Patents by Inventor Alfred Jean Paul Buckmann
Alfred Jean Paul Buckmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240166634Abstract: The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): whereby R?, R?, R1, R2, R3 and R4 are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 600 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.Type: ApplicationFiled: December 1, 2023Publication date: May 23, 2024Inventors: Gerardus Cornelis Overbeek, Patrick Johannes Maria Stals, Daan Van Der Zwaag, Alfred Jean Paul Bückmann
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Patent number: 11878969Abstract: The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): (A) whereby R?, R?, R1, R2, R3 and R4 are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 600 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.Type: GrantFiled: July 17, 2019Date of Patent: January 23, 2024Assignee: Covestro (Netherlands) B.V.Inventors: Gerardus Cornelis Overbeek, Patrick Johannes Maria Stals, Daan Van Der Zwaag, Alfred Jean Paul Bückmann
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Publication number: 20230373159Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.Type: ApplicationFiled: July 26, 2023Publication date: November 23, 2023Applicant: Stratasys, Inc.Inventors: Johan Franz Gradus Antonius JANSEN, Rudolfus Antonius Theodorus Maria VAN BENTHEM, Paulus Franciscus Anna BUIJSEN, Franciscus Johannes Marie DERKS, Mark Petrus Franciscus PEPELS, Alfred Jean Paul BUCKMANN
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Publication number: 20230312525Abstract: The present invention relates to compount (I) comprising at least one functional group A and at least one functional group B, wherein the functional groups A has structural formula A: wherein R1 is H, R2, R3 and R4 are independently chosen from H, methyl or ethyl, m is 1-6; and the functional groups B has structural formula B: R5 is H or methyl, X is O or NH, Z? is a polyalkoxy group or an omega-alkoxy polycaprolacton group, Y? is a collection of atoms covalently connected in linear or branched configuration n? is 0 or 1, and m? is an integer from 1-6; with the proviso that the summed amount of the number of functional groups A and the number of functional groups B in compound (I) is from 2-13; and the compound has a molecular weight in the range from 800-10000 Dalton.Type: ApplicationFiled: January 21, 2021Publication date: October 5, 2023Inventors: Jurgen SCHEERDER, Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Hans GROEN, Emilio MARTIN, Johannes Jacobus Julius VAN DEN BIGGELAAR
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Patent number: 11724447Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.Type: GrantFiled: July 21, 2017Date of Patent: August 15, 2023Assignee: Covestro (Netherlands) B.V.Inventors: Johan Franz Gradus Antonius Jansen, Rudolfus Antonius Theodorus Maria Van Benthem, Paulus Franciscus Anna Buijsen, Franciscus Johannes Marie Derks, Mark Petrus Franciscus Pepels, Alfred Jean Paul Buckmann
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Publication number: 20230193057Abstract: The present invention relates to a multi-aziridine crosslinker composition, characterized in that the multi-aziridine crosslinker composition is an aqueous dispersion having a pH ranging from 8 to 14 and comprises a multi-aziridine compound in dispersed form, wherein said multi-aziridine compound has: a. from 2 to 6 of the following structural units A: whereby R1 is H, R2 and R4 are independently chosen from H or an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, R a is an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, m is 1, b. one or more linking chains wherein each one of these linking chains links two of the structural units A; and c. a molecular weight in the range from 500 to 10000 Daltons wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.Type: ApplicationFiled: January 21, 2021Publication date: June 22, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Kristel DE VOS - VERSCHUREN, Stella Josette VAN DIJK, Jan VAN RIEL, Rob LOOIJMANS
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Publication number: 20230140764Abstract: The present application relates to aziridine functional compounds with reduced genotoxicity and good crosslinking efficiency, for use in the preparation of, for example, coatings.Type: ApplicationFiled: January 21, 2021Publication date: May 4, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Josephus Christiaan VAN OORSCHOT, Ronald TENNEBROEK
