Abstract: A cumene oxidation product containing cumene hydroperoxide (CHP) and dimethylphenylcarbinol (DMPC) is decomposed with acid catalyst in a first step at mild temperatures that lowers the CHP concentration to about 0.5-5% and converts most of the DMPC to dicumylperoxide (DCP). In a second step at mild temperatures the CHP concentration is lowered below 0.4%. In a third step the DCP is decomposed at a higher temperature for a short time to alpha-methylstyrene (AMS), phenol and acetone, with any remaining DMPC also converted to AMS. The DCP concentration is monitored during the third step, and the reaction is stopped by cooling when about 0.5-5% of the DCP remains undecomposed so as to maximize AMS yield.

Abstract: Aqueous phosphoric acid solutions containing uranium values are contacted with an organic solution of a mixture of organophosphorus compounds produced from a carboxylic acid and PCl.sub.3 in the presence of water or from corresponding acid halides or anhydrides and phosphorous acid to extract the uranium values. The organophorus compounds generally include an alkane-1,1,2-triphosphonic acid or a 1-hydroxy-1,1-alkanediphosphonic acid or both, which differ from common organophosphorus extractants in having a carbon-phosphorus bond. The extraction has high distribution coefficients even when the phosphoric acid solution is 10 molar or more and even when the extraction is conducted at elevated temperatures such as 60.degree. C. While distribution coefficients in the presence of iron are higher for tetravalent uranium, efficient extraction can be conducted of hexavalent uranium as well.

Abstract: A process for separating hydroxylamine from an aqueous solution containing hydroxylammonium salts in mixture with salts of predominantly monovalent cations whose corresponding free bases have base dissociation constants greater than 10.sup.-7. Said solution is passed through a bed of cation exchange resin loaded predominantly with monovalent cations whereby hydroxylammonium and the other cations in solution substantially displace said cations from the resin. A second aqueous solution containing a monovalent amine or hydroxide base of at least 0.5 molar concentration having a dissociation constant greater than 10.sup.-7 is passed through the resin bed whereby hydroxylamine is preferentially released to the solution and the resin is correspondingly loaded with the cation of said base. Hydroxylammonium salts can be crystallized from the solution after addition of a stoichiometric amount of an appropriate acid.

Abstract: A process for obtaining hydroxylammonium salts from aqueous solutions containing hydroxylammonium salts in mixture with ammonium and/or sodium salts. Said solutions are contacted with a water immiscible organic solution containing a cation exchange compound of structure R.sub.1 COOX, or (R.sub.2 O)(R.sub.3 O)POOX, or (R.sub.2 O)PO(OX).sub.2, or mixtures thereof and optionally an additive of structure R.sub.4 R.sub.5 R.sub.6 PO, or (R.sub.4 O)(R.sub.5 O)(R.sub.6 O)PO, or mixtures thereof, wherein R.sub.1 is an alkyl or alkenyl group of from twelve to twenty carbon atoms, R.sub.2 and R.sub.3 are alkyl groups of from six to eighteen carbon atoms, R.sub.4, R.sub.5 and R.sub.6 are alkyl groups of from three to twelve carbon atoms, and X is H, Na or NH.sub.4, whereby hydroxylammonium ions are preferentially extracted from the aqueous phase in exchange for X from the organic phase.

Abstract: A process for separating hydroxylamine from an aqueous solution thereof also containing salts of cations whose corresponding free bases have base dissociation constants greater than 10.sup.-7. Said solution is brought to a pH of 6-11 and is passed through a bed of strongly ionic exchange resin loaded with compensating ions whereby hydroxylamine is retained in the gel volume of the resin bed and the ions in solution are substantially excluded from the resin. The ionic salts accordingly move faster through the bed and predominate in a first effluent fraction and the hydroxylamine appears predominantly in a later effluent fraction. Hydroxylammonium salts can be crystallized from the effluent hydroxylamine solution after addition of a stoichiometric amount of an appropriate acid.

Abstract: A process is described for preparing metal alkyl carbonates, useful as carboxylating agents, which comprises reacting an inorganic metal salt with an aliphatic monohydric alcohol containing 1 to 3 carbon atoms and carbon dioxide under substantially anhydrous conditions in the presence of a solid acid acceptor, said alcohol being employed in sufficient amount to form a solution of the resulting metal alkyl carbonate in the alcohol.