Abstract: An electrochemical device suitable to work both as electrolyser and fuel cell has a housing (10), a central tubular electrode (11) provided with a plurality of through holes (13) and having a first electrical connector (6) that is connected to an electrical supply or an electrical load, a first gas diffusion layer or GDL (2), a catalyst coated membrane for exchanging of ionic species or CCM (3), which is wound on the first gas diffusion layer or GDL (2), a second gas diffusion layer or electrode-GDL (4), wound on the catalyst coated membrane or CCM (3) and provided with a second electrical connector (5). The first gas diffusion layer or GDL (2), the catalyst coated membrane or CCM (3), and the second gas diffusion layer or electrode-GDL (4) are suitable to surround the central tubular electrode (11) for at least 360°.

Abstract: The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.

Abstract: The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.

Abstract: Hydrophobic, asymmetric membranes are formed integrally from elastomeric polymers. The membranes have a dense, discriminating layer and a thick, porous support layer and require no other support. The membranes of the invention provide an economic advantage over prior art composite membranes used for separating target organics from a mixture. Using the methods of the invention it is possible to separate two or more organic components wherein discrimination is made on the basis of molecular size.

Abstract: Hydrophobic, asymmetric membranes are formed integrally from elastomeric polymers. The membranes have a dense, discriminating layer and a thick, porous support layer and require not other support. The membranes of the invention provide an economic advantage over prior art composite membranes used for separating target organics from a mixture.

Abstract: Using the methods of the invention, an elastomeric polymer is dissolved in a suitable solvent, cast in one of the membrane casting techniques using a phase inversion technique, and immersed in a coagulation bath comprised of suitable solvent/non-solvent pairs (e.g., THF/water and ethanol). Asymmetric membranes having a dense discriminating layer and a thicker porous support layer suitable for application in pervaporation processes were obtained in a single step. An increase of the polymer concentration in the casting solution gives a more dense layer. When cast as formed using the methods of the invention, the membrane obtained is an integrally skinned membrane comprising a thin, dense separation layer over a porous support layer (asymmetric membrane) formed in a single casting operation. The resulting membrane is homogenous with respect to chemical composition.

Abstract: Hydrophobic, asymmetric membranes are formed integrally from elastomeric polymers. The membranes have a dense, discriminating layer and a thick, porous support layer and require not other support. The membranes of the invention provide an economic advantage over prior art composite membranes used for separating target organics from a mixture.