Abstract: A method for improving wear control, while maintaining or improving solubility and fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component; and at least one metal salt of a carboxylic acid, as a minor component; wherein the metal salt of the carboxylic acid contains no sulfur or phosphorus; wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and mixtures thereof; wherein the carboxylic acid is selected from the group consisting of an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof; wherein the molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 1.0. The lubricating oils are useful in internal combustion engines.

Abstract: A system for in-situ identification of a working fluid disposed in at least one piece of equipment, the system including: a working fluid reservoir that contains the working fluid; an in-situ sensor disposed in the working fluid reservoir such that it detects properties of the working fluid or computes properties from the generated spectra of the working fluid; a transmitter that transmits the detected spectra of the working fluid and equipment identification information; and a cloud computing system that receives the detected spectra and the equipment identification information transmitted from the transmitter, wherein the cloud computing system compares the spectra and equipment identification information against a reference database to determine whether or not the spectra of the working fluid substantially matches the stored reference spectra associated with the expected or specified fluid for the equipment.

Abstract: Methods are provided for lubricating oxygenated diamond-like carbon surfaces to reduce friction while reducing or minimizing wear on the surface. A diamond-like carbon surface layer having a surface ratio of oxygen to carbon of 1:15 or more can be lubricated using a lubricant oil that includes a molybdenum-based friction modifier additive, a tungsten-based friction modifier additive, or a combination thereof. The Mo-based friction modifier (and/or other friction modifier based on a Group VI metal) can be selected based on the Gibbs free energy of adsorption (?G) for the friction modifier on an oxygenated diamond-like carbon surface. Use of a Group VI metal-based friction modifier having a ?G of adsorption with a sufficiently large magnitude can reduce friction at the surface of the oxygenated diamond-like carbon while causing a reduced or minimized amount of wear during lubrication.

Abstract: A method for improving wear control, while maintaining or improving fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and a mixture as a minor component of (i) at least one metal salt of a straight chain carboxylic acid, wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and combinations thereof, and (ii) at least one metal salicylate salt, wherein the metal is calcium (Ca), magnesium (Mg) or combinations thereof, wherein the molar ratio of the total metal concentration from the salicylate salt divided by the total metal concentration from the straight chain carboxylic acid ranges from 0.1 to 40. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control, while maintaining or improving solubility and fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component; and at least one metal salt of a carboxylic acid, as a minor component; wherein the metal salt of the carboxylic acid contains no sulfur or phosphorus; wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and mixtures thereof; wherein the carboxylic acid is selected from the group consisting of an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof; wherein the molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 1.0. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and encapsulated boron-containing microscale particles, as a minor component. The minor component preferably contains no metal or sulfur, and preferably no phosphorus. The encapsulated boron-containing microscale particles include an encapsulating material and a boron-containing compound encapsulated by the encapsulating material. The boron-containing compound is a boron oxide, a boric acid, or mixtures thereof. The encapsulating material is a carboxylic acid selected from an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and encapsulated microscale particles, as a minor component. The minor component contains no sulfur or phosphorus. The encapsulated microscale particles include an encapsulating material and a core material encapsulated by the encapsulating material. The core material includes at least one metal salt selected from a metal oxide, metal hydroxide, metal carbonate, or mixtures thereof. The encapsulating material is derived from a carboxylic acid selected from an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control, while maintaining or improving fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and (i) at least one transition metal salt of a carboxylic acid (e.g., zinc stearate) or (ii) a mixture of at least one transition metal salt of a carboxylic acid (e.g., zinc stearate) and at least one detergent (i.e., an alkali metal or alkaline earth metal salt of an organic acid, or an alkali metal or alkaline earth metal salt of an inorganic acid, or an alkali metal or alkaline earth metal salt of a phenol, or mixtures thereof (e.g., calcium salicylate and/or magnesium sulfonate)), as a minor component. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that includes a lubricating oil base stock as a major component; and at least one phosphazene represented by the formula as a minor component. In the above formula, Q is nitrogen, sulfur or oxygen; a is a value from about 2 to about 6, c is a value from about 2 to about 6, e is a value from about 2 to about 6, g is a value from about 2 to about 6, i is a value from about 2 to about 6, and k is a value from about 2 to about 6; b is a value of 2a+q, d is a value of 2c+r, f is a value of 2e+s, h is a value of 2g+t, j is a value of 2i+u, and l is a value of 2k+v; q, r, s, t, u and v are independently a value of 0 or ?2; with the proviso that not all of a, c, e, g, i and k are the same value.

Abstract: A system for in-situ identification of a working fluid disposed in at least one piece of equipment, the system including: a working fluid reservoir that contains the working fluid; an in-situ sensor disposed in the working fluid reservoir such that it detects properties of the working fluid or computes properties from the generated spectra of the working fluid; a transmitter that transmits the detected spectra of the working fluid and equipment identification information; and a cloud computing system that receives the detected spectra and the equipment identification information transmitted from the transmitter, wherein the cloud computing system compares the spectra and equipment identification information against a reference database to determine whether or not the spectra of the working fluid substantially matches the stored reference spectra associated with the expected or specified fluid for the equipment.

