Patents by Inventor Alexander Korzhenko
Alexander Korzhenko has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11888161Abstract: The present invention relates to a composition for battery electrodes in which at least one solvent is a composition comprising between 80% and 95% by mass of N-methylpyrrolidone (NMP).Type: GrantFiled: June 9, 2021Date of Patent: January 30, 2024Assignee: Arkema FranceInventor: Alexander Korzhenko
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Publication number: 20230339758Abstract: A process for purifying raw carbon nanotubes to obtain a content in metallic impurities of between 5 ppm and 200 ppm. The process includes an increase in the bulk density of the raw carbon nanotubes via compacting to produce compacted carbon nanotubes. The process further includes sintering the compacted carbon nanotubes by undergoing thermal treatment under gaseous atmosphere in order to remove at least a portion of the metallic impurities contained in the raw carbon nanotubes, and consequently producing purified carbon nanotubes. These purified carbon nanotubes are directly usable as electronic conductors serving as basis additive to an electrode material without requiring any subsequent purification step. The electrode material can then be used to manufacture an electrode destined to a lithium-ion battery.Type: ApplicationFiled: April 10, 2023Publication date: October 26, 2023Applicants: HYDRO-QUÉBEC, Arkema FranceInventors: Ali DARWICHE, Martin DONTIGNY, Naoyuki KONDO, Abdelbast GUERFI, Karim ZAGHIB, Julien BEAUSOLEIL, Alexander KORZHENKO
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Patent number: 11661344Abstract: The present invention proposes a process for purifying raw carbon nanotubes to obtain an content in metallic impurities comprised between 5 ppm and 200 ppm. The process includes an increase in the bulk density of the raw carbon nanotubes via compacting to produce compacted carbon nanotubes. The process further includes sintering the compacted carbon nanotubes by undergoing thermal treatment under gaseous atmosphere in order to remove at least a portion of the metallic impurities contained in the raw carbon nanotubes, and consequently producing purified carbon nanotubes. These purified carbon nanotubes are directly usable as electronic conductors serving as basis additive to an electrode material without requiring any subsequent purification step. The electrode material can then be used to manufacture an electrode destined to a lithium-ion battery.Type: GrantFiled: March 29, 2018Date of Patent: May 30, 2023Assignees: HYDRO-QUEBEC, ARKEMA FRANCEInventors: Ali Darwiche, Martin Dontigny, Naoyuki Kondo, Abdelbast Guerfi, Karim Zaghib, Julien Beausoleil, Alexander Korzhenko
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Publication number: 20220376254Abstract: The present invention relates to a composition for battery electrodes in which at least one solvent is a composition comprising between 80% and 95% by mass of N-methylpyrrolidone (NMP).Type: ApplicationFiled: June 9, 2021Publication date: November 24, 2022Applicant: Arkema FranceInventor: Alexander Korzhenko
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Patent number: 11214523Abstract: A process for the production of highly carbonaceous material, including combining a structured precursor including fibres and an unstructured precursor, in the form of a fluid, wherein the fluid has a viscosity of less than 45,000 mPa·s?1 at the temperature at which the combination step occurs, and including at least a cyclic organic or aromatic compound in the molten state, or in solution at a concentration by weight of less than or equal to 65%, in order to obtain a combined precursor corresponding to the structured precursor covered by the unstructured precursor, wherein the process further includes step of thermal and dimensional stabilization of the combined precursor in order to obtain fibres covered with a cyclic organic or aromatic compound deposit, and a step of carbonization of the fibres covered with a cyclic organic or aromatic compound deposit in order to obtain a highly carbonaceous material.Type: GrantFiled: October 26, 2017Date of Patent: January 4, 2022Assignee: ARKEMA FRANCEInventors: Alexander Korzhenko, Célia Mercader
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Publication number: 20210119210Abstract: A new class of alkoxyamines is described that exhibits improved stability on storage, especially in the presence of monomers and/or of a solvent, and particularly where the alkoxylamines are a new class of oligomeric alkoxyamines, which are obtained by addition of one or more monomeric entities to an alkoxyamine.Type: ApplicationFiled: April 19, 2019Publication date: April 22, 2021Applicant: Arkema FranceInventors: Alexander Korzhenko, Pierre-Thomas Skowron, Paul-Guillaume Schmitt, Meriem Anouti
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Publication number: 20210107791Abstract: The present invention proposes a process for purifying raw carbon nanotubes to obtain an content in metallic impurities comprised between 5 ppm and 200 ppm. The process includes an increase in the bulk density of the raw carbon nanotubes via compacting to produce compacted carbon nanotubes. The process further includes sintering the compacted carbon nanotubes by undergoing thermal treatment under gaseous atmosphere in order to remove at least a portion of the metallic impurities contained in the raw carbon nanotubes, and consequently producing purified carbon nanotubes. These purified carbon nanotubes are directly usable as electronic conductors serving as basis additive to an electrode material without requiring any subsequent purification step. The electrode material can then be used to manufacture an electrode destined to a lithium-ion battery.Type: ApplicationFiled: March 29, 2018Publication date: April 15, 2021Applicants: HYDRO-QUÉBEC, Arkema FranceInventors: Ali DARWICHE, Martin DONTIGNY, Naoyuki KONDO, Abdelbast GUERFI, Karim ZAGHIB, Julien BEAUSOLEIL, Alexander KORZHENKO
