Abstract: A coalescent consisting essentially of a residue from a process for forming propyleneglycol phenyl ether, the coalescent consisting essentially of 65%-75% by weight, based on the weight of the residue, dipropyleneglycol phenyl ether, 8%-10% by weight, based on the weight of the coalescent, monopropyleneglycol phenyl ether, 4%-6% by weight, based on the weight of the coalescent, tripropyleneglycol phenyl ether, and 0.1%-10% by weight, based on the weight of the coalescent, alkalinity(reported as NaOH) is provided. Also provided is a method for forming certain low-VOC, low cost, coalesced aqueous polymeric dispersions including, as copolymerized units, from 70% to 100% by weight, based on the solids weight of the aqueous polymeric dispersion, vinyl acetate monomer and an aqueous coating composition including the coalesced aqueous polymeric dispersion.

Abstract: The present invention relates to a composition, an aqueous dispersion of polymer particles functionalized with acetoacetoxyethyl groups and a CO2 abating additive, an ion exchange resin functionalized with amine groups or quaternary ammonium salt groups or a combination thereof. The composition is useful for CO2 abatement in acetoacetoxy functionalized latexes compositions.

Abstract: The present invention relates to a composition, an aqueous dispersion of polymer particles functionalized with acetoacetoxyethyl groups and a CO2 abating additive, which is a high boiling non-hindered primary amine. The composition is useful for CO2 abatement in acetoacetoxy functionalized latexes compositions.

Abstract: The present invention relates to a composition comprising an aqueous solution of an acid suppressible hydrophobically modified alkylene oxide polymer and a phosphoric acid ester surfactant. The composition of the present invention provides a pourable thickener with high solids content and good phase stability.

Abstract: A new binder composition comprising, by dry weight based on the total dry weight of the binder composition, i) from 93% to 99.96% of polymer particles comprising, as polymerized units, by dry weight based on the total weight of the polymer particles, from 25% to 95% of a vinyl acetate; and from 5% to 75% of a vinyl ester of versatic acid and/or a vinyl ester of 2-ethyl hexanoic acid; and ii) from 0.04% to 7% of a low water soluble cyclodextrin.

Abstract: The present invention relates to a process comprising contacting methyl methacrylate or styrene; a C1-C10-alkyl acrylate; and a polymerizable carboxylic acid monomer with a stable aqueous dispersion of first polymer particles, under emulsion polymerization conditions, to form a stable aqueous dispersion of second polymer particles. The first polymer particles have a Tg in the range of from ?30° C. to 30° C., and the monomers have a calculated Tg in the range of 50° C. to 120° C. The present invention also relates to the dispersion of second polymer particles, which is useful as a binder to improve freeze-thaw stability in a coatings formulation.

Abstract: The present invention relates to a stable aqueous dispersion of acrylic based polymer particles with a first and a second polymeric domain, wherein the first polymeric domain is film-forming at room temperature and the second polymeric domain has a Tg of not less than 35° C., and wherein both polymeric domains include structural units of a ureido monomer. The composition of the present invention addresses a need in the art by providing a composition that is useful as a binder with improved alkyd adhesion properties.

Abstract: The present invention addresses a need in the art by providing a composition comprising an aqueous dispersion of a binder and porous ion exchange resin particles that are functionalized with primary amine groups or secondary amine groups or both. The composition of the present invention provides an efficient way of removing aldehydes from or in the vicinity of a coating prepared from the composition.

Abstract: A composition comprising: (a) from 20 to 60 wt % of a saccharide component comprising from two to five sugar ring units having polymerized units of at least one alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide bonded to oxygen atoms on said sugar rings and at least three acetoacetyl groups bonded to terminal oxygen atoms of said polymerized units of at least one alkylene oxide; and (b) from 40 to 80 wt % of a non-saccharide component comprising a polyol unit not containing a sugar ring and having a hydroxyl functionality from two to five; said polyol unit having polymerized units of at least one alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide bonded to hydroxyl oxygen atoms of the polyol and at least two acetoacetyl groups bonded to terminal oxygen atoms of said polymerized units of at least one alkylene oxide; wherein total polymerized units of at least one alkylene oxide comprise from 20 to 80 wt %

Abstract: The present invention relates to a stable aqueous dispersion of acrylic based polymer particles with a first and a second polymeric domain, wherein the first polymeric domain is film-forming at room temperature and the second polymeric domain has a Tg of not less than 35° C., and wherein both polymeric domains include structural units of a ureido monomer. The composition of the present invention addresses a need in the art by providing a composition that is useful as a binder with improved alkyd adhesion properties.

