Patents by Inventor Alain Hut
Alain Hut has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11802194Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: GrantFiled: May 17, 2022Date of Patent: October 31, 2023Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Publication number: 20220363875Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: ApplicationFiled: May 17, 2022Publication date: November 17, 2022Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT
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Publication number: 20220259415Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer matrix comprising from 50 to 100 phr of one or more copolymers of butadiene and of vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight and a Tg within a range extending from ?110° C. to ?70° C.; and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar>6 mol %, (2) Tg?95?2.2*(H Ar), and (3) Tg??53+(0.265*Mn).Type: ApplicationFiled: July 10, 2020Publication date: August 18, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Publication number: 20220251350Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer and a hydrocarbon resin, wherein [[said]]the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a number average molecular weight (Mn) of between 150 and 800 g/mol, and a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar<6 mol %, (2) Tg?95?2.2*(H Ar), (3) Tg?125?(0.08*Mn).Type: ApplicationFiled: July 10, 2020Publication date: August 11, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Publication number: 20220251349Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer matrix comprising from 50 to 100 phr of one or more copolymers of butadiene and of vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight and a Tg within a range extending from ?110° C. to ?70° C.; and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar?6 mol %, (2) Tg?95?2.2*(H Ar), (3) Tg?125?(0.08*Mn).Type: ApplicationFiled: July 10, 2020Publication date: August 11, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Publication number: 20220227975Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar>6 mol %, (2) Tg?95?2.2*(H Ar), and (3) Tg??53+(0.265*Mn).Type: ApplicationFiled: July 10, 2020Publication date: July 21, 2022Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
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Patent number: 11365308Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: GrantFiled: October 14, 2016Date of Patent: June 21, 2022Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Patent number: 11203680Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units derived from terpene and phenol monomers, the resin having a content of aromatic protons of greater than 15%.Type: GrantFiled: December 5, 2017Date of Patent: December 21, 2021Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Benoit De Gaudemaris, Alain Hut
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Patent number: 10889147Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.Type: GrantFiled: December 18, 2015Date of Patent: January 12, 2021Assignee: Compagnie Generale Des Etablissements MichelinInventors: Julien Chatard, Benoit De Gaudemaris, Alain Hut, Fabien Hellot, Francois Dimier
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Publication number: 20200392314Abstract: The tread of a civil engineering vehicle tire comprises a rubber composition based on at least one elastomer matrix comprising from 50 to 100 phr of a styrene-butadiene copolymer and from 0 to 50 phr of isoprene elastomer; a reinforcing filler comprising predominantly carbon black with CTAB specific surface area greater than or equal to 90 m2/g; from 1 to 30 phr of at least one hydrocarbon resin predominantly consisting of units derived from aromatic and cycloaliphatic monomers, having an aromatic proton content between 0 and 12%, an ethylenic proton content greater than 3%, a number-average molecular weight above 500 g/mol and a polydispersity index greater than 2; and a crosslinking system.Type: ApplicationFiled: December 13, 2018Publication date: December 17, 2020Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT, LAURENT PETITJEAN
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Publication number: 20190367707Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units derived from terpene and phenol monomers, the resin having a content of aromatic protons of greater than 15%.Type: ApplicationFiled: December 5, 2017Publication date: December 5, 2019Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT
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Publication number: 20180340055Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: ApplicationFiled: October 14, 2016Publication date: November 29, 2018Inventors: Benoit DE GAUDEMARIS, Alain HUT
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Publication number: 20180001702Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.Type: ApplicationFiled: December 18, 2015Publication date: January 4, 2018Inventors: JULIEN CHATARD, BENOIT DE GAUDEMARIS, ALAIN HUT, FABIEN HELLOT, FRANCOIS DIMIER
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Patent number: 8883929Abstract: Nanoparticles of functionalized, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerizable by free-radical polymerization: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerization. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilylpropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.Type: GrantFiled: April 13, 2012Date of Patent: November 11, 2014Assignees: Compagnie Generale des Etablissements, Michelin Recherche et Technique S.A.Inventors: Sylvie Gandon-Pain, Alain Hut
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Patent number: 8835561Abstract: Branched block polymers, and the rubber compositions containing them, which can be used, in particular, for manufacturing tires or semi-finished products for tires. Processes for preparing said polymers and compositions are also disclosed.Type: GrantFiled: July 31, 2006Date of Patent: September 16, 2014Assignee: Michelin Recherche et Technique S.A.Inventors: Sylvie Gandon-Pain, Alain Hut
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Publication number: 20120208948Abstract: Nanoparticles of functionalised, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerisable by free-radical polymerisation: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerisation. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilyipropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.Type: ApplicationFiled: April 13, 2012Publication date: August 16, 2012Applicant: Michelin Recherche et Technique S.A.Inventors: Sylvie Gandon-Pain, Alain Hut
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Publication number: 20110021702Abstract: Nanoparticles of functionalised, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerisable by free-radical polymerisation: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerisation. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilylpropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.Type: ApplicationFiled: June 29, 2007Publication date: January 27, 2011Applicant: MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Sylvie Gandon-Pain, Alain Hut
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Publication number: 20100154945Abstract: Branched block polymers, and the rubber compositions containing them, which can be used, in particular, for manufacturing tires or semi-finished products for tires. Processes for preparing said polymers and compositions are also disclosed.Type: ApplicationFiled: July 31, 2006Publication date: June 24, 2010Inventors: Sylvie Gandon-Pain, Alain Hut
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Publication number: 20090270558Abstract: Nanoparticles of a functionalized and crosslinked polyvinylaromatic (PVAr) that may be used as reinforcing filler in a polymeric composition, the PVAr being a copolymer of at least: a vinylaromatic comonomer “A”; a comonomer “B” carrying a functional group denoted by Z of formula ?Si—X, X representing a hydroxyl or hydrolyzable group; a crosslinking comonomer “C” which is at least bifunctional and polymerizable by means of an addition reaction, it being possible for comonomer C to be vinylaromatic, in this case identical or different to comonomer A or non-vinylaromatic. The PVAr comprises, for example, a copolymer of styrene, ethylvinylbenzene, divinylbenzene and trimethoxysilylpropyl(meth)acrylate, being in the form of nanobeads, the diameter of which is between 10 and 100 nm. This PVAr filler, thanks to a very low density, allows the weight of polymeric compositions, especially elastomer compositions, to be reduced without degrading the reinforcement, and with an notable reduction in hysteresis.Type: ApplicationFiled: December 30, 2005Publication date: October 29, 2009Applicant: Michelin Recherche et Technique S.A.Inventors: Sylvie Gandon-pain, Alain Hut, Arnaud Lapra