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Publication number: 20230136495Abstract: The present invention relates to a multi-aziridine compound having: ?a) from 2 to 6 of the following structural units (A): whereby R1 is H, R2 and R4 are independently chosen from H or an aliphatic hydrocarbon group containing from 1-4 carbon atoms, R3 is an aliphatic hydrocarbon group containing from 1-4 carbon atoms, R??H or an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms; R? and R?? are independently chosen from an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, a cycloaliphatic hydrocarbon group containing from 4 to 12 carbon atoms or an aromatic hydrocarbon group containing from 6 to 12 carbon atoms, b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 600 Daltons to 5000 Daltons.Type: ApplicationFiled: January 21, 2021Publication date: May 4, 2023Inventors: Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Gerardus Cornelis OVERBEEK, Jan VAN RIEL
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Publication number: 20230127229Abstract: The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A): (A) whereby R1 is H; R2 and R4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R2 and R3 (in case R2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R? and R? are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight from 600 to 20000 Daltons, wherein the molecular weight is determined using MALDIType: ApplicationFiled: January 21, 2021Publication date: April 27, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Josephus Christiaan VAN OORSCHOT
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Publication number: 20230122028Abstract: The present invention relates to an aqueous coating composition comprising a multi-aziridine compound and a carboxylic acid functional polymer, characterized in that (i) the composition is an aqueous dispersion having a pH ranging from 8 to 14, (ii) the aqueous dispersion comprises particles X which particles X comprise multi aziridine compound and particles Y which particles Y comprise carboxylic acid functional polymer, and (iii) said multi-aziridine compound has: a) from 2 to 6 of the following structural units A: b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 500 to 10000 Daltons.Type: ApplicationFiled: January 21, 2021Publication date: April 20, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Hermanus Adrianus LANGERMANS, Stella Josette VAN DIJK, Rob LOOIJMANS
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Publication number: 20230110237Abstract: The invention relates to particles comprising a particular (aziridinyl hydroxy)-functional organic component. The invention further relates to mixtures comprising said particles. The invention further relates to aqueous dispersions comprising said particles. The invention further relates to aqueous compositions comprising said particles. The invention further relates to coating compositions comprising said particles. The invention further relates to aqueous coating compositions comprising said particles. The invention further relates to particles obtained by a process comprising—amongst others—the steps of providing an aqueous dispersion comprising a particular (aziridinyl hydroxy)-functional organic component. The invention further relates to a kit-of-parts comprising in one of its parts an aqueous dispersion comprising a particular (aziridinyl hydroxy)-functional organic component.Type: ApplicationFiled: January 21, 2021Publication date: April 13, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Stella Josette VAN DIJK
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Publication number: 20230096600Abstract: The present invention relates to a multi-aziridine crosslinker composition, characterized in that the composition is an aqueous dispersion having a pH ranging from 9 to 14 and comprising a multi-aziridine compound in dispersed form, wherein said multi-aziridine compound has: a. from 2 to 6 of the following structural units A: (A) whereby R1, R2, R3 and R4 are H; m is 1, R? and R? are according to (1) or (2): (2) R??H or an aliphatic hydrocarbon group containing from 1 to 14 carbon atoms, and R?=an alkyl group containing from 1 to 4 carbon atoms, CH2-O—(C?O)—R?? or CH2-O—R??, whereby R?? is an alkyl group containing from 4 to 12 carbon atoms and R?? is an alkyl group containing from 1 to 14 carbon atoms, (2) R? and R? form together a saturated cycloaliphatic hydrocarbon group containing from 5 to 8 carbon atoms; b. one or more linking chains wherein each one of these linking chains links two of the structural units A; and c. a molecular weight in the range from 600 to 10000 Daltons.Type: ApplicationFiled: January 21, 2021Publication date: March 30, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Jan VAN RIEL, Stella Josette VAN DIJK, Kristel DE VOS - VERSCHUREN, Hermanus Adrianus LANGERMANS
