Patents by Inventor Alan M. Malakoff
Alan M. Malakoff has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9695290Abstract: Films including a Layer A comprising 50.0 to 100.0 wt. %, based on the weight of the Layer A, of an ethylene-based polymer composition having therein a hafnium:zirconium (ppm/ppm) ratio >1.0, a CDBI less than 50%, and a g?vis?0.98; wherein the Layer A is substantially free of polyethylene having 0.50?g?vis?0.85 are described. Particular films are suitable as cast films for TD shrink and draw tape bag applications.Type: GrantFiled: September 30, 2013Date of Patent: July 4, 2017Assignee: ExxonMobil Chemical Patents Inc.Inventor: Alan M. Malakoff
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Patent number: 9493591Abstract: An ethylene-based polymer comprising about 80.0 to 99.0 wt. % of polymer units derived from ethylene and about 1.0 to about 20.0 wt. % of polymer units derived from one or more C3 to C20 ?-olefin comonomers; the ethylene-based polymer having: a CDBI of 60% to 80%; a melt index, I2.16, of about 4.0 to about 12.0 g/10 min.; a high-load melt index, I21.6, of 80.0 to about 160.0 g/10 min.; a melt index ratio (I21.6/I2.16) of 9.0 to 40.0; and a density of from about 0.910 to about 0.930 g/cm3. Articles, such as films, particularly suitable for use in pre-stretch applications, produced from such polymers and methods of making such articles are also provided.Type: GrantFiled: January 31, 2014Date of Patent: November 15, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventor: Alan M. Malakoff
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Publication number: 20160032035Abstract: An ethylene-based polymer comprising about 80.0 to 99.0 wt. % of polymer units derived from ethylene and about 1.0 to about 20.0 wt. % of polymer units derived from one or more C3 to C20 ?-olefin comonomers; the ethylene-based polymer having: a CDBI of 60% to 80%; a melt index, I2.16, of about 4.0 to about 12.0 g/10 min.; a high-load melt index, I21.6, of 80.0 to about 160.0 g/10 min.; a melt index ratio (I21.6/I2.16) of 9.0 to 40.0; and a density of from about 0.910 to about 0.930 g/cm3. Articles, such as films, particularly suitable for use in pre-stretch applications, produced from such polymers and methods of making such articles are also provided.Type: ApplicationFiled: January 31, 2014Publication date: February 4, 2016Inventor: Alan M. Malakoff
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Publication number: 20150291748Abstract: Films including a Layer A comprising 50.0 to 100.0 wt. %, based on the weight of the Layer A, of an ethylene-based polymer composition having therein a hafnium:zirconium (ppm/ppm) ratio>1.0, a CDBI less than 50%, and a g?vis?0.98; wherein the Layer A is substantially free of polyethylene having 0.50?g?vis?0.85 are described. Particular films are suitable as cast films for TD shrink and draw tape bag applications.Type: ApplicationFiled: September 30, 2013Publication date: October 15, 2015Inventor: Alan M. Malakoff
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Patent number: 8765874Abstract: Provided are ethylene-based polymer compositions, articles made therefrom, and methods of making the same. Ethylene-based polymer compositions include blends of a linear low density polyethylene prepared with metallocene catalyst and a low density polyethylene. The linear low density polyethylene may optionally have about five mole percent or less of monomer units derived from an alpha-olefin comonomer. Articles composed of such ethylene-based polymer compositions, such as blown films, exhibit favorable physical properties, including excellent optical properties and retained strength i.e., mitigation of expected decline in physical strength due to LDPE addition.Type: GrantFiled: January 28, 2008Date of Patent: July 1, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Alan M. Malakoff, Danny Van Hoyweghen, Hitesh A. Fruitwala
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Publication number: 20130266786Abstract: Polymer compositions including an ethylene-based polymer having a melt index of from about 0.1 g/10 min to about 5.0 g/10 min; a melt index ratio of from about 15 to about 30; a weight average molecular weight (Mw) of from about 20,000 to about 200,000; a molecular weight distribution (Mw/Mn) of from about 2.0 to about 4.5; and a density of from 0.900 to 0.920 g/cm3. Films having a thickness of 1 mil show a difference between the maximum seal strength and the minimum seal strength over the ranges of temperatures between 95.0° C. and 140.0° C. of ?1.00×102 grams/cm.Type: ApplicationFiled: March 12, 2013Publication date: October 10, 2013Applicant: ExxonMobil Chemical Patents Inc.Inventors: Alan M. Malakoff, Richard W. Halle, Adriana S. Silva, Steve A. Best
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Patent number: 7951873Abstract: This invention relates to blends of linear low density polyethylene copolymers with other linear low density polyethylenes or very low density, low density, medium density, high density, and differentiated polyethylenes. The invention also includes articles produced from the linear low density polyethylene and polyethylene blends described.Type: GrantFiled: April 18, 2007Date of Patent: May 31, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Steven Arthur Best, Paul Masten German, Jerry Michael Johnson, Alan M. Malakoff, Stefan Bertil Ohlsson
