Abstract: The present invention relates to a conductive polymer material of poly(thio- or seleno-)phene type containing at least two distinct species of counteranion, including a first species which is an anionic form of sulphuric acid, and a second species of counteranion selected from triflate, triflimidate, tosylate, mesylate, perchlorate and hexafluorophosphate. The invention also relates to a process for preparing such a material and the use thereof as conductive film. The invention also targets a substrate coated at least partly by a film of a material as defined above, a device comprising a material as defined above as conductive material, and also the use thereof in the organic electronics, organic thermoelectricity, organic photovoltaic and organic photodetector fields.

Abstract: The present application relates to a process that is useful for preparing a graphene layer that is transparent and of stabilized and improved electrical conductivity, the process comprising at least the steps of: (i) providing at least one graphene layer that is transparent and that possesses a sheet resistance, R?ini, (ii) doping at least one zone of the graphene layer to form a doped graphene zone having a stabilized sheet resistance, R??, of value lower than R?ini, wherein step (ii) is carried out by spraying the surface of at least the zone of the graphene layer (i) with at least one dopant chosen from organometallic complexes and salts of platinum or palladium of +IV or +II oxidation state.

Abstract: The present invention relates to a heating device comprising: a base substrate; an electrically conductive layer, referred to as the heating layer, carried by the substrate, formed from at least one percolating network of nano-objects comprising metal nanowires; and a thermal diffusion layer made from aluminum nitride, covering all or part of the heating layer. The invention also concerns a method for preparing such a heating device.

Abstract: The present invention relates to a conductive polymer material of poly(thio- or seleno-)phene type containing at least two distinct species of counteranion, including a first species which is an anionic form of sulphuric acid, and a second species of counteranion selected from triflate, triflimidate, tosylate, mesylate, perchlorate and hexafluorophosphate. The invention also relates to a process for preparing such a material and the use thereof as conductive film. The invention also targets a substrate coated at least partly by a film of a material as defined above, a device comprising a material as defined above as conductive material, and also the use thereof in the organic electronics, organic thermoelectricity, organic photovoltaic and organic photodetector fields.

Abstract: The invention relates to a display screen and its manufacturing process. The display screen of the invention comprises: a substrate made of a plastic; at least one transparent heating element; and at least one thermochromic compound, and is characterized in that the at least one transparent heating element comprises at least one optionally functionalized metal nanowire. The invention in particular has applications in the electronics industry.

Abstract: The invention relates to a process for improving the electrical and optical performance of a transparent electrically conductive material having silver nanowires. The invention also relates to a process for manufacturing a film made of a transparent electrically conductive material, such as a transparent electrode, a transparent heating film, or a film for electromagnetic shielding. The process of the invention includes the following steps: a) a step of bringing silver nanowires into contact with an acid solution, this solution having a pH lower than 7, preferably lower than 3; and b) a step of eliminating the acid. The field of application of the invention is in particular the field of optoelectronics.

Abstract: A method of manufacturing a thermoelectric module including a substrate and at least one conductive or semiconductor polymer film deposited on a surface of the substrate, the method including a step of manufacturing the conductive polymer film independently from the surface of the substrate and transferring the conductive polymer film onto the surface of the substrate. The transfer comprises: immersing the conductive polymer film in a transfer bath to obtain a conductive polymer film which is solvated, self-supporting, and capable of matching the shape of the substrate surface; applying the conductive polymer film in its solvated state on the substrate to match the shape of the surface thereof; and drying the solvated conductive polymer film.

Abstract: The invention relates to a display screen and its manufacturing process. The display screen of the invention comprises: a substrate made of a plastic; at least one transparent heating element; and at least one thermochromic compound, and is characterized in that the at least one transparent heating element comprises at least one optionally functionalized metal nanowire. The invention in particular has applications in the electronics industry.

Abstract: The invention relates to a process for improving the electrical and optical performance of a transparent electrically conductive material having silver nanowires. The invention also relates to a process for manufacturing a film made of a transparent electrically conductive material, such as a transparent electrode, a transparent heating film, or a film for electromagnetic shielding. The process of the invention includes the following steps: a) a step of bringing silver nanowires into contact with an acid solution, this solution having a pH lower than 7, preferably lower than 3; and b) a step of eliminating the acid. The field of application of the invention is in particular the field of optoelectronics.

Abstract: The invention relates to a method for the functionalisation of metal nanowires and the use of said nanowires. The functionalisation method of the invention includes a step comprising the formation of a self-assembled monolayer on at least part of the external surface of metal nanowires, using a compound of formula R1—Zn—R2, wherein Z is S or Se, and n is equal to 1 or 2, and R1 is a hydrogen atom or an acyl group or a hydrocarbon group comprising between 1 and 100 carbon atoms and R2 is an electron-attracting or -donating group. The method if the invention is particularly suitable for use in the field electrode production.

Abstract: A device for detecting and/or quantifying organophosphorus compounds, including an electrical device including a source electrode and a drain electrode separated by a semiconductive material, characterized in that at least one receptor molecule, including a group R and a primary alcohol in spatial proximity to a tertiary amine, with which the primary alcohol is capable of reacting in the presence of an organophosphorus compound, is grafted, by the group R, onto one of the electrodes or onto the semiconductive material, and a device for detecting the variation in positive charges between the two electrodes.

