Patents by Inventor Alain Hut

Alain Hut has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11802194
    Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.
    Type: Grant
    Filed: May 17, 2022
    Date of Patent: October 31, 2023
    Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Benoit De Gaudemaris, Alain Hut
  • Publication number: 20220363875
    Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.
    Type: Application
    Filed: May 17, 2022
    Publication date: November 17, 2022
    Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT
  • Publication number: 20220259415
    Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer matrix comprising from 50 to 100 phr of one or more copolymers of butadiene and of vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight and a Tg within a range extending from ?110° C. to ?70° C.; and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar>6 mol %, (2) Tg?95?2.2*(H Ar), and (3) Tg??53+(0.265*Mn).
    Type: Application
    Filed: July 10, 2020
    Publication date: August 18, 2022
    Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
  • Publication number: 20220251350
    Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer and a hydrocarbon resin, wherein [[said]]the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a number average molecular weight (Mn) of between 150 and 800 g/mol, and a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar<6 mol %, (2) Tg?95?2.2*(H Ar), (3) Tg?125?(0.08*Mn).
    Type: Application
    Filed: July 10, 2020
    Publication date: August 11, 2022
    Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
  • Publication number: 20220251349
    Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer matrix comprising from 50 to 100 phr of one or more copolymers of butadiene and of vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight and a Tg within a range extending from ?110° C. to ?70° C.; and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar?6 mol %, (2) Tg?95?2.2*(H Ar), (3) Tg?125?(0.08*Mn).
    Type: Application
    Filed: July 10, 2020
    Publication date: August 11, 2022
    Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
  • Publication number: 20220227975
    Abstract: Described herein are tires comprising a rubber composition based on at least an elastomer and a hydrocarbon resin, wherein the hydrocarbon resin is based on a cyclic monomer selected from the group consisting of a distillation cut from a petroleum refinery stream, and/or C4, C5 or C6 cyclic olefins and mixtures thereof, and wherein the hydrocarbon resin has a content of aromatic protons (H Ar, expressed in mol %), a glass transition temperature (Tg, expressed in ° C.), and a number average molecular weight (Mn, expressed in g/mol) that are represented by (1) H Ar>6 mol %, (2) Tg?95?2.2*(H Ar), and (3) Tg??53+(0.265*Mn).
    Type: Application
    Filed: July 10, 2020
    Publication date: July 21, 2022
    Inventors: FABIEN BONNETTE, LAURENT COPEY, BENOIT DE GAUDEMARIS, OLIVIER J. F. GEORJON, DEREK W. THURMAN, RANJAN TRIPATHY, ALAIN HUT
  • Patent number: 11365308
    Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.
    Type: Grant
    Filed: October 14, 2016
    Date of Patent: June 21, 2022
    Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Benoit De Gaudemaris, Alain Hut
  • Patent number: 11203680
    Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units derived from terpene and phenol monomers, the resin having a content of aromatic protons of greater than 15%.
    Type: Grant
    Filed: December 5, 2017
    Date of Patent: December 21, 2021
    Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Benoit De Gaudemaris, Alain Hut
  • Patent number: 10889147
    Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.
    Type: Grant
    Filed: December 18, 2015
    Date of Patent: January 12, 2021
    Assignee: Compagnie Generale Des Etablissements Michelin
    Inventors: Julien Chatard, Benoit De Gaudemaris, Alain Hut, Fabien Hellot, Francois Dimier
  • Publication number: 20200392314
    Abstract: The tread of a civil engineering vehicle tire comprises a rubber composition based on at least one elastomer matrix comprising from 50 to 100 phr of a styrene-butadiene copolymer and from 0 to 50 phr of isoprene elastomer; a reinforcing filler comprising predominantly carbon black with CTAB specific surface area greater than or equal to 90 m2/g; from 1 to 30 phr of at least one hydrocarbon resin predominantly consisting of units derived from aromatic and cycloaliphatic monomers, having an aromatic proton content between 0 and 12%, an ethylenic proton content greater than 3%, a number-average molecular weight above 500 g/mol and a polydispersity index greater than 2; and a crosslinking system.
    Type: Application
    Filed: December 13, 2018
    Publication date: December 17, 2020
    Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT, LAURENT PETITJEAN
  • Publication number: 20190367707
    Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units derived from terpene and phenol monomers, the resin having a content of aromatic protons of greater than 15%.
    Type: Application
    Filed: December 5, 2017
    Publication date: December 5, 2019
    Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT
  • Publication number: 20180340055
    Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.
    Type: Application
    Filed: October 14, 2016
    Publication date: November 29, 2018
    Inventors: Benoit DE GAUDEMARIS, Alain HUT
  • Publication number: 20180001702
    Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.
    Type: Application
    Filed: December 18, 2015
    Publication date: January 4, 2018
    Inventors: JULIEN CHATARD, BENOIT DE GAUDEMARIS, ALAIN HUT, FABIEN HELLOT, FRANCOIS DIMIER
  • Patent number: 8883929
    Abstract: Nanoparticles of functionalized, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerizable by free-radical polymerization: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerization. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilylpropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: November 11, 2014
    Assignees: Compagnie Generale des Etablissements, Michelin Recherche et Technique S.A.
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Patent number: 8835561
    Abstract: Branched block polymers, and the rubber compositions containing them, which can be used, in particular, for manufacturing tires or semi-finished products for tires. Processes for preparing said polymers and compositions are also disclosed.
    Type: Grant
    Filed: July 31, 2006
    Date of Patent: September 16, 2014
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Publication number: 20120208948
    Abstract: Nanoparticles of functionalised, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerisable by free-radical polymerisation: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerisation. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilyipropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.
    Type: Application
    Filed: April 13, 2012
    Publication date: August 16, 2012
    Applicant: Michelin Recherche et Technique S.A.
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Publication number: 20110021702
    Abstract: Nanoparticles of functionalised, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerisable by free-radical polymerisation: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerisation. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilylpropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.
    Type: Application
    Filed: June 29, 2007
    Publication date: January 27, 2011
    Applicant: MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Publication number: 20100154945
    Abstract: Branched block polymers, and the rubber compositions containing them, which can be used, in particular, for manufacturing tires or semi-finished products for tires. Processes for preparing said polymers and compositions are also disclosed.
    Type: Application
    Filed: July 31, 2006
    Publication date: June 24, 2010
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Publication number: 20090270558
    Abstract: Nanoparticles of a functionalized and crosslinked polyvinylaromatic (PVAr) that may be used as reinforcing filler in a polymeric composition, the PVAr being a copolymer of at least: a vinylaromatic comonomer “A”; a comonomer “B” carrying a functional group denoted by Z of formula ?Si—X, X representing a hydroxyl or hydrolyzable group; a crosslinking comonomer “C” which is at least bifunctional and polymerizable by means of an addition reaction, it being possible for comonomer C to be vinylaromatic, in this case identical or different to comonomer A or non-vinylaromatic. The PVAr comprises, for example, a copolymer of styrene, ethylvinylbenzene, divinylbenzene and trimethoxysilylpropyl(meth)acrylate, being in the form of nanobeads, the diameter of which is between 10 and 100 nm. This PVAr filler, thanks to a very low density, allows the weight of polymeric compositions, especially elastomer compositions, to be reduced without degrading the reinforcement, and with an notable reduction in hysteresis.
    Type: Application
    Filed: December 30, 2005
    Publication date: October 29, 2009
    Applicant: Michelin Recherche et Technique S.A.
    Inventors: Sylvie Gandon-pain, Alain Hut, Arnaud Lapra