Patents by Inventor Alfred A. Schleppnik
Alfred A. Schleppnik has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4719105Abstract: Compounds of the formula ##STR1## wherein R.sup.1 is C.sub.1-5 alkyl, R.sup.2 is selected from hydrogen and C.sub.1-5 alkyl, X is selected from hydrogen and --COR.sup.3 wherein R.sup.3 is selected from hydrogen and C.sub.1-6 alkyl are useful in room fresheners and other compositions for counteracting malodors in air, wherein the malodors are caused by one or more compounds selected from lower carboxylic acids, thiols, thiophenols, phenols, lower amines, phosphines and arsines. The defined compounds impart little or no fragrance to such compositions but the compositions may include additional fragrances. Particularly valuable and novel compounds are those wherein R.sup.1 is methyl, R.sup.2 is selected from hydrogen and methyl and X is --COR.sup.3 wherein R.sup.3 is C.sub.2-6 alkyl.Type: GrantFiled: May 7, 1986Date of Patent: January 12, 1988Assignee: Bush Boake Allen, Inc.Inventor: Alfred A. Schleppnik
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Patent number: 4622221Abstract: Compounds of the formula ##STR1## wherein R.sup.1 is C.sub.1-5 alkyl, R.sup.2 is selected from hydrogen and C.sub.1-5 alkyl, X is selected from hydrogen and --COR.sup.3 wherein R.sup.3 is selected from hydrogen and C.sub.1-6 alkyl are useful in room freshners and other compositions for counteracting malodors in air, wherein the malodors are caused by one or more compounds selected from lower carboxylic acids, thiols, thiophenols, phenols, lower amines, phosphines and arsines. The defined compounds impart little or no fragrance to such compositions but the compositions may include additional fragrances. Particularly valuable and novel compounds are those wherein R.sup.1 is methyl, R.sup.2 is selected from hydrogen and methyl and X is --COR.sup.3 wherein R.sup.3 is C.sub.2-6 alkyl.Type: GrantFiled: February 21, 1984Date of Patent: November 11, 1986Assignee: Bush Boake Allen Inc.Inventor: Alfred A. Schleppnik
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Patent number: 4606849Abstract: 3,3-Dimethyl-1,5-dioxaspiro [5,5] undecane is useful in perfumery compositions. It can be made economically by reaction of cyclohexanone with neopentyl glycol in the presence of an acid, generally paratoluene sulphonic acid, under dehydrating conditions, generally by refluxing with a non-polar solvent.Type: GrantFiled: January 29, 1985Date of Patent: August 19, 1986Assignee: Bush Boake Allen LimitedInventors: Hifzur R. Ansari, Alfred A. Schleppnik
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Patent number: 4521344Abstract: A phenylethyl substituted dimer of ethylene and maleic anhydride, named 7-phenyloctane-(1,2),(5,6)-dianhydride, is chemically synthesized by(a) alkylating alkyl 2,4-dihalobutyrate with alkyl 2-cyano-3-phenylbutyrate,(b) alkylating the resulting halide condensation product with a carboxylate selected from the group consisting of trialkyl ethane-1,1,2-tricarboxylate and dimethyl cyanoethane-1,2-dicarboxylate,(c) acid hydrolyzing the resulting tetra or pentaester accompanied by decarboxylating, and(d) dehydrating the resulting tetra-acid to yield the desired phenylethyl substituted dimer of ethylene and maleic anhydride,wherein the alkyls in the butyrate and carboxylate ester groups each contain from one to about four carbon atoms and halo is selected from the group consisting of bromo, chloro and iodo.Type: GrantFiled: September 12, 1983Date of Patent: June 4, 1985Assignee: Monsanto CompanyInventors: Jacob S. Tou, Alfred A. Schleppnik
