Abstract: The present invention relates to thermoplastic polyesters, which comprise, by weight: (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shell copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-unsaturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 40/60 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 40/60 and 25/75 for proportions of impact modifier between 2 and 18% in 98 to 82% of polyester, respectively. It is particularly useful for PET and PBT.
    Type: Grant
    Filed: November 24, 2000
    Date of Patent: October 10, 2006
    Assignee: ATOFINA
    Inventors: Christophe Lacroix, Alain Bouilloux
  • Patent number: 7022768
    Abstract: The invention concerns thermoplastic polyesters (such as PET or PBT) comprising, by weight, the total being 100%: 60 to 99% of thermoplastic polyester; 1 to 40% of impact modifier comprising: (a) a core-shell copolymer (A), (b) an ethylene copolymer (B) selected among ethylene copolymers (B1) and an unsaturated carboxylic acid anhydride, ethylene copolymers (B2) and an unsaturated epoxy compound and mixtures thereof, (c) a copolymer (C) selected among ethylene copolymers (C1) and an alkyl (meth)acrylate, ethylene copolymers (C2) and (meth)acrylic acid optionally neutralised and mixtures thereof. The invention also concerns an impact modifying composition which can be added in thermoplastic polyesters to improve their shock-proof properties and comprising constituents (A), (B) and (C).
    Type: Grant
    Filed: November 23, 2000
    Date of Patent: April 4, 2006
    Assignee: Atofina
    Inventors: Christophe Lacroix, Alain Bouilloux, Claude Granel, Michael Tran
  • Patent number: 6864318
    Abstract: A composition comprising a thermoplastic polymer having incorporated therein a crosslinked phase derived from the reaction of: (A) a copolymer made from ethylene and an unsaturated epoxide, a polyolefin grafted with an unsaturated epoxide, or a product having two epoxide groups, (B) a copolymer made from ethylene and an unsaturated carboxylic acid anhydride, and (C) a copolymer made from an unsaturated carboxylic acid or an ?,?-aminocarboxylic acid.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: March 8, 2005
    Assignee: ATOFINA
    Inventors: Alain Bouilloux, Laurent Teze
  • Patent number: 6831131
    Abstract: The invention relates to a composition based on polypropylene homopolymer or copolymer and on an impact modifier comprising an ethylene/alkyl acrylate copolymer. This composition comprises substantially between 1 and 40% by weight of impact modifier and it may comprise an ethylene-based copolymer taken from the group comprising ethylene/acrylate copolymers, vinyl acetate copolymers, polyethylene obtained by metallocene catalysis or mPE and linear low-density polyethylene or LLDPE. The PP thus modified is useful for manufacturing motor-vehicle parts for example of the bumper or dashboard type, requiring good thermomechanical strength over a wide range of temperatures.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: December 14, 2004
    Assignee: Atofina
    Inventors: Alain Bouilloux, Christophe Lacroix
  • Patent number: 6809151
    Abstract: The present invention relates to the thermoplastic polyesters, which comprise, by weight (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shelf copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-saturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 90/10 and 25/75 for proportions of impact modifier between 2 and 40% in 98 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 25/75 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively. It is particularly useful for PET and PBT.
    Type: Grant
    Filed: November 24, 2000
    Date of Patent: October 26, 2004
    Assignee: Atofina
    Inventors: Christophe Lacroix, Alain Bouilloux