Abstract: Mask (10, 10?, 21, 22, 30) for use in coating a carbon-carbon composite brake disc (25) with anti-oxidant. The mask is composed of carbon-carbon composite material or nonreactive ceramic material. The mask is configured with edge ridges (11, 13, 34, 36) that are aligned with the outer and inner annular diameters of the carbon-carbon composite brake disc, a gas flow channel (12, 32) between the ridges, and a gas access port (18, 40) that allows gas to enter the gas flow channel. The mask may also include a gas exit port (16) having a valve (17) operatively connected thereto, so that gas flow may be restricted when pressure within the mask and carbon-carbon composite brake disc falls below a specified minimum value.

Abstract: An apparatus for bonding a first carbon composite to a second carbon composite through a reactant layer includes a housing, and a pair of conductive press plates electrically isolated from the housing. The press plates are adapted to position the two parts to be bonded with a reactant layer therebetween. The press plates are subjected to an electrical potential and a clamping force, sufficient to initiate a combustion reaction that creates a molten ceramic to bond together the carbon-carbon composites.

Abstract: Constraint fixture for processing annular preforms. The constraint fixture is made up of a lower plate, a top plate, a ring for the outside diameter of an annular preform being treated within the constraint fixture, and a ring for the inside diameter of the annular preform. The outside diameter and inside diameter rings are made of thin flexible sheet metal strips or thin flexible carbon-carbon composite strip material. The thin flexible strips are joined together by deformable joints, so that the flexible constraint system retains pitch within the fibrous matrix of the preform. The outside diameter strips may be joined together by expandable joints and the inside diameter strips may be joined together by collapsible joints. Also, a method of avoiding damage to an annular fibrous preform, e.g., an aircraft brake disc preform, during a carbonization procedure. This method involves carbonizing the annular fibrous preform in the constraint fixture of the invention.

Abstract: Method of carbonizing pitch-infiltrated fibrous annular preform by: infiltrating the preform with pitch; placing the pitch-infiltrated preform in a constraint fixture having an ejector base plate, an inner wall, an outer wall, and a top press plate; selecting the relative sizes of the preform and the constraint fixture so that a layer of inert friable material may be situated between the preform and walls of the constraint fixture; placing inert friable material (e.g., activated carbon) between the preform and the top, bottom, and walls of the constraint fixture; and subjecting the pitch-infiltrated fibrous preform to carbonization in the constraint fixture. The activated carbon or other inert friable material adsorbs pitch molecules that escape the preform during carbonization, which reduces problems with foaming.

Abstract: Method of manufacturing dense carbon-carbon composite material by: infiltrating a fibrous preform with pitch to form pitch-infiltrated preform; carbonizing the pitch-infiltrated preform; injecting resin or pitch into the preform in a mold; oxygen stabilizing the filled preform and carbonizing and heat-treating the oxygen-stabilized impregnated preform; and subjecting the preform to a single final cycle of chemical vapor deposition. This process reduces densification time as compared to comparable conventional carbon-carbon composite manufacturing procedures.

Abstract: Process for producing carbon-carbon composite preform, by: providing short carbon fiber segments or short carbon fiber precursor segments; providing pitch in particulate form; combining blend comprising the fiber segments and pitch particles in a mold; subjecting the resulting mixture of fibers and pitch in the mold to an elevated pressure ranging at a temperature above the melting/softening point of the pitch to create an uncarbonized preform; cooling the preform to below its softening point and removing it from the mold; placing the preform in a constraint fixture; and carbonizing the combined components in the constraint fixture at an elevated temperature for a period of time of sufficient to provide a preform having a density in the range 0.8-1.6 grams per cubic centimeter.

Abstract: A resin transfer molding (RTM) apparatus (10) that includes: an extruder (4); at least two mold cavities (15) contained within a mold (16, 18) in the apparatus, arranged so that resin can be extruded from the extruder (4) into the mold; a nozzle (20) for delivering resin from the extruder (4) into the mold; runners (25) in the body of the mold to deliver resin from the nozzle (20) to a mold cavity (15) within the mold; a venting area (29) contiguous to each mold cavity to permit gases to escape from the mold cavity (15) when the mold cavity is infiltrated with resin; and a press (12) to force the mold (16, 18) closed during at least resin injection. An advantageous feature of the present invention is that the mold may be configured to accept a part (19) that is characterized by variations in length, width, and/or thickness, such as a wheel beam key. Also, an RTM process. The process includes: placing a porous preform, e.g.

