Patents by Inventor Alain Milan

Alain Milan has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6740229
    Abstract: This invention relates to a method for drying the charge of a unit that treats petroleum cuts with a low water charge that consists in injecting a hydrolysable chemical compound into said charge. The quantity of the chemical compound injected is at least equal to the quantity necessary for all the water contained in the charge to react by hydrolysis with said chemical compound. The invention finds its application in units that treat petroleum cuts and whose operation is sensitive to the presence of water in their charges, in particular the paraffin base hydrocarbon isomerisation units. One drawing.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: May 25, 2004
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Pedro Nascimento, Jacques Couillard, Jean-Louis Mauleon, Alain Milan
  • Patent number: 6679986
    Abstract: A catalytic support includes a substantial quantity of at least one SVI group Periodic Table metal oxide in which is incorporated silica. The mass ratio between the quantity of SVI group metal oxide and the quantity of silica it contains ranges between 5 and 70, the SVI group metal oxide is in crystalline form, and the specific surface of the support is greater than or equal to 160 m2/g.
    Type: Grant
    Filed: May 16, 2000
    Date of Patent: January 20, 2004
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Pedro Da Silva, Marc Bisson, Alain Milan, Sebastien Decker, Joeri Denayer
  • Publication number: 20030006169
    Abstract: This invention relates to a method for drying the charge of a unit that treats petroleum cuts with a low water charge that consists in injecting a hydrolysable chemical compound into said charge.
    Type: Application
    Filed: July 3, 2002
    Publication date: January 9, 2003
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Pedro Nascimento, Jacques Couillard, Jean-Louis Mauleon, Alain Milan
  • Patent number: 6448198
    Abstract: The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 135 m2/g, a pore volume greater than or equal to 0.16 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions. In a preferred embodiment of the method of the present invention, a hydrated zirconia gel is washed with a soluble polar organic solvent (other than water).
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: September 10, 2002
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Georges Szabo, Pedro Nascimento, Alain Milan, Sebastien Decker, Joeri Denayer, Jean-Pierre Dath
  • Patent number: 6225517
    Abstract: An alkylation catalyst including a least one porous refractory metal oxide with at least one halogen on the surface thereof. The catalyst contains 0.005-1 wt % of at least one metal from groups IA and IIA of the periodic table of the elements and is particularly useful in an isobutane alkylation method using light olefins.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: May 1, 2001
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Pedro Nascimento, Georges Szabo, Alain Milan
  • Patent number: 6194345
    Abstract: The invention relates to a process of activating a supported acid catalyst, and consists in the conversion of Lewis acid-type acid sites which are deposited on a solid substrate into activated acid sites in a non-oxydizing acid medium. The catalyst is exposed to a phase of activation in a medium containing a holohydric acid or a halohydric acid precursor, in the presence of at least one preferably parafinic hydrocarbon or hydrocarbon derivative, at a temperature greater than 20° and preferably between 100° C. and 250° C., and at a pressure of between 105 and 50,106 Pa, for a length of time sufficient to ensure conversion into activated acid sites.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: February 27, 2001
    Assignees: Total Raffinage Distribution S.A., Akzo Nobel N.V.
    Inventors: Peter Mangnus, Alain Milan, Georges Szabo
  • Patent number: 6180555
    Abstract: The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.20 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions.
    Type: Grant
    Filed: October 9, 1998
    Date of Patent: January 30, 2001
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Georges Szabo, Pedro Nascimento, Alain Milan, Sebsastien Decker
  • Patent number: 5151400
    Abstract: The invention relates to a process for the preparation and activation of a catalyst, comprising a stage of fabricating a support consisting at least in part of at least one refractory oxide mineral, a stage of depositing on the support at least one metal from the platinum group, and a stage intended for forming on the support at least two metal halides of the Lewis acid type. Between the deposition of the metal halides of the Lewis acid type and the utilization of the catalyst in the reactor, the catalyst is subjected to an activation stage by being maintained in an acidic and nonoxidizing or reducing medium at a temperature between 300.degree. and 475.degree. C. so that its final content of a promoter metal of the zirconium, molybdenum tungsten or titanium type ranges from 0.15 to 1 percent, based on the weight of the support.
    Type: Grant
    Filed: July 18, 1990
    Date of Patent: September 29, 1992
    Assignee: Compagnie de Raffinage et de Distribution Total France
    Inventors: Georges Szabo, Egbertus F. P. Schasfoort, Alain Milan