Patents by Inventor Alfredo Defrancisci

Alfredo Defrancisci has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240026125
    Abstract: The present invention deals with a composition comprising at least one organic peroxide, at least one sulfur-containing compound chosen among the group consisting of dialkyl phosphorodithioic acid and salts thereof, and optionally sulfur under its free form.
    Type: Application
    Filed: October 8, 2021
    Publication date: January 25, 2024
    Inventor: Alfredo DEFRANCISCI
  • Patent number: 11845838
    Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
    Type: Grant
    Filed: June 10, 2020
    Date of Patent: December 19, 2023
    Assignee: Arkema Inc.
    Inventors: Leonard H. Palys, Peter R. Dluzneski, William P. Pavlek, Alfredo Defrancisci, Feng-Jon Chang, Marina Despotopoulou, Michael B Abrams, Joseph M. Brennan, Isabelle Tartarin
  • Patent number: 11753522
    Abstract: The use of magnesium oxide for increasing the rate of crosslinking and/or the crosslinking density of at least one crosslinkable polymer is described in addition to a composition that can be employed in this use, comprising: from 30 to 80% by weight of a crosslinking co-agent, from 0.5 to 10% by weight of an organic peroxide, from 15 to 60% by weight of magnesium oxide, and from 0 to 40% by weight of one or more crosslinkable polymers. An article obtained from this composition is also described.
    Type: Grant
    Filed: February 27, 2019
    Date of Patent: September 12, 2023
    Assignee: Arkema France
    Inventors: Alfredo Defrancisci, Leonard Palys, Peter Dluzneski
  • Patent number: 11111357
    Abstract: The use of peroxide(s) for cross-linking at least one polymer, the polymer having a homopolymer or copolymer of ethylene and especially the ethylene-vinyl acetate copolymer (EVA) or a mixture of the EVA with another homopolymer or copolymer of ethylene, and at least one peroxide, wherein the peroxide includes OO-tert-butyl O-isopropyl monoperoxycarbonate or OO-tert-amyl O-isopropyl monoperoxycarbonate and OO-tert-butyl-O-2-ethyl hexyl monoperoxycarbonate or OO-tert-amyl-O-2ethyl hexyl monoperoxycarbonate. Also, a cross-linkable composition including the peroxide and to a method for producing a cross-linked polymer as a result of the peroxide.
    Type: Grant
    Filed: July 22, 2015
    Date of Patent: September 7, 2021
    Assignee: ARKEMA FRANCE
    Inventors: Alfredo Defrancisci, Chao Lu
  • Publication number: 20210002454
    Abstract: The use of magnesium oxide for increasing the rate of crosslinking and/or the crosslinking density of at least one crosslinkable polymer is described in addition to a composition that can be employed in this use, comprising: from 30 to 80% by weight of a crosslinking co-agent, from 0.5 to 10% by weight of an organic peroxide, from 15 to 60% by weight of magnesium oxide, and from 0 to 40% by weight of one or more crosslinkable polymers. An article obtained from this composition is also described.
    Type: Application
    Filed: February 27, 2019
    Publication date: January 7, 2021
    Applicant: Arkema France
    Inventors: Alfredo Defrancisci, Leonard Palys, Peter Dluzneski
  • Patent number: 10808051
    Abstract: A primer mixture intended for crosslinking polyethylene, including at least an initiator of free radicals chosen from organic peroxides, azo compounds or mixtures thereof, wherein the mixture has said free-radical initiator and at least one crosslinking promoter chosen from the cycloalkanes having 5 to 7 carbon atoms, substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the aromatic compounds substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the methacrylate, acrylate and maleimide monomers being multi-substituted, and in that the weight ratio of free-radical initiator to the crosslinking promoter is greater than or equal to 1, and preferably between 1.5 and 4. Also, a method and to a use related to this primer mixture.
