Abstract: The invention relates to a process for electrolysis comprising a cathode and an anode comprising a catalyst, both the cathode and anode at least partly immersed in an electrolyte, the process characterised in that the electrolyte at least partly inhibits further oxidation of a product formed at the anode. Typically the catalyst comprises one or more metal-(Group VIb) semiconductors, and one or more metal-(GroupVIb))-phosphorous species.

Abstract: An electrolysis cell system (100) for producing hydrogen and oxygen from water comprising: at least one electrolysis cell (101) including a membrane electrode assembly (102) which comprises at least one pair of gas permeable electrodes (107, 109) comprising an anode (107) and a cathode (109), and an ion conductive electrolyte (108) arranged between each pair of anode (107) and cathode (109); an electrode gas space (104, 106) on the non-electrolyte side of each electrode (107, 109) comprising an anode gas space (104) and a cathode gas space (106), at least one electrode gas space (104) including an inlet (130) and an outlet (132); a recirculating loop (143) for recirculating at least a portion of produced oxygen product gas from the outlet (132) of at least one electrode gas space (104) to the inlet (130) of the respective electrode gas space (104) and through the respective electrode gas space (104); a water supply vessel (142) in fluid communication with the recirculating loop (143), the water supply vessel

Abstract: The present invention relates to a catalyst comprising (i) a semiconductor preferably comprising one or more metal-(Group VIb) semiconductors, and (ii) a semiconductor material having elevated phosphorous content preferably comprising one or more metal-(Group VIb))-phosphorous species.

Abstract: The invention relates to a process for electrolysis comprising a cathode and an anode comprising a catalyst, both the cathode and anode at least partly immersed in an electrolyte, the process characterised in that the electrolyte at least partly inhibits further oxidation of a product formed at the anode. Typically the catalyst comprises one or more metal-(Group VIb) semiconductors, and one or more metal-(GroupVIb))-phosphorous species.

Abstract: The present invention relates to a catalyst comprising (i) a semiconductor preferably comprising one or more metal-(Group VIb) semiconductors, and (ii) a semiconductor material having elevated phosphorous content preferably comprising one or more metal-(Group VIb))-phosphorous species