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Publication number: 20210036331Abstract: An active material formulation comprising a sulfur-based material and an electrically conductive composition is described, wherein the electrically conductive composition comprises carbon nanotubes and carbon fibers. A process is also described for preparing the active material formulation, a catholyte comprising the formulation, a cathode comprising the catholyte and an accumulator comprising the cathode.Type: ApplicationFiled: February 19, 2019Publication date: February 4, 2021Applicant: Arkema FranceInventors: Alexander Korzhenko, Dominique Plee
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Patent number: 10844521Abstract: A process for producing a highly carbonaceous fibre or set of fibres including combining a structured precursor comprising a hydrocellulose fibre or a set of fibres, and an unstructured precursor, including lignin or a lignin derivative in the form of a solution having a viscosity less than 15,000 mPa·s?1 at the temperature at which the combination step takes place, in order to obtain a hydrocellulose fibre or set of fibres coated with the lignin or lignin derivative, wherein the process further includes a step of thermal and dimensional stabilization of the hydrocellulose fibre or set of fibres covered with the lignin in order to obtain a hydrocellulose fibre or set of fibres covered with a deposit of lignin or lignin derivative, and a carbonization step of the hydrocellulose fibre or set of fibres coated with a lignin deposit in order to obtain a highly carbonaceous fibre or set of fibres.Type: GrantFiled: October 26, 2017Date of Patent: November 24, 2020Assignee: ARKEMA FRANCEInventors: Alexander Korzhenko, Tatiana Kolomiets
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Publication number: 20200346930Abstract: An agglomerated solid material comprising loose carbon nanotubes and that is free from organic compounds is described, as well as the method of preparation thereof, and uses thereof, where the agglomerated solid material consists of a continuous network of carbon nanotubes comprising aggregates of carbon nanotubes with an average size d50 under 5 ?m, in a proportion below 60% by area, determined by image analysis by electron microscopy and has an apparent density between 0.01 g/cm3 and 2 g/cm3.Type: ApplicationFiled: January 10, 2019Publication date: November 5, 2020Applicant: Arkema FranceInventors: Patrick Delprat, Alexander Korzhenko, Christophe Vincendeau, Daniel Cochard
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Publication number: 20200350560Abstract: A formulation is described in the form of a solid-liquid dispersion for the manufacture of a cathode, comprising a liquid-phase solvent, a sulfur-carbon composite in the form of particles with a median diameter D50 of less than 50 ?m, and less than 10% by number of the particles of the dispersion are particles of sulfur in elemental form.Type: ApplicationFiled: January 16, 2019Publication date: November 5, 2020Applicant: Arkema FranceInventors: Alexander Korzhenko, Patrick Delprat, Christophe Vincendeau
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Patent number: 10633508Abstract: The invention relates to a method for producing a master batch comprising between 0.01 and 50 wt. % of carbonaceous nanofillers and at least one sulphurated material such as elemental sulphur by melt compounding, and to the master batch thus produced and the different uses thereof. The invention also relates to a solid composition comprising carbonaceous nanofillers dispersed in a sulphurated material.Type: GrantFiled: October 27, 2015Date of Patent: April 28, 2020Assignee: Arkema FranceInventors: Alexander Korzhenko, Christophe Vincendeau, Thierry Aubert
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Patent number: 10446831Abstract: The present invention relates to an active material suitable for the production of an electrode, in particular an electrode for a Li—S battery. The active material according to the invention comprises carbon nanofillers homogeneously dispersed in the substance of a sulphur material, the active material being obtainable according to a method involving melting in the presence of intense mechanical energy. The quantity of carbon nanofillers in the active material represents 1 to 25% by weight with respect to the total weight of the active material. The active material according to the invention allows an improvement in the electronic conductivity of the formulation of the electrode. Another aspect of the invention is the use of the active material in an electrode, in particular in a Li—S battery cathode.Type: GrantFiled: December 21, 2015Date of Patent: October 15, 2019Assignee: Arkema FranceInventors: Alexander Korzhenko, Christophe Vincendeau
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Publication number: 20190271101Abstract: A process for producing a highly carbonaceous fibre or set of fibres including combining a structured precursor comprising a hydrocellulose fibre or a set of fibres, and an unstructured precursor, including lignin or a lignin derivative in the form of a solution having a viscosity less than 15,000 mPa·s?1 at the temperature at which the combination step takes place, in order to obtain a hydrocellulose fibre or set of fibres coated with the lignin or lignin derivative, wherein the process further includes a step of thermal and dimensional stabilization of the hydrocellulose fibre or set of fibres covered with the lignin in order to obtain a hydrocellulose fibre or set of fibres covered with a deposit of lignin or lignin derivative, and a carbonization step of the hydrocellulose fibre or set of fibres coated with a lignin deposit in order to obtain a highly carbonaceous fibre or set of fibres.Type: ApplicationFiled: October 26, 2017Publication date: September 5, 2019Applicant: Arkema FranceInventors: Alexander KORZHENKO, Tatiana KOLOMIETS