Abstract: Method of making a carbon-carbon composite article such as an aircraft brake disc. The method includes: selecting carbon fiber precursors, having limited shrinkage in the axial direction when carbonized, in the form of individualized chopped or cut fibers; placing the selected chopped or cut carbon fiber precursors into a preform mold configured in the form of a brake disc to form a fibrous matrix; and then needling the molded fibrous matrix to provide it with three-dimensional structural integrity and to reduce layering. The carbon fiber precursor matrix may subsequently be infused with liquid carbon matrix precursor, the impregnated matrix may be carbonized; e.g., at 600-1800° C. for 1-10 hours to provide a preform having a density of at least about 1.1 g/cc, and the carbonized preform may be further densified to a density of at least about 1.6 g/cc by known liquid resin infiltration techniques and/or by conventional CVI/CVD processing.

Abstract: Method for manufacturing a carbonized carbon-carbon composite preform, by: mixing (a) chopped carbon fiber, chopped stabilized pitch fiber, or chopped oxidized polyacrylonitrile (PAN) fiber, (b) thermoplastic pitch binder powder, and (c) activated carbon powder to form a mixture of 15-60 parts by weight of chopped carbon fiber or chopped stabilized pitch fiber or chopped oxidized PAN, 28-83 parts by weight of thermoplastic pitch binder powder, and 1-12 parts by weight of activated carbon powder; depositing this mixture into a mold; pressing/heating the materials in the mold to form a preform by compaction; removing the compacted preform from the mold; and carbonizing the compacted preform. The preform is preferably configured in the form of an aircraft landing system brake disc.

Abstract: A restraint fixture (12) is disclosed that includes a preform retention region configured to limit contracting forces applied against a preform (10) in the preform retention region when the restraint fixture (12) thermally contracts. In one embodiment, the restraint fixture (12) comprises a band (12) having a first surface defining the preform retention region and a first expansion portion (26, 28, 29) adapted to deform upon application of a force to the band (12).

Abstract: Mask (10, 10?, 21, 22) for use in coating a carbon-carbon composite brake disc (25) with anti-oxidant. The mask is composed of carbon-carbon composite material or nonreactive ceramic material. The mask is configured with edge ridges (11, 13) that are aligned with the outer and inner annular diameters of the carbon-carbon composite brake disc, a gasflow channel (12) between the ridges, and a gas access port (18) that allows gas to enter the gasflow channel. The mask may also include a gas exit port (16) having a valve (17) operatively connected thereto, so that gas flow may be restricted when pressure within the mask and carbon-carbon composite brake disc falls below a specified minimum value.

Abstract: Methods of making a carbon-carbon composite preforms, particularly suitable as brake discs in aircraft landing systems, by combining titanium carbide particles ranging in size from 0.01 to 10 microns in diameter, resinous binder, and carbon fibers or carbon fiber precursors in a mold, and subsequently subjecting the combined components to pressure and heat to carbonize the resinous binder by methods, thereby providing the carbon-carbon composite preform having particulate titanium carbide uniformly distributed throughout its mass. Prior to combining the titanium carbide and the binder with the fibers in this process, the particulate titanium carbide may be mixed with liquid binder, the resulting TiC/binder mixture may then solidified, and the resulting solid TiC/binder mixture may be ground into a fine powder for use in the process. Also, compositions for preparing a carbon-carbon composite friction materials, and methods of improving wear and dynamic stability in a carbon-carbon composite brake discs.

Abstract: The present invention makes use of loose fibrous material (for instance, chopped fibers) as reinforcement matrix material in the manufacture of carbon-carbon composites. In accordance with this invention, a constraint fixture is provided which can be separated from the mold. The constraint fixture has an internal shape corresponding to the shape of a desired preform component, with the internal shape being defined by a bottom plate (2), an annular ejector plate (3, 3?), a inner wall (10), an outer wall (4), and an annular top plate (11, 11?). The constraint fixture is normally made of metal, porous ceramic, or carbon material. The constraint fixture of the mold holds the loose matrix materials (fibers, along with any fillers and/or additives). The mold assembly itself is segmented, so that the constraint, fixture and the loose fill materials in the fixture can be removed and subjected to further processing as a unit.