    Type: Grant
    Filed: September 6, 2013
    Date of Patent: October 20, 2020
    Assignee: ARKEMA FRANCE
    Inventors: Alfredo Defrancisci, Fabien Debaud
  • Publication number: 20200299469
    Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
    Type: Application
    Filed: June 10, 2020
    Publication date: September 24, 2020
    Inventors: Leonard H. PALYS, Peter R. DLUZNESKI, William P. PAVLEK, Alfredo DEFRANCISCI, Feng-Jon CHANG, Marina DESPOTOPOULOU, Michael B. ABRAMS, Joseph M. BRENNAN, Isabelle TARTARIN
  • Patent number: 10752764
    Abstract: An organic peroxide formulation includes at least one organic peroxide and at least one cellulose compound. Embodiments of the organic peroxide formulations significant improvements in surface tackiness (often including but not limited to tack-free surfaces) when curing elastomers in the presence of oxygen. Embodiments of the present invention relate to organic peroxide formulations that can cure solid elastomers in the full or partial presence of oxygen using, for example, a hot air oven or tunnel, molten salt bath, or steam autoclave. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.
    Type: Grant
    Filed: December 3, 2015
    Date of Patent: August 25, 2020
    Assignee: Arkema Inc.
    Inventors: Feng-Jon Chang, William P. Pavlek, Leonard H. Palys, Peter R. Dluzneski, Marina Despotopoulou, Alfredo Defrancisci, Joseph M. Brennan, Michael B. Abrams, Isabelle Tartarin
  • Patent number: 10717829
    Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
    Type: Grant
    Filed: May 1, 2019
    Date of Patent: July 21, 2020
    Assignee: Arkema Inc.
    Inventors: Leonard H. Palys, Peter R. Dluzneski, William P. Pavlek, Alfredo Defrancisci, Feng-Jon Chang, Marina Despotopoulou, Michael B. Abrams, Joseph M. Brennan, Isabelle Tartarin
  • Publication number: 20190256671
    Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
    Type: Application
    Filed: May 1, 2019
    Publication date: August 22, 2019
    Inventors: Leonard H. PALYS, Peter R. DLUZNESKI, William P. PAVLEK, Alfredo DEFRANCISCI, Feng-Jon CHANG, Marina DESPOTOPOULOU, Michael B. ABRAMS, Joseph M. BRENNAN, Isabelle TARTARIN
  • Patent number: 10316154
    Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
    Type: Grant
    Filed: December 3, 2015
    Date of Patent: June 11, 2019
    Assignee: Arkema Inc.
    Inventors: Leonard H. Palys, Peter R. Dluzneski, William P. Pavlek, Alfredo Defrancisci, Feng-Jon Chang, Marina Despotopoulou, Michael B. Abrams, Joseph M. Brennan, Isabelle Tartarin
  • Publication number: 20170267855
    Abstract: An organic peroxide formulation includes at least one organic peroxide and at least one cellulose compound. Embodiments of the organic peroxide formulations significant improvements in surface tackiness (often including but not limited to tack-free surfaces) when curing elastomers in the presence of oxygen. Embodiments of the present invention relate to organic peroxide formulations that can cure solid elastomers in the full or partial presence of oxygen using, for example, a hot air oven or tunnel, molten salt bath, or steam autoclave. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.
    Type: Application
    Filed: December 3, 2015
    Publication date: September 21, 2017
    Inventors: Feng-Jon CHANG, William P. PAVLEK, Leonard H. PALYS, Peter R. DLUZNESKI, Marina DESPOTOPOULOU, Alfredo DEFRANCISCI, Joseph M. BRENNAN, Michael B. ABRAMS, Isabelle TARTARIN
  • Publication number: 20170260343
    Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
    Type: Application
    Filed: December 3, 2015
    Publication date: September 14, 2017
    Inventors: Leonard H. PALYS, Peter R. DLUZNESKI, William P. PAVLEK, Alfredo DEFRANCISCI, Feng-Jon CHANG, Marina DESPOTOPOULOU, Michael B. ABRAMS, Joseph M. BRENNAN, Isabelle TARTARIN
  • Publication number: 20170166726
    Abstract: The use of peroxide(s) for cross-linking at least one polymer, the polymer having a homopolymer or copolymer of ethylene and especially the ethylene-vinyl acetate copolymer (EVA) or a mixture of the EVA with another homopolymer or copolymer of ethylene, and at least one peroxide, wherein the peroxide includes OO-tert-butyl O-isopropyl monoperoxycarbonate or OO-tert-amyl O-isopropyl monoperoxycarbonate and OO-tert-butyl-O-2-ethyl hexyl monoperoxycarbonate or OO-tert-amyl-O-2ethyl hexyl monoperoxycarbonate. Also, a cross-linkable composition including the peroxide and to a method for producing a cross-linked polymer as a result of the peroxide.