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Patent number: 4514340Abstract: A phenylethyl substituted dimer of ethylene and maleic anhydride, named 7-phenyloctane-(1,2),(5,6)-dianhydride, is chemically synthesized by(a) alkylating alkyl 2,4-dihalobutyrate with alkyl 2-cyano-3-phenylbutyrate,(b) alkylating the resulting halide condensation product with a carboxylate selected from the group consisting of trialkyl ethane-1,1,2-tricarboxylate and dimethyl cyanoethane-1,2-dicarboxylate,(c) acid hydrolyzing the resulting tetra or pentaester accompanied by decarboxylating, and(d) dehydrating the resulting tetra-acid to yield the desired phenylethyl substituted dimer of ethylene and maleic anhydride,wherein the alkyls in the butyrate and carboxylate ester groups each contain from one to about four carbon atoms and halo is selected from the group consisting of bromo, chloro and iodo.Type: GrantFiled: September 12, 1983Date of Patent: April 30, 1985Assignee: Monsanto CompanyInventors: Jacob S. Tou, Alfred A. Schleppnik
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Patent number: 4442298Abstract: A phenylethyl substituted dimer of ethylene and maleic anhydride, names 7-phenyloctane-(1,2),(5,6)-dianhydride, is chemically synthesized by(a) alkylating alkyl 2,4-dihalobutyrate with alkyl 2-cyano-3-phenylbutyrate,(b) alkylating the resulting halide condensation product with a carboxylate selected from the group consisting of trialkyl ethane-1,1,2-tricarboxylate and dimethyl cyanoethane-1,2-dicarboxylate,(c) acid hydrolyzing the resulting tetra or pentaester accompanied by decarboxylating, and(d) dehydrating the resulting tetra-acid to yield the desired phenylethyl substituted dimer of ethylene and maleic anhydride,wherein the alkyls in the butyrate and carboxylate ester groups each contain from one to about four carbon atoms and halo is selected from the group consisting of bromo, chloro and iodo.The dimer has anti-tumor and anti-viral properties and can be used in silver halide emulsions.Type: GrantFiled: August 30, 1982Date of Patent: April 10, 1984Assignee: Monsanto CompanyInventors: Jacob S. Tou, Alfred A. Schleppnik
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Patent number: 4428887Abstract: Mono-substituted terminal diesters of malonic acid are prepared by reaction of the corresponding substituted 1,2-diesters with alkali metal hydride in the presence of organic solvent medium.Type: GrantFiled: July 14, 1982Date of Patent: January 31, 1984Assignee: Monsanto CompanyInventors: Jacob S. Tou, Alfred A. Schleppnik
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Patent number: 4310512Abstract: Compounds of the formula ##STR1## wherein A, B, C individually represent hydrogen or an alkyl group of 1 to 6 carbon atoms, provided that the total combined number of carbon atoms of A, B and C does not exceed 8;X represents oxygen, sulfur, ##STR2## wherein the alkyl group has 1 to 7 carbon atoms or ##STR3## wherein R and R' represent hydrogen or a methyl group; n represents 1 or 2; andZ represents a hydroxyalkyl group of 2 to 7 carbon atomshave been found to be useful in compositions and methods for counteracting malodors.Type: GrantFiled: December 4, 1979Date of Patent: January 12, 1982Assignee: Bush Boake Allen Inc.Inventor: Alfred A. Schleppnik
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Patent number: 4187251Abstract: The compounds represented by the structural formula ##STR1## wherein A, B and C each independently represent hydrogen or lower alkyl having from 1 to 4 carbon atoms, provided that the sum of the carbon atoms in A, B and C is no more than 5,R.sup.1 represents alkyl having from 1 to 4 carbons,have been found to be particularly useful in compositions and methods for counteracting malodors. Novel compounds are also disclosed.Type: GrantFiled: May 22, 1978Date of Patent: February 5, 1980Inventor: Alfred A. Schleppnik
