Abstract: A solution for injection to a formation containing hydrocarbons includes an ionic liquid and a brine having a salinity of at least 60,000 ppm total dissolved solids (TDS). The ionic liquid is configured to lower an interfacial tension between the solution and the hydrocarbons in the formation.

Abstract: A solution for injection to a formation containing hydrocarbons includes an ionic liquid and a brine having a salinity of at least 60,000 ppm total dissolved solids (TDS). The ionic liquid is configured to lower an interfacial tension between the solution and the hydrocarbons in the formation.

Abstract: A method for manufacturing a micromodel with a mixed wettability surface representing a hydrocarbon reservoir is disclosed. The method includes coating a top surface of a hydrophilic substrate with photoresist, covering a top of the photoresist with a photomask, exposing the covered top of the photoresist to UV light that changes a chemical property of a region of the photoresist corresponding to a pattern of the photomask, removing the photomask, removing the region of the photoresist corresponding to the pattern of the photomask based on the chemical property of the region, depositing a hydrophobic thin-film on top of the hydrophilic substrate, and removing a remaining photoresist covered with the thin-film, such that the surface of the hydrophilic substrate is patterned with both a region covered with the hydrophobic thin-film and an uncovered region of the hydrophilic substrate, creating a mixed wettability surface on the hydrophilic substrate that represents the micromodel.

Abstract: Methods for fabricating a sensor module for detecting carbon dioxide leakage from a subsurface reservoir are disclosed. The methods include attaching anodic aluminum oxide porous membrane onto a first conductive electrode to form an anodic aluminum oxide template; initiating growth of a plurality of TiO2 nanotubes inside the AAO template using an atomic layer deposition process; removing the anodic aluminum oxide template from the first metal electrode leaving the plurality of TiO2 nanotubes on the first conductive electrode; attaching a second conductive electrode to the plurality of TiO2 nanotubes; connecting the first and the second conductive electrodes with an electric line to form a sensor; providing a rollable sheet of non-conductive material; and attaching a plurality of sensors to the rollable sheet of non-conductive material forming the sensor module.

Abstract: A method includes 3d printing a polymer substrate having microfluidic channels and depositing calcite onto the polymer substrate then using atomic layer deposition to form a calcite microfluidic device. A device made from the method includes a 3d printed polymer substrate having microfluidic channels. The 3d printed polymer substrate has a calcite coating.

Abstract: A method of making a portion of a microfluidic channel includes lithographically patterning a first pattern into a first layer of photoresist disposed on a substrate, the first pattern representative of morphology of a reservoir rock; etching the first pattern into the substrate to form a patterned substrate; disposing a second layer of photoresist onto the patterned substrate; lithographically patterning a second pattern into the second layer of photoresist to reveal portions of the patterned substrate; and depositing calcite onto the exposed portions of the patterned substrate.

Abstract: A method for determining interfacial tension of a hydrocarbon in a brine fluid, the method including injecting a first brine fluid into a test cell, the first brine fluid having an initial ionic composition, injecting a hydrocarbon fluid into the test cell, contacting the hydrocarbon fluid with the first brine fluid, forming a droplet, measuring the interfacial tension of the hydrocarbon fluid in contact with the first brine fluid, at least partially displacing the first brine fluid with an inert gas, measuring a ionic composition salinity of the displaced first brine fluid in an ionic chromatograph, and comparing the measured ionic composition salinity to the initial ionic composition.

Abstract: A method includes flowing an inlet solution having an inlet salinity and an inlet ion concentration from an inlet to a membrane filtration system, dynamically adjusting the salinity or ion concentration of the inlet solution in situ as the inlet solution flows to an inlet of a microfluidic cell, and determining a wettability alteration in situ while dynamically adjusting the salinity or ion concentration of the inlet solution. A system includes a fluid inlet, a microfluidic cell fluidly coupled to the fluid inlet, the microfluidic cell having a surface representative of a reservoir rock, and a membrane filtration system coupled between the microfluidic cell and the fluid inlet.

Abstract: A pressure cell for sum frequency generation spectroscopy includes: a metal pressure chamber; a heating stage that heats a liquid sample; an ultrasonic stage that emulsifies the liquid sample; a chamber pump that pressurizes an interior of the metal pressure chamber; and a controller that controls the chamber pump, the ultrasonic stage, and the heating stage to control a pressure of the interior of the metal pressure chamber, an emulsification of the liquid sample, and a temperature of the liquid sample, respectively. The metal pressure chamber includes: a liquid sample holder that retains the liquid sample; a removable lid that seals against a base; a window in the removable lid; a sample inlet that flows the liquid sample from an exterior of the metal pressure chamber to the liquid sample holder at a predetermined flow rate; and a sample outlet.

Abstract: A pressure cell includes a metal pressure chamber, a heating stage, disposed in the interior of the metal pressure chamber, that heats the liquid sample, a chamber pump, connected to the interior of the metal pressure chamber, that pressurizes the interior of the metal pressure chamber, a salinity control system including a membrane coupled to the sample inlet, where the membrane is configured to reduce a salinity level of the liquid sample, and a controller that controls the chamber pump, the salinity control system, and the heating stage to control a pressure of the interior of the metal pressure chamber, a salinity level of the liquid sample, and a temperature of the liquid sample, respectively. The metal pressure chamber includes a liquid sample holder, a removable lid, a window in the removable lid, a sample inlet, and a sample outlet.

