Abstract: A compositionally-graded structure including a body having a first major surface and a second major surface opposed from the first major surface along a thickness axis, the body including a metallic component and a ceramic component, wherein a concentration of the ceramic component in the body is a function of location within the body along the thickness axis, wherein transitions of the concentration of the ceramic component in the body are continuous such that distinct interfaces are not macroscopically established within the body, and wherein the concentration of the ceramic component is at least 95 percent by volume at at least one location within the body along the thickness axis.

Abstract: A metallic material manufactured by a method including steps of (1) subjecting a semifinished metallic billet having at least one of a nanocrystalline microstructure and an ultrafine-grained microstructure to a rotary incremental forming process to form an intermediate wrought metallic billet and (2) subjecting the intermediate wrought metallic billet to a high rate forming process, wherein the high rate forming process includes a high rate forming process average equivalent strain rate, the high rate forming process average equivalent strain rate being at least about 0.1 s?1.

Abstract: An integrated composite structure with a graded coefficient of thermal expansion (CTE) is formed by selecting a plurality of layers of materials with a graded CTE and using build-up (bottom-up) fabrication approaches such as metal deposition or powder metallurgy to produce a CTE-graded layered composite preform, which is then consolidated and heat treated to create the CTE graded integrated composite billet or near net shape. The integrated composite billet or near net shape is then processed to produce a first surface for attachment of a first structural member having a first CTE and to produce a second surface of for attachment of a second structural member having a second CTE.

Abstract: An interlayered structure for joining of dissimilar materials, includes a first material substrate, a second material substrate having a composition dissimilar from a composition of the first material substrate, and a plurality of interlayers disposed between the first material substrate and the second material substrate, including a first interlayer nearest to the first material substrate and a last interlayer nearest to the second material substrate. The first interlayer has a composition selected to have a maximum solid solubility within the composition of the first material substrate that is greater than or equal to the other interlayers' solubility within the composition of the first material substrate. The last interlayer has a composition selected to have a maximum solid solubility within the composition of the second material substrate that is greater than or equal to the other interlayers' solubility within the composition of the second material substrate.

Abstract: A method for manufacturing a component having a spatially graded property includes providing a first layer of particulate matter, the first layer having first material characteristics, and providing a second layer of particulate matter, the second layer having second material characteristics different from the first material characteristics. The method further includes providing an interlayer between the first layer and the second layer and heating the first layer, the second layer, and the interlayer to bond the first layer with the second layer.

Abstract: A compositionally-graded structure including a body having a first major surface and a second major surface opposed from the first major surface along a thickness axis, the body including a metallic component and a ceramic component, wherein a concentration of the ceramic component in the body is a function of location within the body along the thickness axis, wherein transitions of the concentration of the ceramic component in the body are continuous such that distinct interfaces are not macroscopically established within the body, and wherein the concentration of the ceramic component is at least 95 percent by volume at at least one location within the body along the thickness axis.

Abstract: In one or more aspects of the present disclosure, an aerospace vehicle includes a frame, an actuable multifunctional cellular structure connected to the frame, the actuable multifunctional cellular structure including a first face member and a second face member, and a shape memory alloy core coupled to the first face member and the second face member, and wherein, at least one of the first face member and the second face member is a graded thermal structure configured so that heat transferred through the graded thermal structure in a predetermined thermal pattern to the shape memory alloy core effects a predetermined change in a shape of the shape memory alloy core and effects a change in shape of the actuable multifunctional cellular structure.

Abstract: A method for production of a metallic material from a semifinished metallic billet, the semifinished metallic billet including a nanocrystalline microstructure and/or an ultrafine-grained microstructure, the method including the steps of (1) subjecting the semifinished metallic billet to a rotary incremental forming process to form an intermediate wrought metallic billet, and (2) subjecting the intermediate wrought metallic billet to a high rate forming process to form a metallic product.

Abstract: In one or more aspects of the present disclosure, an aerospace vehicle includes a frame, an actuable multifunctional cellular structure connected to the frame, the actuable multifunctional cellular structure including a first face member and a second face member, and a shape memory alloy core coupled to the first face member and the second face member, and wherein, at least one of the first face member and the second face member is a graded thermal structure configured so that heat transferred through the graded thermal structure in a predetermined thermal pattern to the shape memory alloy core effects a predetermined change in a shape of the shape memory alloy core and effects a change in shape of the actuable multifunctional cellular structure.

Abstract: A method for production of a metallic material from a semifinished metallic billet, the semifinished metallic billet including a nanocrystalline microstructure and/or an ultrafine-grained microstructure, the method including the steps of (1) subjecting the semifinished metallic billet to a rotary incremental forming process to form an intermediate wrought metallic billet, and (2) subjecting the intermediate wrought metallic billet to a high rate forming process to form a metallic product.

Abstract: A method for production of a metallic material from a semifinished metallic billet, the semifinished metallic billet including a nanocrystalline microstructure and/or an ultrafine-grained microstructure, the method including the steps of (1) subjecting the semifinished metallic billet to a rotary incremental forming process to form an intermediate wrought metallic billet, and (2) subjecting the intermediate wrought metallic billet to a high rate forming process to form a metallic product.

