Abstract: An abrasive compact comprising 40 to 90 volume percent of cubic boron nitride (CBN) crystals bonded by 60 to 10 volume percent of a bonding matrix comprised mainly of an intimate mixture of silicon nitride and metallic diboride MB.sub.2 where M represents metal atoms chosen from the group of titanium, zirconium and hafnium atoms. The compact may be produced by a method which comprises intimately mixing particulate CBN crystals with a bonding agent in the proportion 95 to 60 volume percent of CBN and 5 to 40 volume percent of bonding agent, the bonding agent containing the metal atoms in the atomic proportions Si.sub.30 M.sub.70 to Si.sub.85 M.sub.15, subjecting the mixture of CBN crystals and bonding agent to temperatures in the range 900.degree. to 1800.degree. C. and pressures in the range 5 to 70 Kilobars, and maintaining the temperature and pressure conditions for a period of at least about 30 seconds, sufficient to cause most of bonding agent to form the bonding matrix.

Abstract: A diamond compact comprised of more than 60 volume percent and less than 90 volume percent of diamond crystals connected by a silicon carbide bond. The bond contains more than 500 parts per million of nitrogen and/or phosphorus and the compact possesses a low electrical resistivity of less than 0.2 ohm cm. The compact may be produced by a process in which the diamond crystals are intimately mixed with a bonding agent comprising silicon and the mixture is subjected within a confining space to a high temperature and pressure within the graphite stability field to cause silicon in the bonding agent to react extensively with carbon in the diamond crystals to form the silicon carbide bond. To produce the low electrical resistivity, a material containing nitrogen and/or phosphorus is introduced into the confining space prior to application of the high temperature and pressure conditions.

Abstract: A process for producing a diamond compact comprised of diamond crystals bonded mainly by silicon carbide. The diamond crystals are intimately mixed with silicon in the proportions 97 to 65 percent by weight of diamond to 3 to 35 percent by weight of silicon. The thus-mixed diamond crystals and silicon are placed immediately adjacent to one or more bodies of silicon within a container and subjected to high pressure and temperature so as to cause melting of the premixed silicon and of the external silicon which infiltrates into the interstitial spaces between the diamond crystals to cause most of the silicon between the diamond crystals to react with diamond to produce silicon carbide. The elevated temperature is in the range 1,100.degree. to 18,000.degree. C., and the elevated pressure is in the range 10 to 40 kilobars. The resulting compact contains between 50 and 85 volume percent of diamond with a density of at least 3.35 g/cm.sup.3 and a compressive strength of at least 10 kilobars.

Abstract: Diamond compact composed of 60-95 volume % diamond crystals plastically deformed into a closely packed, rigid structure with contacts between the diamond crystals over extended mating surfaces arising from the plastic deformation. The diamond crystals are bonded together by an interstitial bonding material composed of a refractory carbide, such as silicon carbide, or a bonding material composed of a metal such as rhenium and a refractory carbide formed by reaction of a metallic bonding agent, such as tungsten, with carbon.

Abstract: A diamond compact comprised of 60-95 volume percent of diamond crystals which have been plastically deformed so that they form a rigid framework structure in which contacts between the diamond crystals occur over surfaces arising from plastic deformation of the diamond crystals during formation of the compact under pressure and temperature conditions within the graphite stability field. The diamond framework structure is bonded together by interstitial refractory carbide phases or metallic phases comprised of metals not forming carbides in the presence of carbon. The phases have a melting point greater than 1600.degree. C. The compact comprises less than about 2 percent volume of graphite and possesses a compressive strength greater than 10 kbars.

Abstract: A process for producing a diamond compact having a compressive strength of at least 10 kbars, the process being performed in the graphite stability field at a maximum pressure of 40 kbars at a temperature of between 1100.degree. C. and 1600.degree. C. for a time which permits plastic deformation of the diamond crystals giving face-to-face contacts there-between and a substantial or complete degree of chemical equilibration between the bonding agent and the diamond crystals. Bonding agents are selected from elements and alloys which produce a bond with diamond having a melting point above 1600.degree. C. and which inhibit the formation of free graphite in the compact.

