Abstract: A reactor system includes a fluidized-bed. A fuel and a sulfur absorbent material are eluted through the fluidized-bed. The reactor system may include a heat exchanger having a heat-exchanging portion within a heating zone of the reactor that is hermetically sealed from the heating zone. The reactor may include loose particles of an inert bed material for forming the fluidized-bed. A feed system may be provided to inject a solid fuel composite that includes a mixture of a solid, carbonaceous fuel and a solid reagent into the reactor.

Abstract: A reactor system includes a fluidized-bed. A fuel and a sulfur absorbent material are eluted through the fluidized-bed. The reactor system may include a heat exchanger having a heat-exchanging portion within a heating zone of the reactor that is hermetically sealed from the heating zone. The reactor may include loose particles of an inert bed material for forming the fluidized-bed. A feed system may be provided to inject a solid fuel composite that includes a mixture of a solid, carbonaceous fuel and a solid reagent into the reactor.

Abstract: A reactor system includes a fluidized-bed. A fuel and a sulfur absorbent material are eluted through the fluidized-bed. The reactor system may include a heat exchanger having a heat-exchanging portion within a heating zone of the reactor that is hermetically sealed from the heating zone. The reactor may include loose particles of an inert bed material for forming the fluidized-bed. A feed system may be provided to inject a solid fuel composite that includes a mixture of a solid, carbonaceous fuel and a solid reagent into the reactor.

Abstract: A method for in situ extraction of hydrocarbon materials in a subsurface region includes increasing permeability of a low permeability hydrocarbon-containing subsurface region to create a first well sub-region and a second well sub-region vertically below the first well sub-region. The first well sub-region is heated to extract liquid hydrocarbon materials that flow to the second well sub-region. The liquid hydrocarbon materials are then transported from the second well sub-region.

Abstract: An injection device transfers calcium carbonate particles for regeneration into calcium oxide. The device includes an injector body having an inlet end which receives a heated air volume, and a discharge end. At least one transfer tube disposed through a portion of the injector body discharges the calcium carbonate particles at the discharge end. At least one flow nozzle receives the heated air volume and discharges the heated air volume at the discharge end. Each flow nozzle is angularly oriented to directly impinge the plurality of calcium carbonate particles discharged from the transfer tube with the heated air volume. A flow splitter can also be connected to the device to split the calcium carbonate particles into multiple flow streams.

Abstract: A gas generator includes a high pressure gas-generation system that is capable of generating a product gas stream at a non-ambient, elevated nominal pressure. A thermal swing absorber has a first configuration and a second configuration relative to being connected with the product gas stream. In the first configuration, the thermal swing absorber is connected with the high pressure gas-generation system to receive the product gas stream and remove a constituent gas from the stream. In the second configuration, the thermal swing absorber is disconnected from the product gas stream and releases the constituent gas at a pressure that is substantially equal to the elevated nominal pressure. In the second configuration, the thermal swing absorber is an input source to provide the released constituent gas into the high pressure gas-generation system, which permits more efficient use of materials within the system.

Abstract: A reactor system includes a fluidized bed reactor with a fluidized zone having sorbent particles and catalyst particles. The sorbent particles are sized to become entrained in a product stream from the fluidized zone and the catalyst particles are sized to gravimetrically stay within the fluidized zone.

Abstract: A system for substantially continuously providing a solid material, for example pulverized coal, to a pressurized container. The system provides the solid material to a first container of a first pressure elevated above an initial pressure of the solid material. Generally, a screw conveyor augmented with a jet port is used to move the material where the jet port provides a gas to provide a make-up volume of the solid material. The system also provides the material to a second high pressure container after the material has been formed into a slurry. Therefore, the solid material may be substantially continuously provided in a system to a high pressure container.

Abstract: A method for regenerating a solid reactant includes streaming the solid reactant into an inlet port of a contact or vessel and heating the solid reactant inside the contactor vessel, streaming a purge oxidant into an oxidant port of the contactor vessel to reduce a partial pressure of gas released from the solid reactant, venting the gas from a gas port of the contactor vessel, and removing the solid reactant from a discharge port of the contactor vessel.

Abstract: A reactor system includes a fluidized-bed. A fuel and a sulfur absorbent material are eluted through the fluidized-bed. The reactor system may include a heat exchanger having a heat-exchanging portion within a heating zone of the reactor that is hermetically sealed from the heating zone. The reactor may include loose particles of an inert bed material for forming the fluidized-bed. A feed system may be provided to inject a solid fuel composite that includes a mixture of a solid, carbonaceous fuel and a solid reagent into the reactor.