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Publication number: 20190270678Abstract: A process for the production of highly carbonaceous material, including combining a structured precursor including fibres and an unstructured precursor, in the form of a fluid, wherein the fluid has a viscosity of less than 45,000 mPa·s?1 at the temperature at which the combination step occurs, and including at least a cyclic organic or aromatic compound in the molten state, or in solution at a concentration by weight of less than or equal to 65%, in order to obtain a combined precursor corresponding to the structured precursor covered by the unstructured precursor, wherein the process further includes step of thermal and dimensional stabilization of the combined precursor in order to obtain fibres covered with a cyclic organic or aromatic compound deposit, and a step of carbonization of the fibres covered with a cyclic organic or aromatic compound deposit in order to obtain a highly carbonaceous material.Type: ApplicationFiled: October 26, 2017Publication date: September 5, 2019Applicant: Arkema FranceInventors: Alexander KORZHENKO, Célia MERCADER
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Patent number: 10208180Abstract: Hardenable inorganic systems such as cements, plasters, ceramics or liquid silicates, usable for example in the building trade, construction industry or oil drilling industry. The insertion of carbonaceous nanofillers, such as carbon nanotubes, for reinforcing mechanical properties and improving such systems. A method for producing a master mixture including at least one superplasticiser and carbonaceous nanofillers at a mass ratio of between 0.1% and 25%, preferably between 0.2% and 20%, in relation to the total weight of the master mixture, and also to said master mixture thus obtained and to the use thereof in a hardenable inorganic system with a view to producing materials with improved properties. The disclosure applies to the construction industry, the building trade and the oil drilling industry.Type: GrantFiled: November 21, 2017Date of Patent: February 19, 2019Assignee: ARKEMA FRANCEInventors: Alexander Korzhenko, Christophe Vincendeau, Anna Lushnikova, Grigory Ivanovich Yakovlev, Grigoriy Nikolayevich Pervushin, Jean-Marc Suau, David Platel
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Publication number: 20190006059Abstract: A method for preparing a paste-like composition including carbon-based conductive fillers, at least one polymeric binder, at least one solvent, and at least one polymeric dispersant being different from the binder. Also, the paste that can result from said method, and to the uses thereof, in pure or diluted form, in particular for the manufacture of Li-ion batteries and super-capacitors.Type: ApplicationFiled: May 2, 2018Publication date: January 3, 2019Applicant: ARKEMA FRANCEInventors: Serge NICOLAS, Alexander KORZHENKO, Amélie MERCERON, Yvan LECOMTE
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Patent number: 10158116Abstract: A method for the manufacture of a paste composition suitable for the production of an electrode for lead-acid battery, including mixing a carbon nanofiller/lead oxide composite of a first particulate size with sulphuric acid, water and further lead oxide of a second particulate size. Also, the paste thus obtained, the composite used in its manufacture, and the electrode and lead-acid battery obtained from this paste.Type: GrantFiled: January 25, 2013Date of Patent: December 18, 2018Assignee: ARKEMA FRANCEInventors: Alexander Korzhenko, Patrick Delprat, Christophe Vincendeau, Beni Cahana
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Patent number: 10125243Abstract: A composite material containing a polymer composition and a very low concentration of carbon nanofillers, in particular carbon nanotubes, having improved mechanical properties. The method for producing said composite material and to the different uses thereof. The use of carbon nanofillers at a concentration of between 0.1 ppm and 99 ppm in order to improve mechanical properties, in particular the tensile properties of a polymer matrix encasing at least one polymer selected from a thermoplastic polymer alone or mixed with an elastomer resin base, while facilitating the shaping thereof into composite parts using any suitable technique, in particular injection, extrusion, compression or molding, and while improving the electrostatic dissipation capability thereof.Type: GrantFiled: June 3, 2013Date of Patent: November 13, 2018Assignee: ARKEMA FRANCEInventors: Alexander Korzhenko, Patrick Delprat, Catherine Bluteau, Andriy Tymoshenko, Anatolly Goryachkin, Dmitry Zakharov
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Publication number: 20180166689Abstract: A masterbatch in agglomerated solid form including carbon nanofibers and/or nanotubes and/or carbon black, the content of which is between 15 wt % and 40 wt %, preferably between 20 wt % and 35 wt %, relative to the total weight of the masterbatch; at least one solvent; at least one polymer binder, which represents from 1 wt % to 40 wt %, preferably from 2 wt % to 30 wt % relative to the total weight of the masterbatch. Also, a concentrated masterbatch, characterized in that it is obtained by eliminating all or part of the solvent from the masterbatch described previously. Also, a process for preparing said masterbatches and to the uses of the latter, especially in the manufacture of an electrode or of a composite material for an electrode.Type: ApplicationFiled: January 25, 2018Publication date: June 14, 2018Applicant: Arkema FranceInventors: Serge Nicolas, Alexander Korzhenko, Amelie Merceron, Mickael Havel, Yvan Lecomte