Abstract: A compressible bellows type metal canister is used in a hot pressing process for immobilizing high level radioactive nuclear waste material in the form of synthetic rock, the canister comprises a base wall and a corrugated bellows side wall of generally circular cross-section, concentrically arranged within the corrugated side wall is a cylindrical liner. In the center of the base wall a conically-tapered aperture is provided with a filter plug. Diametrically opposed apertures are provided in the base wall and are connected by an outlet pipe for removal of waste gases.

Abstract: A metal compressible bellows-type container or canister is used in a hot uniaxial pressing process with a mixture of high level radioactive nuclear waste material and a synthetic rock forming material filling the canister. The canister has a bottom wall, a convoluted bellows-like side wall, a lid or top wall and transverse metal apertured plates dividing the canister into three equally sized zones. Preferably the apertures are of a clover leaf configuration and are located at the center of the plates. Cylindrical liners can be provided to maintain a zone between each liner and the bellows-like side wall to prevent ingress of the particulate mixture of waste and synthetic rock forming material.

Abstract: A dry, pourable particulate mixture of nuclear waste and synthetic rock-forming components is produced by supplying the rock forming components in dry particulate form to a mixer, supplying the nuclear waste in liquid phase and operating the mixer to distribute the waste substantially uniformly through the synthetic rock components; the mixture is calcined to produce a precursor powder which is adapted to be used in a hot pressing process to form synthetic rock throughout which the radioactive nuclear waste is distributed and immobilized. A reducing gas atmosphere is preferably maintained in the calcining process stage, the gas being for example pure hydrogen or a mixture of hydrogen in nitrogen in proportions which are non-explosive. A screw type or paddle type conveyor can be used for the mixing and calcining stages although the calcining can be effected in a vertically downwardly directed tube device having associated heating means such as microwave heating.

Abstract: Particulate material is poured into a container which is decay and heat resistant, the container is sealed and subjected to axial compression at elevated temperature to cause densification of the material, there being an arrangement for preventing substantial radially outward deformation of the container during compression. An important application is to immobilization of nuclear reactor waste in a synthetic rock structure formed during the high temperature compression step, and advantageously the containers are secured within an outer metal cannister for subsequent safe handling and disposal. An important embodiment includes a bellows container which advantageously is upwardly pressed into an inverted metal cannister restrained by an upper abutment, the bellows container becoming an interference fit within the metal cannister during the final portion of compression, but the bellows container wall itself being substantially sufficient to prevent gross outward deformation of the bellows container.

Abstract: Disclosed are two improved container alloys for radioactive nuclear waste. Radioactive nuclear waste can be contained over extended periods of time by encapsulating the waste materials in containers composed of these alloys and burying the containers underground in an impervious, stable rock formation.

Abstract: Disclosed are two improved container materials for radioactive nuclear waste. Radioactive nuclear waste can be contained over extended periods of time by encapsulating the waste materials in containers composed of these alloys and burying the containers underground in an impervious, stable rock formation.

Abstract: A process for immobilizing high level waste (HLW) sludge containing aluminium and/or iron compounds which comprises the steps of:(1) mixing the sludge with a mixture of oxides, the oxides in said mixture and the relative proportions thereof being selected so as to form a mixture when heated at temperatures between 800.degree. and 1400.degree. C.

Abstract: A process for immobilizing high level radioactive waste (HLW) calcine comprises the steps of:(1) mixing the HLW calcine with a mixture of oxides, the oxides in the mixture and the relative proportions thereof being selected so as to form a mixture which, when heated and then cooled, crystallizes to produce a mineral assemblage containing well-formed crystals capable of providing lattice sites in which elements of the HLW are securely bound, the crystals belonging to or possessing crystal structures closely related to crystals belonging to mineral classes which are resistant to leaching and alteration in appropriate geological environments and including crystals belonging to the titanate classes of minerals; and(2) heating and then cooling the mixture so as to cause crystallization of the mixture to a mineral assemblage having the elements of the HLW incorporated as solid solutions within the crystals thereof.

Abstract: Disclosed are two improved container alloys for radioactive nuclear waste. Radioactive nuclear waste can be contained over extended periods of time by encapsulating the waste materials in containers composed of these alloys and burying the containers underground in an impervious, stable rock formation.