Abstract: There is disclosed a process for the production of carbon disulfide and hydrogen sulfide from a particulate carbon source. In one embodiment, an oxygen containing gas is reacted with a particulate carbon source in a one step process so as to provide the temperatures necessary for the reaction of the particulate carbon source with sulfur to produce carbon disulfide. In another embodiment, a source of hydrogen is introduced along with the oxygen containing gas and sulfur so as to produce hydrogen sulfide in a single step process.

Abstract: A fluidized bed boiler having a water-wall type construction has a steam-water natural circulation system for heat exchange. Vertical in-bed heat exchange tubes are provided and the steam drum of the boiler extends across the full length of the boiler combustion chamber and the convection heat exchange chamber. An air distributor grate is provided for introduction of fluidizing air into the combustion chamber and the air flow therefrom can be controlled to afford a flexible turn-down capability.

Abstract: Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

Abstract: A fluid bed heater or vaporizer unit has a generally cylindrical configuration with its major axis horizontally disposed. A mixture of coal and limestone is fed into the elongated fluidized bed within the unit for combustion; the limestone being present to minimize sulfur emissions due to the sulfur present in the coal. The wall of the unit in the region of the freeboard is lined with horizontally disposed heat exchange tubing. The delivery of air to the fluidized bed is regulated so as to establish a combustion zone of high turbulence and one or more heat transfer zones of lower turbulence. A plurality of heat exchange tubes are located in the heat transfer zone or zones and within the expanded bed level of the fluidized bed but above the region occupied by the slumped bed. Economizer heat exchange coils may be located in the passageway for exhaust gases.

Abstract: A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.