Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising N-butoxycarbonyl-O-butylthionocarbamate.

Abstract: Collector compositions of a mixture of a C6 to C22 fatty hydroxamic acid and an oil for use in a method the removal of impurities from mineral ores by the froth flotation method. The collectors are prepared by reacting an ester of a C6 to C22 fatty acid with a hydroxylamine salt and a base in the presence of an oil and water to produce an alkyl hydroxamate salt; acidifying the alkyl hydroxamate salt, forming an organic layer and an aqueous layer, wherein the organic layer contains a C6 to C22 fatty hydroxamic acid substantially free of starting esters and hydrolysis and transesterification products of the ester; and separating the organic layer from the aqueous layer to provide a collector composition of the C6 to C22 fatty hydroxamic acid and the oil.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising N-butoxycarbonyl-O-butylthionocarbamate.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising N-butoxycarbonyl-O-butylthionocarbamate.

Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising an N-butoxycarbonyl-O-alkylthionocarbamate selected from the group consisting of N-butoxycarbonyl-O-methylthionocarbamate, N-butoxycarbonyl-O-ethylthionocarbamate, N-butoxycarbonyl-O-propylthiononocarbamate, N-butoxycarbonyl-O-butylthionocarbamate, N-butoxycarbonyl-O-pentylthionocarbamate, and N-butoxycarbonyl-O-hexylthionocarbamate.

Abstract: Materials and a process are provided whereby polymers with the pendant group or end group containing —Si (OR″)3 (where R″ is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in a Bayer process. When materials of the present invention are added to the Bayer liquor before the heat exchangers, they reduce and even completely prevent formation of aluminosilicate scale on heat exchanger walls. The present materials are effective at treatment concentrations that make them economically practical.

Abstract: Collector compositions of a mixture of a C6 to C22 fatty hydroxamic acid and an oil for use in a method the removal of impurities from mineral ores by the froth flotation method. The collectors are prepared by reacting an ester of a C6 to C22 fatty acid with a hydroxylamine salt and a base in the presence of an oil and water to produce an alkyl hydroxamate salt; acidifying the alkyl hydroxamate salt, forming an organic layer and an aqueous layer, wherein the organic layer contains a C6 to C22 fatty hydroxamic acid substantially free of starting esters and hydrolysis and transesterification products of the ester; and separating the organic layer from the aqueous layer to provide a collector composition of the C6 to C22 fatty hydroxamic acid and the oil.

Abstract: Collector compositions of a mixture of a C6 to C22 fatty hydroxamic acid and an oil for use in a method for the removal of impurities from mineral ores by the froth flotation method. The collectors are prepared by reacting an ester of a C6 to C22 fatty acid with a hydroxylamine salt and a base in the presence of an oil and water to produce an alkyl hydroxamate salt; acidifying the alkyl hydroxamate salt, forming an organic layer and an aqueous layer, wherein the organic layer contains a C6 to C22 fatty hydroxamic acid substantially free of starting esters and hydrolysis and transesterification products of the ester; and separating the organic layer from the aqueous layer to provide a collector composition of the C6 to C22 fatty hydroxamic acid and the oil.

Abstract: A process for the flocculation of impurities from clays in which the following steps are performed: blunging the clay with a dispersing agent or combination of dispersing agents in water to form an aqueous dispersion, treating the aqueous dispersion with at least one aliphatic or aromatic hydroxamic acid or salt conditioning agent, flocculating the conditioned dispersion with a water soluble or water dispersible organic polymer containing hydroxamic acid groups or salts thereof, and removing the flocculated impurities to form a purified clay dispersion.

Abstract: An improved process for the selective flocculation of impurities from clays is disclosed. The process comprises blunging the clay in the presence of dispersing agents, conditioning the blunged clay with aliphatic or aromatic hydroxamic acids, or salts thereof, flocculating the impurities with a high molecular weight polymeric flocculant, particularly polymers containing hydroxamate groups, and removing the flocculated impurities from the unflocculated clay. The use of hydroxamic conditioning agents improves the removal of impurities from the clay, thereby providing a clay product having high brightness and low level impurities. The hydroxamic acid conditioning agents may advantageously be used in combination with other conditioning additives and with a wide variety of polymeric flocculating agents.

