Patents by Inventor Albert I. Yezrielev
Albert I. Yezrielev has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6103826Abstract: Clearcoat compositions using a phenolic ester compound are described. The phenolic ester compound is selected from the group consisting of a phenolic ester alcohol, a phenolic urethane, a phenolic blocked isocyanate, and mixtures thereof.Type: GrantFiled: January 29, 1997Date of Patent: August 15, 2000Assignee: Eastern Michigan UniversityInventors: Frank N. Jones, Vijay Swarup, Albert I. Yezrielev, Ramachandran P. Subrayan
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Patent number: 6087464Abstract: The present invention is directed to a polymeric vehicle, a formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a polyol, an isocyanate compound and a phenolic ester alcohol having at least one aliphatic hydroxyl group and at least one phenolic hydroxyl group.Type: GrantFiled: March 21, 1996Date of Patent: July 11, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Vijay Swarup, Frank N. Jones, Albert I. Yezrielev, Ramachandran P. Subrayan
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Polymeric vehicles which include a phenol blocked isocyanate having aliphatic hydroxyl fucntionality
Patent number: 6051674Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenol blocked isocyanate having reactive aliphatic hydroxyl groups. The phenol blocked isocyanate may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group and one phenolic hydroxyl group.Type: GrantFiled: August 26, 1996Date of Patent: April 18, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Albert I. Yezrielev, Frank N. Jones, Ramachandran P. Subrayan, Vijay Swarup -
Patent number: 5717039Abstract: A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.Type: GrantFiled: June 6, 1995Date of Patent: February 10, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Joseph Victor Cusumano, William Daniel Diana, Jacob Emert, Keith Raymond Gorda, Richard H. Schlosberg, David A. Young, Albert I. Yezrielev, William Bernard Eckstrom, Edris Eileen Manry, Michael John Keenan
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Patent number: 5703256Abstract: A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.Type: GrantFiled: December 16, 1996Date of Patent: December 30, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Joseph Victor Cusumano, William Daniel Diana, Jacob Emert, Keith Raymond Gorda, Richard H. Schlosberg, David A. Young, Albert I. Yezrielev, William Bernard Eckstrom, Edris Eileen Manry, Michael John Keenan
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Patent number: 5631330Abstract: Non liquid-crystalline esterphenol-capped liquid polymer and polyol compositions in combination with an amino crosslinking agent endow coating compositions containing them with the ability of providing films having superior properties. The esterphenol-capped polymers and polyols can be prepared by direct esterification of hydroxybenzoic acid without its decarboxylation.Type: GrantFiled: June 7, 1995Date of Patent: May 20, 1997Assignee: Exxon Chemical Patents, Inc.Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, George A. Knudsen, Michael G. Romanelli
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Patent number: 5536794Abstract: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.Type: GrantFiled: December 27, 1994Date of Patent: July 16, 1996Assignee: Exxon Chemical Patents Inc. (ECPI)Inventors: Albert I. Yezrielev, William E. Wellman
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Patent number: 5458920Abstract: The invention relates to the use of polybasic acids as gloss reduction agents in the preparation of paint or coating compositions based on hydroxy or phenolic functional resins and also containing an amino crosslinking agent and a pigment. Cured coatings exhibiting good flexibility, hardness and solvent resistance, as well as reduced or controllable gloss are obtained.Type: GrantFiled: May 20, 1994Date of Patent: October 17, 1995Assignee: Exxon Chemical Patents, Inc.Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, Robert N. Sachs
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Patent number: 5453469Abstract: Non liquid-crystalline esterphenol-capped liquid polymer and polyol compositions in combination with an amino crosslinking agent endow coating compositions containing them with the ability of providing films having superior properties. The esterphenol-capped polymers and polyols can be prepared by direct esterification of hydroxybenzoic acid without its decarboxylation.Type: GrantFiled: July 22, 1993Date of Patent: September 26, 1995Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, George A. Knudsen, Michael G. Romanelli
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Patent number: 5334652Abstract: The present invention is directed towards liquid coating formulations containing a mixture of a curable polyester or diester resin, an amino crosslinking agent and a pigment wherein the pigment is dispersed in the coating solution at a weight loading level such that the pigment to binder ratio falls within the range of from 1.25 to 1 up to about 5.0 to 1. The polyester or diester resins employed in the coating formulations are such that when formulated with an appropriate crosslinking agent, acid catalyst and pigment within the ranges stated above and properly applied to a substrate and cured, produce coatings having a minimum Knoop hardness of at least about 4 and a flexibility (T-bend test) of less than 6, generally less than about 5, and a MEK rub value of greater than 5, more preferably at least about 15 and most preferably greater than 50.Cured coating compositions prepared in accordance with this invention exhibit all of the attributes considered essential for coil coatings, i.e.Type: GrantFiled: June 18, 1991Date of Patent: August 2, 1994Assignee: Exxon Chemical Patents, Inc.Inventors: William E. Wellman, Albert I. Yezrielev, Ralph M. Kowalik
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Patent number: 5334671Abstract: The present invention is directed towards a mixture of phenol terminated diesters and an amino crosslinking agent. The diesters are characterized by a structure consisting of ##STR1## wherein R is an aliphatic divalent hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, provided however that R contains at least about 8 carbon atoms when n is 0 and p is 0, R.sub.1 is an aliphatic or cycloaliphatic hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, R.sub.2 is a aliphatic, aromatic or a mixture of aliphatic and aromatic hydrocarbon radicals having from 2 to 40 carbon atoms, A is divalent aromatic radical selected from the group consisting of phenylene, naphthylene or bis phenylene, p is 0 or 1, n is 0 or an integer ranging from 1 to about 40, provided however, that p is 0 when n is 0 and p is 1 when n is an integer and ##STR2## wherein q is an integer ranging from 1 to about 40, n is 0 or an integer ranging from 1 to about 40 and A, R.sub.1 and R.Type: GrantFiled: January 15, 1993Date of Patent: August 2, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, George A. Knudsen, Michael G. Romanelli
