Abstract: A glass article having anti-sun properties includes a glass substrate having a stack of layers, which includes, successively from the surface of the substrate: a first module M1 having a layer based on a dielectric material with a thickness e1 or of a set of layers, a layer TN1 including titanium nitride with a thickness of between 2 nanometers and 80 nanometers, a second module M2 including a layer based on a dielectric material with a thickness e2 or of a set of layers based on dielectric materials with a cumulative thickness e2, an intermediate layer including at least one element selected from silicon, aluminum, titanium or a mixture of at least two of these elements is deposited between the layer TN1 and the first module M1 and/or between the layer TN1 and the second module M2, the intermediate layer having a thickness of between 0.2 nm and 6 nm.

Abstract: A process of forming a member for a structure can include depositing a solar control layer over a first substrate, wherein depositing is performed using a plasma-assisted technique. The process can also include coupling the solar control layer and the first substrate to a second substrate. The process can further include removing the first substrate from the solar control layer while at least a portion of the solar control layer remains coupled to the second substrate. In an embodiment, second substrate can include a substrate for a structural member. Due to the composition or size of the substrate, the process described herein can be used to deposit a solar control layer that is initially deposited on a different substrate and is subsequently transferred to the substrate of the structural member.