Abstract: A laminated ceramic matrix composite structure is strengthened with one or more layers of a metal reinforcement. The metal reinforcement is selected to provide optimal strength and thermal compatibility with the ceramic matrix composite. The metal reinforcement includes an outer oxidized layer that bonds to the ceramic matrix composite. It may also include a barrier layer on the surface of the metal that helps prevent further oxidation. The structure is formed using standard composite prepreg layup techniques.

Abstract: An integrated composite structure with a graded coefficient of thermal expansion (CTE) is formed by selecting a plurality of layers of materials with a graded CTE and using build-up (bottom-up) fabrication approaches such as metal deposition or powder metallurgy to produce a CTE-graded layered composite preform, which is then consolidated and heat treated to create the CTE graded integrated composite billet or near net shape. The integrated composite billet or near net shape is then processed to produce a first surface for attachment of a first structural member having a first CTE and to produce a second surface of for attachment of a second structural member having a second CTE.

Abstract: An integrated composite structure with a graded coefficient of thermal expansion (CTE) is formed by selecting a plurality of layers of materials with a graded CTE and using build-up (bottom-up) fabrication approaches such as metal deposition or powder metallurgy to produce a CTE-graded layered composite preform, which is then consolidated and heat treated to create the CTE graded integrated composite billet or near net shape. The integrated composite billet or near net shape is then processed to produce a first surface for attachment of a first structural member having a first CTE and to produce a second surface of for attachment of a second structural member having a second CTE.

Abstract: The present invention provides a heretofore-unknown use for zirconium nitride as a hydrogen peroxide compatible protective coating that was discovered to be useful to protect components that catalyze the decomposition of hydrogen peroxide or corrode when exposed to hydrogen peroxide. A zirconium nitride coating of the invention may be applied to a variety of substrates (e.g., metals) using art-recognized techniques, such as plasma vapor deposition. The present invention further provides components and articles of manufacture having hydrogen peroxide compatibility, particularly components for use in aerospace and industrial manufacturing applications. The zirconium nitride barrier coating of the invention provides protection from corrosion by reaction with hydrogen peroxide, as well as prevention of hydrogen peroxide decomposition.

Abstract: The present invention provides a heretofore-unknown use for zirconium nitride as a hydrogen peroxide compatible protective coating that was discovered to be useful to protect components that catalyze the decomposition of hydrogen peroxide or corrode when exposed to hydrogen peroxide. A zirconium nitride coating of the invention may be applied to a variety of substrates (e.g., metals) using art-recognized techniques, such as plasma vapor deposition. The present invention further provides components and articles of manufacture having hydrogen peroxide compatibility, particularly components for use in aerospace and industrial manufacturing applications. The zirconium nitride barrier coating of the invention provides protection from corrosion by reaction with hydrogen peroxide, as well as prevention of hydrogen peroxide decomposition.

Abstract: The present invention provides a heretofore-unknown use for zirconium nitride as a hydrogen peroxide compatible protective coating that was discovered to be useful to protect components that catalyze the decomposition of hydrogen peroxide or corrode when exposed to hydrogen peroxide. A zirconium nitride coating of the invention may be applied to a variety of substrates (e.g., metals) using art-recognized techniques, such as plasma vapor deposition. The present invention further provides components and articles of manufacture having hydrogen peroxide compatibility, particularly components for use in aerospace and industrial manufacturing applications. The zirconium nitride barrier coating of the invention provides protection from corrosion by reaction with hydrogen peroxide, as well as prevention of hydrogen peroxide decomposition.

Abstract: An integrated composite structure with a graded coefficient of thermal expansion (CTE) is formed by selecting a plurality of layers of materials with a graded CTE and using joining approaches such as welding, brazing, or solid state bonding to produce a CTE-graded layered composite or near net shape. The integrated composite billet or near net shape is then processed to produce a first surface for attachment of a first structural member having a first CTE and to produce a second surface of for attachment of a second structural member having a second CTE.

Abstract: An integrated composite structure with a graded coefficient of thermal expansion (CTE) is formed by selecting a plurality of layers of materials with a graded CTE and using build-up (bottom-up) fabrication approaches such as metal deposition or powder metallurgy to produce a CTE-graded layered composite preform, which is then consolidated and heat treated to create the CTE graded integrated composite billet or near net shape. The integrated composite billet or near net shape is then processed to produce a first surface for attachment of a first structural member having a first CTE and to produce a second surface of for attachment of a second structural member having a second CTE.

Abstract: A laminated ceramic matrix composite structure is strengthened with one or more layers of a metal reinforcement. The metal reinforcement is selected to provide optimal strength and thermal compatibility with the ceramic matrix composite. The metal reinforcement includes an outer oxidized layer that bonds to the ceramic matrix composite. It may also include a barrier layer on the surface of the metal that helps prevent further oxidation. The structure is formed using standard composite prepreg layup techniques.