Abstract: A solid rocket motor includes a combustion chamber bounded by an outer casing, a propellant grain within the combustion chamber, and an igniter within the outer casing for igniting the propellant grain. A nozzle is coupled to the combustion chamber for releasing hot gasses evolved from burning the propellant grain to provide thrust for propelling the solid rocket motor. The propellant grain is a self-extinguishing propellant grain that includes at least one fuel, at least one oxidizing agent, at least one binder, and at least one surfactant that imparts the self-extinguishing property. The propellant grain provides a burning rate as a function of pressure that includes a negative pressure dependence portion, wherein the burning rate in the negative pressure dependence portion decreases with increasing pressure until a cutoff pressure is reached which results in extinguishment of the propellant grain.

Abstract: Solid composite propellant compositions include at least one oxidizing agent, at least one binder, and at least one surfactant. The surfactant provides the solid propellant the property of being “self-extinguishing”, where the burning rate of the solid composite propellant as a function of pressure includes a negative pressure dependence portion, wherein the burning rate in the negative pressure dependence portion decreases with increasing pressure until a cutoff pressure is reached which results in extinguishment of the solid composite propellant. The solid composite propellant can also include at least one catalyst that modifies the burning rate of the solid composite propellant. Solid composite propellants can be extinguished without the need for depressurization by reaching a cutoff pressure, and with a tailored burning rate.