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Patent number: 4128509Abstract: 1-(Norborn-5'-en-2'-yl) or 1-(norborn-2'-yl) substituted 1-alken-3-ols and alkan-3-ols characterized by the structural formulae ##STR1## wherein R.sup.1 represents hydrogen or methyl, R represents an alkyl with from 1 to 8 carbon atoms, and R.sup.2 and R.sup.3 represent hydrogen or an alkyl with from 1 to 8 carbon atoms, provided that R and R.sup.2 can be --CH.sub.2 --.sub.n wherein n represents the integer 2, 3 or 4. The compounds have very pleasant, lasting floral-woody aromas and are useful as components in fragrance compositions.Type: GrantFiled: November 29, 1974Date of Patent: December 5, 1978Assignee: Monsanto CompanyInventor: Alfred A. Schleppnik
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Patent number: 4061667Abstract: 2-Alkyl-oct-5-en-2-ols and their esters characterized by the structural formula ##STR1## wherein R represents alkyl having from 1 to 8 carbon atoms and R.sup.1 represents hydroxyl or R.sup.2 COO--, wherein R.sup.2 represents alkyl having from 1 to 8 carbon atoms, aryl or aralkyl. These compounds can be in the cis or trans forms or mixtures thereof. The compounds have very pleasant, strong and long lasting green, floral, rosy aromas and are useful as fragrances or as components in fragrance compositions.Type: GrantFiled: March 24, 1975Date of Patent: December 6, 1977Assignee: Monsanto CompanyInventor: Alfred A. Schleppnik
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Patent number: 4009253Abstract: Compositions and methods for counteracting malodors. 4-cyclohexyl-4-methyl-2-pentanone has been found to be particularly useful in such compositions and methods.Type: GrantFiled: March 17, 1975Date of Patent: February 22, 1977Assignee: Monsanto CompanyInventors: Alfred A. Schleppnik, Steve G. Vanata
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Patent number: 3984354Abstract: 1-(3'-Hexenyl)-1-cycloalkanols and their esters characterized by the structural formula ##SPC1##Wherein R represents hydroxyl or R.sup.1 COO--, wherein R.sup.1 represents alkyl having from 1 to 8 carbon atoms, aryl or aralkyl and n is an integer from 1 to 3. These compounds can be in the cis or trans forms or mixtures thereof. The compounds have very pleasant, strong and long lasting green, floral, rosy aromas and are useful as fragrances or as components in fragrance compositions.Type: GrantFiled: December 30, 1974Date of Patent: October 5, 1976Assignee: Monsanto CompanyInventor: Alfred A. Schleppnik
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Patent number: 3966648Abstract: 2-Alkyl-oct-5-en-2-ols and their esters characterized by the structural formula ##EQU1## wherein R represents alkyl having from 1 to 8 carbon atoms and R.sup.1 represents hydroxyl or R.sup.2 COO--, wherein R.sup.2 represents alkyl having from 1 to 8 carbon atoms, aryl or aralkyl. These compounds can be in the cis or trans forms or mixtures thereof. The compounds have very pleasant, strong and long lasting green, floral, rosy aromas and are useful as fragrances or as components in fragrance compositions.Type: GrantFiled: January 9, 1974Date of Patent: June 29, 1976Assignee: Monsanto CompanyInventor: Alfred A. Schleppnik
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Patent number: 3942761Abstract: 4-(2'-norbornyl)-2-butanones characterized by the structural formula ##SPC1##Wherein R.sup.1 represents hydrogen or methyl, and R represents hydrogen or a lower alkyl group are prepared by a crossed aldol condensation of 5-norbornene-2-carboxaldehyde or norbornane-2-carboxaldehyde with methyl ketones in a basic medium followed by a subsequent dehydration of the aldol formed to prepare the 3-buten-2-ones which are subsequently hydrogenated. The compounds have very pleasant, strong and long lasting woody odors and are useful as compounds in fragrance compositions.Type: GrantFiled: November 16, 1973Date of Patent: March 9, 1976Assignee: Monsanto CompanyInventor: Alfred A. Schleppnik