Abstract: Cosmetic compositions are provided, which are capable of forming an immiscible multi-layered composition. Cosmetic compositions according to the invention typically include a first composition comprised of a pH dependent film-forming polymer with a target pH and wherein the pH of the first composition is greater than the target pH, and a second composition having a pH less than or equal to the target pH. The immiscible multi-layered composition enable various optical effects that provide enhance coverage, color trueness and enhanced naturalness.