Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.

Abstract: System and method of a pace engine for governing the different transmission rates tailored for different connections by rate pacing a plurality of queues are described. Roughly described, the pace engine includes a binning controller for receiving queues from a transmit DMA queue manager and determines the earliest allowed time for a particular queue that is stored and paced in a Work Bin, a Fast Bin, or a Slow Bin. A pace table stores information about the minimum inter-packet-gap for each connection that is coupled to the transmit DMA queue manager. A timer is coupled to the binning controller with a multi-bit continuous counter that increments at a predetermined time unit and wraps around after a predetermined amount of time.

Abstract: Catalytic enzyme-modified textiles are disclosed for providing protection from chemical exposure. The textiles are composed of a cloth substrate, at least one polyelectrolyte layer, at least one enzyme layer to degrade the chemical agent, and at least one capping layer. Also disclosed is the related method for making catalytic enzyme-modified textiles.

Abstract: A composite structure exhibiting the ability to degrade chemical or biological agents upon contact comprising a substrate to be protected from the deleterious effects of chemical or biological agents possessing surface groups capable of deactivating materials having the ability to degrade chemical or biological agents, a buffer film, coated onto the substrate, that blocks the ability of the substrate surface groups to deactivate the materials having the ability to degrade chemical or biological agents, and a protective film, coated onto the buffer film, containing materials having the ability to degrade chemical or biological agents encapsulated in or comprising the outer surface of the protective film.

Abstract: A bioactive catalytic material is disclosed for providing protection from chemical exposure. The material is composed of enzymes immobilized within polyelectrolyte multilayers and a polymerizable end-capping layer to render stability to enzymes. Also disclosed is the related method for making a bioactive catalytic material and their deposition on substrates of varying size, shape and flexibility for providing active protection from chemical exposure.

Abstract: Catalytic enzyme-modified textiles are disclosed for providing protection from chemical exposure. The textiles are composed of a cloth substrate, at least one polyelectrolyte layer, at least one enzyme layer to degrade the chemical agent, and at least one capping layer. Also disclosed is the related method for making catalytic enzyme-modified textiles.

Abstract: System and method of a pace engine for governing the different transmission rates tailored for different connections by rate pacing a plurality of queues are described. Roughly described, the pace engine includes a binning controller for receiving queues from a transmit DMA queue manager and determines the earliest allowed time for a particular queue that is stored and paced in a Work Bin, a Fast Bin, or a Slow Bin. A pace table stores information about the minimum inter-packet-gap for each connection that is coupled to the transmit DMA queue manager. A timer is coupled to the binning controller with a multi-bit continuous counter that increments at a predetermined time unit and wraps around after a predetermined amount of time.

Abstract: Catalytic enzyme-modified textiles are disclosed for providing protection from chemical exposure. The textiles are composed of a cloth substrate, at least one polyelectrolyte layer, at least one enzyme layer to degrade the chemical agent, and at least one capping layer. Also disclosed is the related method for making catalytic enzyme-modified textiles.

Abstract: A bioactive catalytic material is disclosed for providing protection from chemical exposure. The material is composed of enzymes immobilized within polyelectrolyte multilayers and a polymerizable end-capping layer to render stability to enzymes. Also disclosed is the related method for making a bioactive catalytic material and their deposition on substrates of varying size, shape and flexibility for providing active protection from chemical exposure.

Abstract: A galvanic cell having a cathode, an anode, and an electrolyte. The cathode and anode each have vesicles, an electroactive species encapsulated into the vesicles, a conducting substrate, and functionalized tethers immobilizing the vesicles to the substrates. The electrolyte is in contact with both conducting substrates. At least some of the vesicles contain benzoquinone and/or hydroquinone.

Abstract: A membrane is disclosed made from a compound having a hydrophilic head group, an aliphatic tail group, and a polymerizable functional group. The membrane spans an aperture and may be polymerized. The membrane may be useful for DNA sequencing when the membrane includes an ion channel.

Abstract: A bioactive catalytic material is disclosed for providing protection from chemical exposure. The material is composed of enzymes immobilized within polyelectrolyte multilayers and a polymerizable end-capping layer to render stability to enzymes. Also disclosed is the related method for making a bioactive catalytic material and their deposition on substrates of varying size, shape and flexibility for providing active protection from chemical exposure.

Abstract: Catalytic enzyme-modified textiles are disclosed for providing protection from chemical exposure. The textiles are composed of a cloth substrate, at least one polyelectrolyte layer, at least one enzyme layer to degrade the chemical agent, and at least one capping layer. Also disclosed is the related method for making catalytic enzyme-modified textiles.

Abstract: Enzymes are modified by incorporating anchor sites for linking the enzymes to a target surface without destroying the catalytic activity of the enzymes. A stable carrier to accommodate and bind the selected enzyme is constructed, and the enzyme is non-covalently linked to the carrier, generally through metal salts of iminodiacetate.

Abstract: A galvanic cell having a cathode, an anode, and an electrolyte. The cathode and anode each have vesicles, an electroactive species encapsulated into the vesicles, a conducting substrate, and functionalized tethers immobilizing the vesicles to the substrates. The electrolyte is in contact with both conducting substrates. At least some of the vesicles contain benzoquinone and/or hydroquinone.

Abstract: Enzymes are modified by incorporating anchor sites for linking the enzymes to a target surface without destroying the catalytic activity of the enzymes.

Abstract: A colorimetric detector for chemical and biological agents or toxins is made of a giant unilamellar vesicle (GUV) having a membrane bilayer which is polymerized to stabilize the giant unilamellar vesicle and to provide extended conjugated polymer backbone, and the GUV has at least one incorporated molecular recognition site for the chemical and biological agents or toxins. The GUVs are about 10-300 microns and preferably made of a polymerizable diacetylenic GUV where the acyl chains are crosslinked. When the agents or toxins bind to the recognition site the detector exhibits a color change. The detector can be used in a colorimetric detector apparatus where the samples can be present in air or in water.

Abstract: The invention relates to a microbattery made of bioelectroactive components based on biomimetic processes. Bio-derived electron donors and electron acceptors are separately encapsulated in at least one pair of polymerized phospholipid vesicles. Embedded within the vesicle walls are lipophilic electron mediators that facilitate the transfer of electrons across the vesicle walls. Each pair of vesicles is immobilized on a conducting surface. The pair of vesicles are isolated from each other to create a galvanic cell, in which electrons flow from high to low electrochemical potential. A high energy density battery can be achieved if the vesicles are immobilized on highly porous conducting substrates.

Abstract: Enzymes are modified by incorporating anchor sites for linking the enzymes to a target surface without destroying the catalytic activity of the enzymes.

Abstract: A colorimetric detector for chemical and biological agents or toxins is made of a giant unilamellar vesicle (GUV) having a membrane bilayer which is polymerized to stabilize the giant unilamellar vesicle and to provide extended conjugated polymer backbone, and the GUV has at least one incorporated molecular recognition site for the chemical and biological agents or toxins. The GUVs are about 10-300 microns and preferably made of a polymerizable diacetylenic GUV where the acyl chains are crosslinked. When the agents or toxins bind to the recognition site the detector exhibits a color change. The detector can be used in a colorimetric detector apparatus where the samples can be present in air or in water.