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Patent number: 5326831Abstract: The present invention is directed towards a process for preparing non-liquid crystalline phenol-terminated diester compositions characterized by the structure of formula 1: ##STR1## wherein R is an aliphatic divalent hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, provided however that R contains at least about 8 carbon atoms when n is 0 and p is 0, R.sub.1 is an aliphatic or cycloaliphatic hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, R.sub.2 is an aliphatic, aromatic or a mixture of aliphatic and aromatic hydrocarbon radicals having from 2 to 40 carbon atoms, A is divalent aromatic radical selected from the group consisting of phenylene, naphthylene or his phenylene, p is 0 or 1, n is 0 or an integer ranging from 1 to about 40, provided however, that p is 0 when n is 0 and p is 1 when n is an integer.Type: GrantFiled: January 19, 1993Date of Patent: July 5, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, George A. Knudsen, Michael G. Romanelli
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Patent number: 5322884Abstract: The present invention is directed towards liquid coating formulations containing a mixture of a curable polyester or diester resin, an amino crosslinking agent and a pigment wherein the pigment is dispersed in the coating solution at a weight loading .level such that the pigment to binder ratio falls within the range of from greater than 2.0 to 1 up to about 5.0 to 1. The polyester or diester resins employed in the coating formulations are such that when formulated with an appropriate crosslinking agent, acid catalyst and pigment within the ranges stated above and properly applied to a substrate and cured, produce coatings having a minimum Knoop hardness of at least about 4 and a flexibility (T-bend test) of less than 6, generally less than about 5, and a MEK rub value of greater than 5, more preferably at least about 15 and most preferably greater than 50.Type: GrantFiled: January 6, 1993Date of Patent: June 21, 1994Assignee: Exxon Chemical Patents Inc.Inventors: William E. Wellman, Albert I. Yezrielev, Ralph M. Kowalik
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Patent number: 5239018Abstract: Non liquid-crystalline esterphenol-capped liquid polymer and polyol compositions in combination with an amino crosslinking agent endow coating compositions containing them with the ability of providing films having superior properties. The esterphenol-capped polymers and polyols can be prepared by direct esterification of hydroxybenzoic acid without its decarboxylation.Type: GrantFiled: June 22, 1990Date of Patent: August 24, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, George A. Knudsen, Michael G. Romanelli
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Patent number: 5210155Abstract: The present invention is directed towards non-liquid crystalline phenol-terminated diester compositions which may be liquids or solids and crosslinkable formulations containing a mixture of the phenol terminated diesters and an amino crosslinking agent. These diesters are characterized by the structure of formula 1: ##STR1## wherein R is an aliphatic divalent hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, provided however that R contains at least about 8 carbon atoms when n is 0 and p is 0, R.sub.1 is an aliphatic or cycloaliphatic hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, R.sub.Type: GrantFiled: August 24, 1990Date of Patent: May 11, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, William E. Wellman, Ralph M. Kowalik, George A. Knudsen, Michael G. Romanelli
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Patent number: 5166289Abstract: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.The crosslinkable compositions of this invention may be used to prepare curable coating and paint formulations, and also may contain other ingredients such as a crosslinking catalyst, fillers, pigments and the like.Type: GrantFiled: December 19, 1990Date of Patent: November 24, 1992Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, William E. Wellman
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Patent number: 5034154Abstract: According to one aspect of the present invention, an improved method for preparing acrylic copolymer resins is provided in which the polymerization solvent includes an internal olefin. The monomers comprise hydroxy-substituted alkyl (meth)acrylates, and non-hydroxy substituted alky (meth)acrylates, and the process provides an improved method for forming low molecular weight acrylic resins useful as components in high solids acrylic coatings suitable for electrostatic spraying. The polymerization solvent can remain in the resin to become the solvent employed in the higher solids coating containing the thus-forming acrylic resins and provides surprisingly improved electrical resistivity and color decreased over previously used polymerization solvents, and has good compatibility with the acrylic monomer/resin system.Type: GrantFiled: July 18, 1988Date of Patent: July 23, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, Michael G. Romanelli, William E. Wellman, Richard H. Schlosberg
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Patent number: 4985517Abstract: According to one aspect of the present invention, improved acrylic copolymer resins are provided which are formed by co-polymerization of a monomer mixture comprising hydroxy-substituted alkyl (meth)acrylates, alkyl methacrylates or vinyl aromatics, and higher alpha-olefins. The invention provides improved low molecular weight acrylic resins useful as components in high solids acrylic coatings suitable for electrostatic spraying.Type: GrantFiled: June 2, 1989Date of Patent: January 15, 1991Assignee: Exxon Chemical Patents, Inc.Inventors: Albert I. Yezrielev, Michael G. Romanelli, William E. Wellman
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Patent number: 4855369Abstract: According to one aspect of the present invention, improved acrylic copolymer resins are provided which are formed by co-polymerization of a monomer mixture comprising hydroxy-substituted alkyl (meth)acrylates, alkyl methlacrylates or vinyl aromatics, and higher alpha-olefins. The invention provides improved low molecular weight acrylic resins useful as components in high solids acrylic coatings suitable for electrostatic spraying.Type: GrantFiled: June 6, 1988Date of Patent: August 8, 1989Assignee: Exxon Chemical Patents Inc.Inventors: Albert I. Yezrielev, Michael G. Romanelli, William E. Wellman