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Publication number: 20230097706Abstract: The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): whereby R?, R? are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 840 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.Type: ApplicationFiled: January 21, 2021Publication date: March 30, 2023Inventors: Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Gerardus Cornelis OVERBEEK, Jan VAN RIEL
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Publication number: 20230069357Abstract: The present invention relates to a two-component coating system comprising a first component and a second component each of which is separate and distinct from each other, wherein the first component comprises a carboxylic acid functional polymer dissolved and/or dispersed in an aqueous medium, and the second component comprises a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): b) whereby m is an integer from 1 to 8; and o R? and R? are both H b) one or more linking chains wherein each one of these linking chains links two of the structural units A; c) one or more connecting groups whereby each one of the connecting groups connects two of the structural units A; and d) a molecular weight in the range from 840 Daltons to 5000 Daltons, wherein the molecular weight is measured using MALDI-TOF mass spectrometry.Type: ApplicationFiled: January 21, 2021Publication date: March 2, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN
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Publication number: 20230054196Abstract: The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A) whereby R1 is H; R2 and R4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R2 and R3 (in case R2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R? and R? are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight of at least 600 Daltons, wherein the molecular weight is determined using MALDI-TOF maType: ApplicationFiled: January 21, 2021Publication date: February 23, 2023Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN, Josephus Christiaan VAN OORSCHOT
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Patent number: 11525061Abstract: The current invention relates to an one-pack aqueous coating composition comprising dispersed carbonyl functional vinyl polymer(s) particles, characterized in that the coating composition further comprises carbodihydrazide, whereby (i) the equivalent molar ratio of hydrazide groups to carbonyl groups is from 0.1 to 0.95, (ii) the ratio of number-average molecular weight of the carbonyl functional vinyl polymer(s) to acid value of the carbonyl functional vinyl polymer(s) is higher than 400, and (iii) the acid value of the carbonyl functional vinyl polymer(s) is from 2 to 100 mg KOH/gram carbonyl functional vinyl polymer.Type: GrantFiled: July 16, 2018Date of Patent: December 13, 2022Assignee: Covestro (Netherlands) B.V.Inventors: Gerardus Cornelis Overbeek, Alfred Jean Paul Bückmann, Patrick Johannes Maria Stals, Daan Van Der Zwaag, Jurgen Scheerder, Stella Josette Van Dijk
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Patent number: 11390023Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.Type: GrantFiled: March 30, 2021Date of Patent: July 19, 2022Assignee: Covestro (Netherlands) B.V.Inventors: Johan Franz Gradus Antonius Jansen, Rudolfus Antonius Theodorus Maria Van Benthem, Paulus Franciscus Anna Buijsen, Franciscus Johannes Marie Derks, Mark Petrus Franciscus Pepels, Alfred Jean Paul Buckmann
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Publication number: 20210332031Abstract: The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): (A) whereby R?, R?, R1, R2, R3 and R4 are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 600 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.Type: ApplicationFiled: July 17, 2019Publication date: October 28, 2021Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN
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Publication number: 20210213679Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.Type: ApplicationFiled: March 30, 2021Publication date: July 15, 2021Inventors: Johan Franz Gradus Antonius JANSEN, Rudolfus Antonius Theodorus Maria VAN BENTHEM, Paulus Franciscus Anna BUIJSEN, Franciscus Johannes Marie DERKS, Mark Petrus Franciscus PEPELS, Alfred Jean Paul BUCKMANN
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Patent number: 10994479Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.Type: GrantFiled: July 21, 2017Date of Patent: May 4, 2021Assignee: DSM IP ASSETS B.V.Inventors: Johan Franz Gradus Antonius Jansen, Rudolfus Antonius Theodorus Maria Van Benthem, Paulus Franciscus Anna Buijsen, Franciscus Johannes Marie Derks, Mark Petrus Franciscus Pepels, Alfred Jean Paul Buckmann