Abstract: The present invention relates to a process comprising contacting methyl methacrylate or styrene; a C1-C10-alkyl acrylate; and a polymerizable carboxylic acid monomer with a stable aqueous dispersion of first polymer particles, under emulsion polymerization conditions, to form a stable aqueous dispersion of second polymer particles. The first polymer particles have a Tg in the range of from ?30° C. to 30° C., and the monomers have a calculated Tg in the range of 50° C. to 120° C. The present invention also relates to the dispersion of second polymer particles, which is useful as a binder to improve freeze-thaw stability in a coatings formulation.

Abstract: The present invention addresses a need in the art by providing a composition comprising an aqueous dispersion of a binder and porous ion exchange resin particles that are functionalized with primary amine groups or secondary amine groups or both. The composition of the present invention provides an efficient way of removing aldehydes from or in the vicinity of a coating prepared from the composition.

Abstract: This invention provides an aqueous polymeric dispersion, the polymer including, as polymerized units: from 0.1 to 10%, by weight based on the weight of the polymer, monomer selected from the group consisting of strong carboxylic acid monomers, sulfonic acid monomers and phosphorous-containing acid monomers, and from 0.01 to 3%, by weight based on the weight of the polymer, a moiety including the structure, wherein X?CY, N, or P and Y, independently ?H, C, N, O, Cl, Br, F, Si, S, or P. Also, a method for forming the aqueous polymeric dispersion and a method for providing a coating having improved adhesion to a substrate, particularly to a metal substrate, is provided.

Abstract: This invention provides stable aqueous compositions including stable coating compositions, and methods of their production. The stable aqueous compositions and stable aqueous coating compositions comprise one or more emulsion-polymerized addition polymer, one or more carboxylesterase enzyme, and one or more carboxylesterase deactivating agent, such that the ester hydrolysis activity in the composition is less than 0.010 micromole/minute, and wherein the aqueous composition has a headspace volatile organic compound (VOC) content, as measured by headspace gas chromatography-mass spectrometry (GC-MS) at 33° C., of less than 10 ppm of organic carboxylester with a normal boiling point of less than 150° C. and more than 50 ppm of mono-alcohol with a formula molecular weight of less than 76.

Abstract: This invention provides stable aqueous compositions including stable coating compositions, and methods of their production. The stable aqueous compositions and stable aqueous coating compositions comprise i) an aqueous dispersion of one or more emulsion-polymerized addition polymer comprising polymerized units of one or more carboxylester monomer, wherein at least one carboxylester monomer is a vinyl ester monomer; ii) one or more carboxylesterase enzyme; iii) one or more mono-alcohol with a formula molecular weight of less than 76; iv) optionally, acetaldehyde; and v) optionally, one or more organic carboxylester with a normal boiling point of less than 150° C.; and wherein the aqueous composition has a headspace volatile organic compound (VOC) content, as measured by headspace gas chromatography-mass spectrometry (GC-MS) at 33° C.

Abstract: An aqueous including a particulate polymer having a particle diameter of from 0.5 microns to 150 microns, the polymer including, as copolymerized units, from 0.1% to 50%, by weight based on the polymer weight, monomer having a Hansch parameter of from 2.5 to 10, the polymer having been formed in the presence of a non-formaldehyde reductant such as, for example, from 0.01% to 0.5%, by weight based on the polymer weight, isoascorbic acid; and from 0.1% to 5%, by weight based on polymer weight, thickener is provided as is a method for forming a coated substrate and the coated substrate so formed.

Abstract: A low odor aqueous styrene containing polymer dispersions comprising low level acetoacetoxy or acetoacetamide functional group in monomer or as non-polymeric additive with high boiling point organic amine is provided. The aqueous polymer dispersion is useful for preparing low odor coatings.

Abstract: Thickened aqueous compositions, and a method for controlling viscosity drift for thickened aqueous compositions comprising a pigment, a copolymer containing polymerized units of phosphate- or phosphonate-containing monomers, and an acid suppressible thickener.

Abstract: This invention provides stable aqueous compositions including stable coating compositions, and methods of their production. The stable aqueous compositions and stable aqueous coating compositions comprise i) an aqueous dispersion of one or more emulsion-polymerized addition polymer comprising polymerized units of one or more carboxylester monomer, wherein at least one carboxylester monomer is a vinyl ester monomer; ii) one or more carboxylesterase enzyme; iii) one or more mono-alcohol with a formula molecular weight of less than 76; iv) optionally, acetaldehyde; and v) optionally, one or more organic carboxylester with a normal boiling point of less than 150° C.; and wherein the aqueous composition has a headspace volatile organic compound (VOC) content, as measured by headspace gas chromatography-mass spectrometry (GC-MS) at 33° C.

Abstract: A low odor aqueous styrene containing polymer dispersions comprising low level acetoacetoxy or acetoacetamide functional group in monomer or as non-polymeric additive with high boiling point organic amine is provided. The aqueous polymer dispersion is useful for preparing low odor coatings.