Abstract: Disclosed herein are photocurable compositions and methods of use thereof. The photocurable compositions comprise: a (co)monomer; a photosensitizer having an absorption hand, wherein at least a portion of the absorption band is located at one or more wavelength from 400 nm to 1400 nm, and wherein the photosensitizer comprises a xanthene, a squaraine, a boron-dipyrromethene, a cyanine, a porphyrin, or a combination thereof; an acceptor co-initiator comprising a diphenyliodonium salt; and a donor co-initiator comprising a borate salt. The photocurable compositions optionally further comprise a crosslinker, an opacifier, a solvent, an oxygen scavenger, a radical scavenger, or a combination thereof.