Abstract: A pressure cell includes a metal pressure chamber, a heating stage, disposed in the interior of the metal pressure chamber, that heats the liquid sample, a chamber pump, connected to the interior of the metal pressure chamber, that pressurizes the interior of the metal pressure chamber, a salinity control system including a membrane coupled to the sample inlet, where the membrane is configured to reduce a salinity level of the liquid sample, and a controller that controls the chamber pump, the salinity control system, and the heating stage to control a pressure of the interior of the metal pressure chamber, a salinity level of the liquid sample, and a temperature of the liquid sample, respectively. The metal pressure chamber includes a liquid sample holder, a removable lid, a window in the removable lid, a sample inlet, and a sample outlet.

Abstract: A pressure cell for sum frequency generation spectroscopy includes: a metal pressure chamber; a heating stage that heats the liquid sample; a pump, connected to an interior of the metal pressure chamber, that pressurizes the interior of the metal pressure chamber; and a controller that controls the pump and the heating stage to control a pressure of the interior of the metal pressure chamber and a temperature of a liquid sample. The metal pressure chamber includes: a base that retains the liquid sample; a removable lid that seals against the base to enclose the liquid sample in the metal pressure chamber; and a window in the removable lid that exposes the liquid sample to an exterior of the metal pressure chamber.

Abstract: A method for fabricating calcite channels in a nanofluidic device is described. A porous membrane is attached to a substrate. Calcite is deposited in porous openings in the porous membrane attached to the substrate. A width of openings in the deposited calcite is in a range from 50 to 100 nanometers (nm). The porous membrane is etched to remove the porous membrane from the substrate to form a fabricated calcite channel structure. Each channel has a width in the range from 50 to 100 nm.

Abstract: A method may include providing a humidification-dehumidification unit proximate one or more abandoned wells, circulating a water feed through the one or more abandoned wells, using geothermal heat in the one or more abandoned wells to heat the water feed, directing the heated water feed to the humidification-dehumidification unit, and treating the heated water feed in the humidification-dehumidification unit to provide purified water.

Abstract: A method may include providing a humidification-dehumidification unit proximate one or more abandoned wells, circulating a water feed through the one or more abandoned wells, using geothermal heat in the one or more abandoned wells to heat the water feed, directing the heated water feed to the humidification-dehumidification unit, and treating the heated water feed in the humidification-dehumidification unit to provide purified water.

Abstract: Methods and systems are provided for measuring the zeta potential of macroscopic solid surfaces including and not limited to: porous samples, flat substrates, coarse particles, and granular samples. Methods include: subjecting the sample to an injection of a first aqueous solution at an initial pressure with an initial ion concentration; measuring a first electrical conductivity and a first temperature of the first aqueous solution; measuring a first pH and a second pH of the first aqueous solution immediately before and after passing the first aqueous solution through the sample; measuring a first ion concentration and a second ion concentration of the first aqueous solution immediately before and after passing the first aqueous solution through the sample; and processing the measured data to derive a first zeta potential from the first electrical conductivity and the first temperature.

Abstract: A hydrocarbon recovery method using artificial, fresh rain water is described. The method includes generating artificial, fresh rain water. A volume of the generated artificial, fresh rain water is mixed with a volume of brine water obtained from a brine water source to form a mixture having a water salinity that satisfies a threshold water salinity. The mixture is injected into an injection well formed in a subterranean zone. The injection well is fluidically coupled to a producing well formed in the subterranean zone to produce hydrocarbons residing in the subterranean zone. The mixture flows the hydrocarbons in the subterranean zone surrounding the producing well toward the producing well. The hydrocarbons are produced in response to injecting the mixture in the injection well.

Abstract: A method may include providing a humidification-dehumidification unit proximate one or more abandoned wells, circulating a water feed through the one or more abandoned wells, using geothermal heat in the one or more abandoned wells to heat the water feed, directing the heated water feed to the humidification-dehumidification unit, and treating the heated water feed in the humidification-dehumidification unit to provide purified water.

Abstract: Methods for fabricating a sensor module for detecting carbon dioxide leakage from a subsurface reservoir are disclosed. The methods include attaching anodic aluminum oxide porous membrane onto a first conductive electrode to form an anodic aluminum oxide template; initiating growth of a plurality of TiO2 nanotubes inside the AAO template using an atomic layer deposition process; removing the anodic aluminum oxide template from the first metal electrode leaving the plurality of TiO2 nanotubes on the first conductive electrode; attaching a second conductive electrode to the plurality of TiO2 nanotubes; connecting the first and the second conductive electrodes with an electric line to form a sensor; providing a rollable sheet of non-conductive material; and attaching a plurality of sensors to the rollable sheet of non-conductive material forming the sensor module.

Abstract: Downhole drilling tools and methods for drilling and detecting carbon dioxide leakage in a subsurface reservoir are disclosed. The tools include a cylindrical body; a sensor module including a plurality of sensors including a first conductive electrode, a second conductive electrode, and a plurality of TiO2 nanotubes, and an electric line located between and connecting the first and the second conductive electrodes; and a communication device communicatively connected to the sensor module; wherein the sensor module and the communication device are attached to an outer surface of the cylindrical body.