Abstract: A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that includes a lubricating oil base stock as a major component; and at least one phosphazene represented by the formula as a minor component. In the above formula, Q is nitrogen, sulfur or oxygen; a is a value from about 2 to about 6, c is a value from about 2 to about 6, e is a value from about 2 to about 6, g is a value from about 2 to about 6, i is a value from about 2 to about 6, and k is a value from about 2 to about 6; b is a value of 2a+q, d is a value of 2c+r, f is a value of 2e+s, h is a value of 2g+t, j is a value of 2i+u, and l is a value of 2k+v; q, r, s, t, u and v are independently a value of 0 or ?2; with the proviso that not all of a, c, e, g, i and k are the same value.

Abstract: A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and encapsulated microscale particles, as a minor component. The minor component contains no sulfur or phosphorus. The encapsulated microscale particles include an encapsulating material and a core material encapsulated by the encapsulating material. The core material includes at least one metal salt selected from a metal oxide, metal hydroxide, metal carbonate, or mixtures thereof. The encapsulating material is derived from a carboxylic acid selected from an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and encapsulated boron-containing microscale particles, as a minor component. The minor component preferably contains no metal or sulfur, and preferably no phosphorus. The encapsulated boron-containing microscale particles include an encapsulating material and a boron-containing compound encapsulated by the encapsulating material. The boron-containing compound is derived from a boron powder, a boron alkoxide, a boron oxide, a boric acid, a borane, or mixtures thereof. The encapsulating material is derived from a carboxylic acid selected from an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control, while maintaining or improving fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and (i) at least one transition metal salt of a carboxylic acid (e.g., zinc stearate) or (ii) a mixture of at least one transition metal salt of a carboxylic acid (e.g., zinc stearate) and at least one detergent (i.e., an alkali metal or alkaline earth metal salt of an organic acid, or an alkali metal or alkaline earth metal salt of an inorganic acid, or an alkali metal or alkaline earth metal salt of a phenol, or mixtures thereof (e.g., calcium salicylate and/or magnesium sulfonate)), as a minor component. The lubricating oils are useful in internal combustion engines.

Abstract: A method for improving wear control, while maintaining or improving fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and a mixture of (i) at least one carboxylic acid or metal salt of a carboxylic acid (e.g., metal stearate or stearic acid), and (ii) at least one surfactant (e.g., nonionic surfactant), as a minor components. A method for improving solubility, compatibility and dispersancy of polar additives in a lubricating oil is also provided. A lubricating oil having a composition including a lubricating oil base stock as a major component, and a mixture of (i) at least one carboxylic acid or metal salt of a carboxylic acid, and (ii) at least one surfactant, as minor components. The lubricating oils are useful in internal combustion engines.

Abstract: A method for determining and identifying corrosion protective layers that provide corrosion protection against crude oils and crude oil fractions is disclosed. The method identifies naturally occurring constituents in crude oils that indirectly provide corrosion protection. A method assessing the potential of these constituents is also disclosed. The method includes exposing metal coupons with the crude oil or crude fraction of interest at the expected operating temperature of concern. The corrosion potential assessment further analyzes the exposed coupons with transmission electron microscopy and an additional high temperature exposure that challenges the tenacity of the protection offered by the corrosion protective layer.

Abstract: A method for determining and identifying corrosion protective layers that provide corrosion protection against crude oils and crude oil fractions is disclosed. The method identifies naturally occurring constituents in crude oils that indirectly provide corrosion protection. A method assessing the potential of these constituents is also disclosed. The method includes exposing metal coupons with the crude oil or crude fraction of interest at the expected operating temperature of concern. The corrosion potential assessment further analyzes the exposed coupons with transmission electron microscopy and an additional high temperature exposure that challenges the tenacity of the protection offered by the corrosion protective layer.

Abstract: Mechanical oscillators employ the use of resonance parameters, frequency and the quality factor Q, for the measurement of corrosion or deposition. The ability of a mechanical oscillator to measure small amounts of metal loss or deposition is not only dependent upon the mechanical design but is limited by the precision in determining the resonance frequency and Q. Methods for measuring these resonance parameters with a high precision in the presence of noise are provided. The increased degree of precision improves the utility of these devices as sensitive probes for corrosion and deposition (fouling) measurement. The increased degree of precision is enabled in part by employing curve fitting consistent with modeling the mechanical oscillator as a simple harmonic oscillator. This curve fitting procedure, combined with averaging and utilizing signal processing parameters to mitigate noise effects, adds precision in measuring resonance parameters.

Abstract: The prior art describes the application of mechanical oscillators for the measurement of corrosion and/or deposition. Mechanical oscillators employ the use of resonance parameters, frequency and the quality factor Q, for the measurement of corrosion or deposition. However, the prior art does not consider the required precision for measuring frequency or Q in the presence of noise to make these measurements. In particular, the ability of the mechanical oscillator to measure small amounts of metal loss or deposition is not only dependent upon the mechanical design but is limited by the precision in determining the resonance frequency and Q. The present invention discloses methods for measuring these resonance parameters with a high precision in the presence of noise. This degree of precision is required to maximize the utility of these devices as sensitive probes for corrosion and deposition (fouling) measurement.

Abstract: The present invention provides systems and methods for determining the viscosity of a lubricating fluid in a process on line. The method of the present invention obviates the need to accurately control the temperature of the lubricating fluid in the system when taking fluid viscosity measurements.