    Type: Application
    Filed: July 22, 2015
    Publication date: June 15, 2017
    Applicant: ARKEMA FRANCE
    Inventors: Alfredo DEFRANCISCI, Chao LU
  • Publication number: 20170121280
    Abstract: A peroxide solution of organic peroxide in an organic solvent, including at least one peroxide in a solvent, the solvent having a hydrophobic alcohol wherein the main carbonated chain having the alcohol function includes at least six carbon atoms, the solution also including a second, hydrophilic alcohol solvent representing a maximum of 15% wt. % of the solution. Also, a thermohardenable composition including said solution, and a method and a use relating to the composition.
    Type: Application
    Filed: June 8, 2015
    Publication date: May 4, 2017
    Applicant: ARKEMA FRANCE
    Inventors: Jean-Luc DUBOIS, Serge HUB, Alfredo DEFRANCISCI
  • Publication number: 20150239997
    Abstract: A primer mixture intended for crosslinking polyethylene, including at least an initiator of free radicals chosen from organic peroxides, azo compounds or mixtures thereof, wherein the mixture has said free-radical initiator and at least one crosslinking promoter chosen from the cycloalkanes having 5 to 7 carbon atoms, substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the aromatic compounds substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the methacrylate, acrylate and maleimide monomers being multi-substituted, and in that the weight ratio of free-radical initiator to the crosslinking promoter is greater than or equal to 1, and preferably between 1.5 and 4. Also, a method and to a use related to this primer mixture.
    Type: Application
    Filed: September 6, 2013
    Publication date: August 27, 2015
    Applicant: ARKEMA FRANCE
    Inventors: Alfredo Defrancisci, Fabien Debaud
  • Publication number: 20140305677
    Abstract: A masterbatch including an ethylene copolymer and at least one ethylene comonomer having at least one polar group, an organic peroxide, and an anti-oxidant, the organic peroxide accounting for 0.2 to 100 parts by weight, for 100 parts by weight of the copolymer, and the anti-oxidant accounting for 0.02 to 50 parts by weight, for 100 parts by weight of the copolymer. Also, methods for preparing the masterbatch and to the uses of said masterbatch for manufacturing insulating layers for electric cables and for limiting or preventing the water tree phenomenon for electric cables.
    Type: Application
    Filed: October 19, 2012
    Publication date: October 16, 2014
    Applicant: ARKEMA FRANCE
    Inventors: Alfredo Defrancisci, Vincent Palluault
  • Patent number: 8629213
    Abstract: The invention relates to a composition including at least one elastomer and at least one supramolecular polymer. The supramolecular polymer is obtained by the reaction of at least one trifunctional compound (A), having first and second functions, with: at least one compound (B) having at least one reactive group capable of reacting with the first functions of (A) and at least one associative group; and at least one at least bifunctional compound (C) having functions capable of reacting with the second functions of compound (A) in order to form ester, thioester and amide bridges.
    Type: Grant
    Filed: September 21, 2010
    Date of Patent: January 14, 2014
    Assignee: Arkema France
    Inventors: Manuel Hidalgo, Christelle Plaut, Alfredo Defrancisci
  • Publication number: 20120220725
    Abstract: The invention relates to a composition including at least one elastomer and at least one supramolecular polymer. The supramolecular polymer is obtained by the reaction of at least one trifunctional compound (A), having first and second functions, with: at least one compound (B) having at least one reactive group capable of reacting with the first functions of (A) and at least one associative group; and at least one at least bifunctional compound (C) having functions capable of reacting with the second functions of compound (A) in order to form ester, thioester and amide bridges.
    Type: Application
    Filed: September 21, 2010
    Publication date: August 30, 2012
    Applicant: ARKEMA FRANCE
    Inventors: Manuel Hidalgo, Christelle Plaut, Alfredo Defrancisci
  • Patent number: 7829634
    Abstract: The invention relates to scorch prevention and, more specifically, to a composition which comprises a nitroxide and at least one organic peroxide and which can be used to delay scorching prior to crosslinking of thermoplastic compositions and/or elastomers. The invention also relates to a crosslinkable composition and to a crosslinking method.
    Type: Grant
    Filed: September 16, 2005
    Date of Patent: November 9, 2010
    Assignee: Arkema France
    Inventors: Fabien Debaud, Jacques Kervennal, Alfredo Defrancisci, Olivier Guerret