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Publication number: 20090192270Abstract: Provided are ethylene-based polymer compositions, articles made therefrom, and methods of making the same. Ethylene-based polymer compositions include blends of a linear low density polyethylene prepared with metallocene catalyst and a low density polyethylene. The linear low density polyethylene may optionally have about five mole percent or less of monomer units derived from an alpha-olefin comonomer. Articles composed of such ethylene-based polymer compositions, such as blown films, exhibit favorable physical properties, including excellent optical properties and retained strength i.e., mitigation of expected decline in physical strength due to LDPE addition.Type: ApplicationFiled: January 28, 2008Publication date: July 30, 2009Inventors: Alan M. Malakoff, Danny Van Hoyweghen, Hitesh A. Fruitwala
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Publication number: 20090156764Abstract: Provided are ethylene-based polymer compositions, articles made therefrom, and methods of making the same. Ethylene-based polymer compositions include linear low density polyethylene prepared with metallocene catalyst, which may optionally have about 5 mole percent or less of monomer units derived from an alpha-olefin comonomer. Ethylene-based polymer compositions include blends of linear low density polyethylene and one or more very low density polyethylene compositions, one or more low density polyethylene compositions, one or more medium density polyethylene compositions, one or more high density polyethylene compositions, one or more differentiated polyethylene compositions, or other conventional polymers. Articles composed of such ethylene-based polymer compositions are prepared according to a process window, e.g., at a specific extrusion rates, which provides favorable physical properties, including tear resistance and dart drop properties.Type: ApplicationFiled: December 18, 2007Publication date: June 18, 2009Inventors: Alan M. Malakoff, Danny Van Hoyweghen, Nicolas Kappes
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Patent number: 6932592Abstract: A very low density polyethylene having a density of 0.890 to 0.915 and a Dart Drop value of at least about 450 g/mil or above is disclosed. Gas phase polymerization methods are also disclosed for making very low density linear polyolefins utilizing a metallocene catalyst, and the resulting polyolefin products. In a specific embodiment, a gas phase polymerization process is disclosed relating to the formation of a linear polyethylene having a very low density, e.g., ranging from 0.890 to 0.915, but with improved toughness.Type: GrantFiled: June 22, 2001Date of Patent: August 23, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventors: James M. Farley, Richard W. Halle, George Panagopoulos, Jerry M. Johnson, Douglas J. Laurent, Alan M. Malakoff
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Patent number: 6800692Abstract: The present invention provides a polymer blend suitable for use as a film or a coating, the polymer blend including from 1 to 99% by weight of a metallocene-produced VLDPE polymer having a density less than 0.916 g/cm3, and from 1 to 99% by weight of an LDPE polymer having a density of from 0.916 to 0.928 g/cm3 wherein the sum of (a) and (b) is 100%. The VLDPE polymer can have a melt index of from 6 to 15 dg/min, or from 9 to 12 dg/min.Type: GrantFiled: March 24, 2003Date of Patent: October 5, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: James McLeod Farley, Richard Wayne Halle, George Panagopoulous, Donna Sue Davis, Douglas J. Laurent, Alan M. Malakoff, David M. Simpson, Kevin Cable
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Publication number: 20030215659Abstract: The present invention provides a polymer blend suitable for use as a film or a coating, the polymer blend including from 1 to 99% by weight of a metallocene-produced VLDPE polymer having a density less than 0.916 g/cm3, and from 1 to 99% by weight of an LDPE polymer having a density of from 0.916 to 0.928 g/cm3 wherein the sum of (a) and (b) is 100%. The VLDPE polymer can have a melt index of from 6 to 15 dg/min, or from 9 to 12 dg/min.Type: ApplicationFiled: March 24, 2003Publication date: November 20, 2003Inventors: James MacLeod Farley, Richard Wayne Halle, George Panagopoulos, Donna Sue Davis, Douglas J Laurent, Alan M Malakoff, David M Simpson, Kevin Cable
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Publication number: 20030213938Abstract: A very low density polyethylene having a density of 0.890 to 0.915 and a Dart Drop value of at least about 450 g/mil or above is disclosed. Gas phase polymerization methods are also disclosed for making very low density linear polyolefins utilizing a metallocene catalyst, and the resulting polyolefin products. In a specific embodiment, a gas phase polymerization process is disclosed relating to the formation of a linear polyethylene having a very low density, e.g., ranging from 0.890 to 0.915, but with improved toughness.Type: ApplicationFiled: December 13, 2002Publication date: November 20, 2003Inventors: James M. Farley, Richard W. Halle, George Panagopoulos, Jerry M. Johnson, Douglas J. Laurent, Alan M. Malakoff