Abstract: A fluidized-bed reactor for producing hydrogen from methane by steam reforming includes a flow splitter that splits a dense-phase flow of a gas having entrained calcium oxide particles into a plurality of equal flow streams. The reactor also incorporates an orifice plate having at least one high-velocity, rocket-style impinging injector for injecting reactants into the reactor bed. The injector includes a central orifice extending perpendicularly through the plate, and one or more adjacent peripheral orifices that extend through the plate at such an angle that respective streams of reactants injected into the reactor bed through the peripheral orifices impinge on a stream of reactants injected vertically into the reactor bed through the central orifice. The injector cooperates with adjacent base-bleed orifices in the plate to provide a uniform distribution and rapid mixing of the calcium oxide particles with a steam/methane gas mixture across the entire bottom of the reactor bed.

Abstract: A reactor system includes a fluidized bed reactor with a fluidized zone having sorbent particles and catalyst particles. The sorbent particles are sized to become entrained in a product stream from the fluidized zone and the catalyst particles are sized to gravimetrically stay within the fluidized zone.

Abstract: A calcining system includes a calcining chamber of a sufficient length to effect a desired level of calcination of solid particles. A hot gas source to communicate hot gases within the calcining chamber. An entrainment gas source operable to communicate an entrainment gas to transport the solid particles into the calcining chamber to calcine the solid particles to form calcined solid particles.

Abstract: A gas generator includes a high pressure gas-generation system that is capable of generating a product gas stream at a non-ambient, elevated nominal pressure. A thermal swing absorber has a first configuration and a second configuration relative to being connected with the product gas stream. In the first configuration, the thermal swing absorber is connected with the high pressure gas-generation system to receive the product gas stream and remove a constituent gas from the stream. In the second configuration, the thermal swing absorber is disconnected from the product gas stream and releases the constituent gas at a pressure that is substantially equal to the elevated nominal pressure. In the second configuration, the thermal swing absorber is an input source to provide the released constituent gas into the high pressure gas-generation system, which permits more efficient use of materials within the system.

Abstract: A system for substantially continuously providing a solid material, for example pulverized coal, to a pressurized container. The system provides the solid material to a first container of a first pressure elevated above an initial pressure of the solid material. Generally, a screw conveyor augmented with a jet port is used to move the material where the jet port provides a gas to provide a make-up volume of the solid material. The system also provides the material to a second high pressure container after the material has been formed into a slurry. Therefore, the solid material may be substantially continuously provided in a system to a high pressure container.

Abstract: A fluidized-bed reactor for producing hydrogen from methane by steam reforming includes a flow splitter that splits a dense-phase flow of a gas having entrained calcium oxide particles into a plurality of equal flow streams. The reactor also incorporates an orifice plate having at least one high-velocity, rocket-style impinging injector for injecting reactants into the reactor bed. The injector includes a central orifice extending perpendicularly through the plate, and one or more adjacent peripheral orifices that extend through the plate at such an angle that respective streams of reactants injected into the reactor bed through the peripheral orifices impinge on a stream of reactants injected vertically into the reactor bed through the central orifice. The injector cooperates with adjacent base-bleed orifices in the plate to provide a uniform distribution and rapid mixing of the calcium oxide particles with a steam/methane gas mixture across the entire bottom of the reactor bed.

Abstract: Hydrogen gas is produced by reacting a carbon-hydrogen-containing species with water provided as a water reforming inflow at a reforming temperature to produce a primary reacted gas flow containing hydrogen gas. The carbon-hydrogen-containing species and water are heated to the reforming temperature with solar energy. The heating is preferably performed by heating a molten metal to at least the reforming temperature with solar energy, and using the molten metal to heat the carbon-hydrogen-containing species and water to at least the reforming temperature. The water reforming inflow is preheated by heat exchange from the primary reacted gas flow. The primary reacted gas flow is reacted with water to produce additional hydrogen gas in a secondary reacted gas flow.

Abstract: A method and apparatus are disclosed for regenerating calcium oxide used in the production of hydrogen gas. The method includes steps of: (a) streaming a solid reactant into an inlet port of a contactor vessel; (b) streaming a purge oxidant into an oxidant port of the contactor vessel to reduce a partial pressure of a gas over the solid reactant; (c) venting the gas from a gas port of the contactor vessel; and (d) removing the solid reactant from a discharge port of the contactor vessel.

Abstract: A method and apparatus are disclosed for regenerating calcium oxide used in the production of hydrogen gas. The method includes steps of: (a) streaming a solid reactant into an inlet port of a contactor vessel; (b) streaming a purge oxidant into an oxidant port of the contactor vessel to reduce a partial pressure of a gas over the solid reactant; (c) venting the gas from a gas port of the contactor vessel; and (d) removing the solid reactant from a discharge port of the contactor vessel.

Abstract: A screw feeder can be used to transport a high temperature particulate material. A housing contains the material within the screw feeder which includes an inlet and an outlet port. A screw is rotatably positioned within the housing to advance the material from the inlet port to the outlet port, which rotates axially. A labyrinth seal can be formed around and in communication with the screw to eliminate reverse movement of the material. A cooling medium can be directed into contact with at least the housing. A fluid can be injected through the screw to prevent blockage of the particulate material. A pressure differential is created from the inlet to the outlet port of at least 0.069 MPad.