Abstract: Collector compositions of a mixture of a C.sub.6 to C.sub.22 fatty hydroxamic acid and an oil for use in the removal of impurities from mineral ores by the froth flotation method. The collectors are prepared by reacting an ester of a C.sub.6 to C.sub.22 fatty acid with a hydroxylamine salt and a base in the presence of an oil and water to produce an alkyl hydroxamate salt; acidifying the alkyl hydroxamate salt, forming an organic layer and an aqueous layer, wherein the organic layer contains a C.sub.6 to C.sub.22 fatty hydroxamic acid substantially free of starting esters and hydrolysis and transesterification products of the ester; and separating the organic layer from the aqueous layer to provide a collector composition of the C.sub.6 to C.sub.22 fatty hydroxamic acid and the oil.

Abstract: A process is disclosed for the formation of highly anionic hydroxamic acid polymers whereby (meth) acrylic acid polymers are esterified in aqueous solution to poly (meth) acrylates. The resultant polymers are then reacted with an hydroxylamine to produce hydroxamated (meth) acrylic acid containing polymers. The esterified polymers, their hydroxamated derivatives and their use to flocculate Bayer Process streams are also disclosed.

Abstract: The processing of bauxite in the Bayer Process results in the formation of titanaceous, siliceous, and other scale on equipment and apparatus such that a great deal of time and effort is spent in order to maintain the process at its height efficiency by reducing or eliminating the same. The scale is treated, reduced, altered, etc., according to the present invention by the use of hydroxamated polymers having weight average molecular weights ranging from about 1,000 to less than about 10,000.

Abstract: The processing of bauxite in the Bayer Process results in the formation of titanaceous, siliceous, and other scale on equipment and apparatus such that a great deal of time and effort is spent in order to maintain the process at its height efficiency by reducing or eliminating the same. The scale is treated, reduced, altered, etc., according to the present invention by the use of hydroxamated polymers having weight average molecular weights of over about 10,000.

Abstract: Metal ions are removed from solution by contacting the solution with a combination of a water-soluble cationic polymer and a water-soluble polymer containing pendant hydroxamic acid or salt groups.

Abstract: A process for flocculating, in a liquid other than Bayer process streams, suspended solids comprised primarily of minerals other than iron oxide and tin oxide. The solids are contacted with a hydroxamated polymer. The amount of hydroxamated polymer is sufficient to increase the settling rate of the solids and to decrease the turbidity of the solids.

Abstract: A novel polymer composition comprising recurring units of the formula: ##STR1## wherein each R.sup.1 is, individually, hydrogen or C.sub.1 -C.sub.4 alkyl; each R.sup.5, individually, is hydrogen or a C.sub.1 -C.sub.4 lower alkyl group; X is OH or SH; Y is OR.sup.2, SR.sup.2, NR.sub.2.sup.2, or NR.sup.2 -NR.sub.2.sup.2 ; R.sup.2 is hydrogen, a C.sub.1 -C.sub.4 lower alkyl or a C.sub.1 -C.sub.4 substituted lower alkyl, no more than one of Y and X being hydroxyl, and M is hydrogen, an alkali metal cation or an ammonium ion; x represents a residual mole percent fraction; y is a mole percent fraction ranging from about 0.5% to about 25%; z is a mole percent fraction ranging from about 0% to about 25%; and the molecular weight of the polymer is between about 1,000 and 500,000.

Abstract: A process for the froth flotation separation of value sulfide minerals from gangue iron sulfide minerals in which a novel terpolymer of copolymer of acylamide, acrylic acid and/or derivatives of acrylamide and acrylic acid is employed as a depressant for the gangue iron sulfide minerals.

Abstract: An improved method of separating non-sulfide value minerals from non-sulfide ores is disclosed. The improved method includes the step of adding a depressant selective for siliceous gangue minerals and materials to a flotation slurry previously conditioned with an anionic collector. In preferred embodiments, the depressants comprise copolymers or terpolymers derived from acrylamide units and N-acrylamidoglycolic acid units. The method provides generally improved recoveries of non-sulfide value minerals at higher grade, in a reduced number of flotation steps and at reduced consumption levels of flotation reagents.

Abstract: The iron content of Bayer process streams is reduced by contacting said stream with a tertiary hydroxyl-containing polyamine.