Abstract: Durable, transparent, inorganic-organic hybrid hydrophobic coating materials for glass, metal or plastic substrates are provided. The coating materials are generally an acid catalyzed condensation reaction product comprised of an organic polymeric silane (e.g., a polyol functionalized with a silane through a urethane linkage or a polyamine functionalized with a silane through a urea linkage, such as isocyanatopropyltrimethoxysilane or isocyanatopropyltriethoxysilane), an inorganic metal alkoxide (e.g., silicon alkoxides such as tetraethoxysilane or tetramethoxysilane) and a fluorinated silane (e.g., (3,3,3-trifluoropropyl)trimethoxysilane or nonafluorohexyltrimethoxysilane).

Abstract: Durable, transparent, inorganic-organic hybrid hydrophobic coating materials for glass, metal or plastic substrates are provided. The coating materials are generally an acid catalyzed condensation reaction product comprised of an organic polymeric silane (e.g., a polyol functionalized with a silane through a urethane linkage or a polyamine functionalized with a silane through a urea linkage, such as isocyanatopropyltrimethoxysilane or isocyanatopropyltriethoxysilane), an inorganic metal alkoxide (e.g., silicon alkoxides such as tetraethoxysilane or tetramethoxysilane) and a fluorinated silane (e.g., (3,3,3-trifluoropropyl)trimethoxysilane or nonafluorohexyltrimethoxysilane).