Abstract: The invention relates to a new catalyst component for the polymerization of olefins comprising a compound of formula CyLMZp, wherein M is a Group 4-6 metal, Z is an anionic ligand, p is the number of anionic ligands, Cy is a mono- or poly-substituted cyclopentadienyl-type ligand and L is a guanidinate ligand of the formula wherein: each A is independently selected from nitrogen or phosphorus and R, R1, R2 and R3 are independently selected from the group consisting of hydrogen, hydrocarbyl, silyl and germyl residues, substituted or not with one or more halogen, amido, phosphido, alkoxy, or aryloxy radicals. The invention also relates to a catalyst system for the polymerization of olefins and a process for the polymerization of at least one olefin having 2 to 20 carbon atoms.

Abstract: The present invention relates to copolymers with polar and non-polar olefin blocks with a variable polar monomer content of 0.1 mol % to 99.9 mol %. The invention also relates to a method for obtaining copolymers with olefin blocks and vinyl polar monomer blocks, said method using a single-component catalytic system made up of an organometallic complex containing a metal belonging to groups VIII to X. Said organometallic complex is advantageously active in the medium without adding cocatalyst.

Abstract: The invention relates to a new catalyst component for the polymerization of olefins comprising a compound of formula CyLMZp, wherein M is a Group 4-6 metal, Z is an anionic ligand, p is the number of anionic ligands, Cy is a mono- or poly-substituted cyclopentadienyl-type ligand and L is a guanidinate ligand of the formula wherein: each A is independently selected from nitrogen or phosphorus and R, R1, R2 and R3 are independently selected from the group consisting of hydrogen, hydrocarbyl, silyl and germyl residues, substituted or not with one or more halogen, amido, phosphido, alkoxy, or aryloxy radicals. The invention also relates to a catalyst system for the polymerization of olefins and a process for the polymerization of at least one olefin having 2 to 20 carbon atoms.

Abstract: The present invention relates to copolymers with polar and non-polar olefin blocks with a variable polar monomer content of 0.1 mol % to 99.9 mol %. The invention also relates to a method for obtaining copolymers with olefin blocks and vinyl polar monomer blocks, said method using a single-component catalytic system made up of an organometallic complex containing a metal belonging to groups VIII to X. Said organometallic complex is advantageously active in the medium without adding cocatalyst.