Patents by Inventor Alfred Germann
Alfred Germann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5888423Abstract: Flourobenzyl ether derivatives of the formula ##STR1## and liquid crystalline mixtures which contain such compounds are prepared and employed in electro-optical display devices.Type: GrantFiled: June 21, 1996Date of Patent: March 30, 1999Assignee: Rolic AgInventors: Richard Buchecker, Alfred Germann
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Patent number: 5292452Abstract: Compounds of the formula ##STR1## wherein Z.sup.1 denotes a single covalent bond or --CH.sub.2 Ch.sub.2 --; ring A.sup.1 represents 1,4-phenylene, pyrimidine-2,5-diyl, pyridine-2,5-diyl or, when Z.sup.1 stands for --CH.sub.2 CH.sub.2 --, also trans-1,4-cyclohexylene; X.sup.1 stands for fluorine or chlorine; X.sup.2 signifies fluorine, chlorine or hydrogen, with the proviso that X.sup.2 only signifies hydrogen when X.sup.1 is chlorine or when ring A.sup.1 signifies pyridine-2,5-diyl and Z.sup.1 signifies --CH.sub.2 CH.sub.2 --; and R.sup.1 signifies 1E-alkenyl with 2 to 12 carbon atoms,their manufacture, liquid crystalline mixtures which contain these compounds and their use for electro-optical purposes.Type: GrantFiled: August 19, 1991Date of Patent: March 8, 1994Assignee: Hoffmann-La Roche Inc.Inventors: Richard Buchecker, Alfred Germann, Martin Schadt, Alois Villiger
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Patent number: 5174921Abstract: Compounds of the formula ##STR1## wherein Z.sup.1 is a single covalent bond or --CH.sub.2 CH.sub.2 --, X.sup.1 is hydrogen, fluorine or chlorine and R.sup.1 is 1E-alkenyl with 2 to 12 carbon atoms,their preparation, liquid crystalline mixtures which contain these compounds and their use for electro-optical purposes.Type: GrantFiled: May 20, 1991Date of Patent: December 29, 1992Assignee: Hoffmann-La Roche Inc.Inventors: Richard Buchecker, Alfred Germann, Martin Schadt, Alois Villiger
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Patent number: 4898455Abstract: There is described compounds of the formula ##STR1## wherein X stands for CH and Y stands for N or X stands for N and Y stands for CH; A.sup.1 and A.sup.2 signify single covalent bonds or one of the groups A.sup.1 and A.sub.2 also signifies trans-1,4-cyclohexylene, cis-4-cyano-trans-1,4-cyclohexylene or 1,4-phenylene optionally substituted with halogen or methyl; ring B represents trans-1,4-cyclohexylene, 1,4-phenylene optionally substituted with halogen or methyl or, when A.sup.2 signifies a single covalent bond, also cis-4-cyano-trans-1,4-cyclohexylene; R.sup.1 denotes an optionally halogen-substituted alkyl or alkenyl group in which optionally one CH.sub.2 group or two non-adjacent CH.sub.2 groups is/are replaced by --O--, --COO-- and/or --OOC--; R.sup.2 signifies an optionally halogen-substituted alkyl or alkenyl group in which optionally one CH.sub.2 group or two non-adjacent CH.sub.2 groups is/are replaced by --O--, --COO-- and/or --OOC-- or R.sup.Type: GrantFiled: April 16, 1987Date of Patent: February 6, 1990Assignee: Hoffmann-La Roche Inc.Inventors: Richard Buchecker, Alfred Germann, Stephen Kelly, Martin Schadt
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Patent number: 4613208Abstract: A liquid crystalline mixture comprising(a) at least one compound of the formula: ##STR1## wherein R.sup.1 is alkyl, alkoxy, p-alkylphenyl, p-alkoxyphenyl, trans-4-alkylcyclohexyl, 4'-alkyl-4-biphenylyl, p-(trans-4-alkylcyclohexyl)phenyl, 2-(trans-4-alkylcyclohexyl)ethyl or p-[2-(trans-4-alkylcyclohexyl)ethyl]phenyl and R.sup.2 is trans-4-alkylcyclohexyl; or R.sup.1 is trans-4-alkylcyclohexyl and R.sup.2 is p-(trans-4-alkylcyclohexyl)phenyl, p-[2-(trans-4-alkylcyclohexyl)ethyl]phenyl or 4'-(trans-4-alkylcyclohexyl)-4-biphenylyl; or R.sup.1 is p-alkylphenyl and R.sup.2 is p-[2-(trans-4-alkylcyclohexyl)ethyl]phenyl; and the alkyl and alkoxy groups in the substituents R.sup.1 and R.sup.2 are straight-chain groups of 1 to 7 carbon atoms, and;(b) at least one dichroic coloring substance selected from the group of compounds consisting of: ##STR2## wherein R.sup.3 is straight-chain C.sub.1 -C.sub.12 -alkyl and R.sup.4 is straight-chain C.sub.1 -C.sub.4 -alkyl, Z.sup.1 is hydrogen or chlorine, one of the symbols Z.Type: GrantFiled: November 18, 1983Date of Patent: September 23, 1986Assignee: Hoffmann-La Roche Inc.Inventors: Arthur Boller, Alfred Germann, Martin Petrzilka, Martin Schadt
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Patent number: 4395350Abstract: Liquid crystal mixtures containing a coloring substance which comprise about 5 to about 40 weight % of trans-p-[5-(4-alkylcyclohexyl)-2-pyrimidinyl]benzonitriles, about 10 to about 60 weight % of trans-4-alkylcyclohexane carboxylic acid phenyl esters and about 0.1 to about 15 weight % of one or more coloring substances of the formula ##STR1## wherein m stands for the number 1 and X is alkoxy and Y is nitro; or m stands for the number 1 or 2; and X is p-alkoxyphenyl and Y is nitro or dialkylamino, or X is alkoxy and Y is -p-nitrophenyl or -(dialkylamino)phenyl; or m stands for the number 2, and X is alkoxy and Y is alkoxy, nitro or dialkylamino, or both X and Y are dialkylamino; and wherein the alkoxy denotes a straight-chain group containing 1 to 12 carbon atoms and the alkyl groups in the dialkylamino each denote a straight-chain alkyl group containing 1 to 4 carbon atoms are described.Type: GrantFiled: July 1, 1981Date of Patent: July 26, 1983Assignee: Hoffmann-La Roche Inc.Inventors: Arthur Boller, Alfred Germann, Martin Schadt, Alois Villiger
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Patent number: 4364838Abstract: Liquid crystalline mixtures comprising trans-phenyldioxane, phenylpyrimidine and phenylbenzoate compounds which are useful in electro-optical apparatuses are disclosed.Type: GrantFiled: November 10, 1980Date of Patent: December 21, 1982Assignee: Hoffmann-La Roche Inc.Inventors: Arthur Boller, Alfred Germann, Martin Schadt, Alois Villiger
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Patent number: 4198130Abstract: Liquid crystal mixtures having positive anisotropy of the dielectric constants comprising a nematogenic material having a clearing point above 60.degree. C., one or more compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen or straight-chain alkyl, provided that at least one of R.sub.1 and R.sub.2 is other than hydrogen and that R.sub.1 and R.sub.2 together contain no more than 9 carbon atoms,and, if desired, one or more additional doping agents, are described.Type: GrantFiled: May 22, 1978Date of Patent: April 15, 1980Assignee: Hoffmann-La Roche Inc.Inventors: Arthur Boller, Alfred Germann, Martin Schadt, Hanspeter Scherrer