Abstract: A method for preparing lithium concentrate from natural lithium-bearing brines was developed. The brine is first subjected to purification from the suspended solids, then filtered through a static layer of a granulated sorbent based on LiCl.2Al(OH)3.mH2O, where m=3-5, to obtain a primary lithium concentrate. The process is carried out in sorption-desorption units consisting of 4 columns, two of which are in the process of sorption of lithium chloride from the brine, one column is in the process of washing the sorbent saturated with lithium chloride from the brine, and one column is in the process of lithium chloride desorption. The primary lithium concentrate is converted to a secondary lithium concentrate by concentration in evaporative pools or reverse osmotic concentration-desalination. The secondary lithium concentrate is used for further production of lithium chloride or lithium carbonate.

Abstract: Disclosed a method for the preparation of granular sorbent based on LiCl.2Al(OH)3.nH2O for lithium recovery from lithium-containing brines, comprising production of a powder of LiCl.2Al(OH)3.nH2O (DHAL-Cl) from aluminum chloride solution comprising lithium, separation of the powder DHAL-Cl from the obtained solution by centrifugation with further removing the excess LiCl, drying of the powder DHAL-Cl; and, granulation of the powder DHAL-Cl with the addition of chlorinated polyvinylchloride and a organochlorine solvent to obtain the granular sorbent based on LiCl.2Al(OH)3.nH2O; wherein the aluminum chloride solution comprising lithium is prepared by dissolving crystalline hydrate of hexaaqua aluminum chloride in aqueous solutions comprising lithium in the form of LiCl, Li2CO3, or LiOH.H2O or mixtures thereof, and concentration of aluminum chloride in the solution is 45-220 kg/m3.

Abstract: Method for preparing lithium concentrate from natural lithium-bearing brines was developed. The brine is first subjected to purification from the suspended solids, then filtered through a static layer of the granulated sorbent based on the LiCl-2Al(OH)3-mH20, where m=3-5, to obtain primary lithium concentrate. The process is carried out in sorption-desorption units consisting of 4 columns, two of which are in the process of lithium chloride from the brine, one column is in the process of washing the sorbent saturated with lithium chloride from the brine, and one column is in the process of lithium chloride desorption. Primary lithium concentrate is converted to a secondary lithium concentrate by concentration in evaporative pools or reverse-osmotic concentration-desalination. Secondary lithium concentrate is used for further production of lithium chloride or lithium carbonate.

Abstract: Disclosed a method for the preparation of granular sorbent based on LiCl.2Al(OH)3.nH2O for lithium recovery from lithium-containing brines, comprising production of a powder of LiCl.2Al(OU)3.nH2O (DUAL-Cl) from aluminum chloride solution comprising lithium, separation of the powder DUAL-Cl from the obtained solution by centrifugation with further removing the excess LiCl, drying of the powder DUAL-Cl; and, granulation of the powder DUAL-Cl with the addition of chlorinated polyvinylchloride and a organochlorine solvent to obtain the granular sorbent based on LiCl.2Al(OU)3.nH2O; wherein the aluminum chloride solution comprising lithium is prepared by dissolving crystalline hydrate of hexaaqua aluminum chloride in aqueous solutions comprising lithium in the form of LiCl, Li2CO3, or LiOH.H2O or mixtures thereof, and concentration of aluminum chloride in the solution is 45-220 kg/m3.