Abstract: The present invention relates to a method and device for the detecting and/or electrically quantifying organophosphorus compounds as a gas or solution. The device includes: an electrical device including a source electrode and a drain electrode, separated by a semiconductor material; and a device for detecting positive charges between the two electrodes. One surface of the semiconductor material is in contact with a polymer material having at least one receptor group including: 1) a function X capable of reacting with the detectable organophosphorus compound, to form an intermediate grouping —Z; and 2) a function Y capable of reacting with —Z to form a positively charged ring. The polymer material includes molecular imprint cavities, with geometrical and chemical configuration allowing the detectable organophosphorus compounds to penetrate into said polymer material. The invention can be used in the field of detecting and/or quantifying organophosphorus compounds.

Abstract: The invention relates to a method for functionalizing a conductive or semiconductor material (M) by covalent grafting of receptor molecules (R) to its surface, said method comprising the following steps: (i) applying, across the terminals of a source electrode and a drain electrode located on either side of the material (M), sufficient potential difference to thermally activate the material (M) with respect to the grafting reaction of the molecules (R); and (ii) placing the material (M) thus activated in contact with a liquid or gaseous medium containing receptor molecules (R), thereby obtaining a material (M) functionalized by covalently grafted receptor molecules (R).

Abstract: The invention relates to an apparatus and method for detecting and/or quantifying compounds of interest present in gaseous form or dissolved in a solvent. The apparatus according to the invention includes an electrical device including two electrodes, and a device for measuring the variation in charges between the two electrodes of the electrical device. The electrical device includes a layer made of an insulating dielectric material onto which a layer of receptor molecules is grafted, and finally, a layer of semiconductor material is deposited onto the receptor molecule layer. The invention can be used in the field of detecting and/or quantifying compounds of interest present, in particular, in a gas or in a solution.

Abstract: The invention relates to an apparatus and to a method for detecting and/or quantifying mercuric ions, Hg2+. The apparatus of the invention is of the type comprising an electrical device comprising two electrodes and a substrate comprising at least one surface made of an organic or inorganic semiconductor material, the electrodes being in electrical contact with said organic or inorganic semiconductor material, and a device for measuring the variation in the conduction current between the two electrodes, and wherein at least one compound which complexes mercuric ions Hg2+, selected from a dithia-dioxa-monoaza crown ether compound, an N,N-di(hydroxyethyl)amine, an N,N-di(carboxyethyl)amine, and mixtures of two at least of these compounds, is bonded to said semiconductor material or to an electrode of said electrical device. The invention finds application in the field of the detection of mercuric ions, in particular.

Abstract: The invention relates to a method for functionalizing a conductive or semiconductor material (M) by covalent grafting of receptor molecules (R) to its surface, said method comprising the following steps: (i) applying, across the terminals of a source electrode and a drain electrode located on either side of the material (M), sufficient potential difference to thermally activate the material (M) with respect to the grafting reaction of the molecules (R); and (ii) placing the material (M) thus activated in contact with a liquid or gaseous medium containing receptor molecules (R), thereby obtaining a material (M) functionalized by covalently grafted receptor molecules (R).

Abstract: The invention relates to an apparatus and to a method for detecting and/or quantifying mercuric ions, Hg2+. The apparatus of the invention is of the type comprising an electrical device comprising two electrodes and a substrate comprising at least one surface made of an organic or inorganic semiconductor material, the electrodes being in electrical contact with said organic or inorganic semiconductor material, and a device for measuring the variation in the conduction current between the two electrodes, and wherein at least one compound which complexes mercuric ions Hg2+, selected from a dithia-dioxa-monoaza crown ether compound, an N,N-di(hydroxyethyl)amine, an N,N-di(carboxyethyl)amine, and mixtures of two at least of these compounds, is bonded to said semiconductor material or to an electrode of said electrical device. The invention finds application in the field of the detection of mercuric ions, in particular.

Abstract: The present invention relates to a method and a device for the electrical detection and/or quantification of organophosphorus compounds present in gaseous form or in solution in a solvent. A device for detecting and/or quantifying organophosphorus compounds, comprising an electrical device comprising a source electrode and a drain electrode separated by a semiconductive material, characterized in that at least one receptor molecule, comprising a group R and a primary alcohol in spatial proximity to a tertiary amine, with which the primary alcohol is capable of reacting in the presence of an organophosphorus compound, is grafted, by means of the group R, onto one of the electrodes or onto the semiconductive material, and a device for detecting the variation in positive charges between the two electrodes.

Abstract: The synthesis of new ?-helix scaffolds mimicking i, i+3 or i+4, i+7 residues, was accomplished. The common pyridazine heterocycle originates from the easily available dimethyl pyridazine-3,6-dicarboxylate building block. These scaffolds may be thought of as synthetic counterparts of amphiphilic ?-helices having a hydrophilic face along one side and a hydrophobic face along the other side of the helix.

Abstract: The invention provides a nanowire made of a silicon-based material, the surface of which includes at least one gold protuberance, said nanowire being noteworthy in that an organosulfur derivative is grafted onto at least one of these gold protuberances.